Refractory silicone rubber, preparation method therefor and conducting wire

A silicone rubber and refractory technology, applied in the field of refractory materials, can solve the problems of complex processing technology, cumbersome production equipment, easy breakdown, etc., and achieve the effect of high residual amount, excellent mechanical and processing performance, and fast porcelain forming speed

Inactive Publication Date: 2019-07-16
常州市沃科科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The traditional refractory materials used to produce fire-resistant wires and cables are mainly mica tape, magnesium oxide, and refractory mud, but there are complex processing techniques, cumbersome production equipment, expensive laying costs, complex cable structures, easy moisture absorption, and easy to fall off after ablation, etc. Disadvantages: In recent years, the emerging ceramic refractory silicone rubber and ceramic polyolefin polymer composite materials have solved the above problems to a large extent and have been successfully used in medium and low voltage fire-resistant cables.
[0004] At present, the existing ceramic silica gel and other polymer composite materials on the market generally have the disadvantages of easy cracking after burning candles, poor ductility, high sintering temperature, slow sintering speed, and easy breakdown to cause short circuit, so the application is limited, especially In the fire-resistant wire industry with simple structure, it cannot meet the test requirements of BS6387 and GB / T19216 and other fire-resistant standards

Method used

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  • Refractory silicone rubber, preparation method therefor and conducting wire
  • Refractory silicone rubber, preparation method therefor and conducting wire
  • Refractory silicone rubber, preparation method therefor and conducting wire

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] Add 100 parts of methyl vinyl silicone rubber into a kneader and knead for 5 minutes, add 50 parts of precipitated silica and 8 parts of hydroxyl silicone oil in 5 times, and knead for 20 minutes each time to obtain base rubber A. Here, 50 parts of white carbon black and 8 parts of hydroxy silicone oil are divided into 5 additions mainly because of the long time of one addition, unstable performance, failure to produce qualified products, or high defective rate of products.

[0036] Add 50 parts of wollastonite, 30 parts of kaolin, and 2 parts of vinyltrimethoxysilane to the base rubber A in 4 times, and knead for 15 minutes each time to obtain the base rubber B; the temperature rises to 110 ° C, and vacuumizes for 1 hour. The temperature is -0.06 to -0.08MPa; lower the temperature to below 80°C, add 20 parts of silicon micropowder and 10ppm (based on platinum content) platinum vinyl complex, and continue kneading for 20min to obtain base C; cool the obtained base C Aft...

Embodiment 2

[0038] Add 100 parts of methyl vinyl silicone rubber into a kneader and knead for 5 minutes, add 50 parts of fumed silica and 70 parts of hydroxy silicone oil in 5 times, and knead for 20 minutes each time to obtain base rubber A; Add 60 parts of wollastonite, 20 parts of α-alumina, and 2 parts of vinyltrimethoxysilane in 4 times, and knead for 15 minutes each time to obtain the base rubber B; the temperature rises to 110 ° C, and the vacuum is started for 1 hour. -0.06MPa; lower the temperature to below 80°C, add 20 parts of silicon micropowder and 10ppm (based on platinum content) platinum vinyl complex, and continue kneading for 20 minutes to obtain base C; cool and filter the obtained base C, that is Refractory silicone rubber compounds are available.

Embodiment 3

[0040]Put 100 parts of methyl vinyl silicone rubber into the kneader and knead for 5 minutes, 20 parts of fumed silica, 20 parts of precipitated silica, and 8 parts of hydroxyl silicone oil, add in 5 times, knead for 20 minutes each time, and obtain the base Adhesive A; add 50 parts of wollastonite, 15 parts of α-alumina, 10 parts of talc, and 2.5 parts of vinyltriethoxysilane to the base A in 4 times, and knead for 15 minutes each time to obtain the base B; The temperature rises to 110°C, start vacuuming for 1 hour, and the vacuum degree is -0.065MPa; cool down to below 80°C, add 10 parts of silicon micropowder and 20ppm (based on platinum content) platinum vinyl complex, continue kneading for 20 minutes, and obtain the base Rubber C: After the obtained base rubber C is cooled and filtered, the refractory silicone rubber compound can be obtained.

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Abstract

The invention discloses refractory silicone rubber, a preparation method therefor and a conducting wire. The refractory silicone rubber is prepared from the following raw materials in parts by weight:100 parts of methylvinyl silicone rubber, 10-70 parts of reinforcing filler, 20-150 parts of porcelain forming filler, 0-50 parts of silica micropowder, 3-20 parts of structuring control agent, 0.1-5parts of couplant, 3 ppm to 200 ppm of platinum compound or complex by content of platinum and 0.5-5 parts of vulcanizer. According to the technical scheme of the invention, through effectively matching the above-mentioned several kinds of materials, the refractory silicone rubber with excellent mechanical and processing properties, high porcelain forming speed, no sintering cracking and high residue level can be obtained.

Description

technical field [0001] The invention relates to the technical field of refractory materials, in particular to a refractory silicone rubber, a preparation method thereof, and a wire prepared from the refractory silicone rubber. Background technique [0002] With the progress of society and the improvement of people's living standards, the country pays more and more attention to safety. Especially in the field of wire and cable, once a fire occurs during operation, it may cause chain combustion, affect fire protection and rescue of personnel, and cause unpredictable loss of human life and property. Fire-resistant wire and cable has become an inevitable trend in the field of wire and cable. [0003] The traditional refractory materials used to produce fire-resistant wires and cables are mainly mica tape, magnesium oxide, and refractory mud, but there are complex processing techniques, cumbersome production equipment, expensive laying costs, complex cable structures, easy moist...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L83/07C08L83/04C08K13/02C08K3/36C08K3/34C08K3/22H01B7/295
CPCC08K2003/2227C08K2201/006C08K2201/014C08L83/04C08L2201/02C08L2203/202C08L2205/025H01B7/295C08K13/02C08K3/36C08K3/34C08K3/346C08K3/22
Inventor 郑亚森谢士诚秦克良宋永琦马葵周国华陈玲聪曹俊
Owner 常州市沃科科技有限公司
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