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Refining method and refining system of p-xylene crude product

A technology for crude xylene and p-xylene, which is applied in chemical instruments and methods, isomerization hydrocarbon production, and hydrocarbon purification/separation, etc. rate, adverse effects of adsorbent adsorption capacity, etc.

Pending Publication Date: 2019-07-05
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Second, the adsorption selectivity of the adsorbent to each compound is different, and the limited adsorption space determines that it is difficult to improve the adsorption yield of p-xylene
It can be seen from the strength ranking that although the toluene content is small, it easily occupies the effective adsorption space of the adsorbent and has an adverse effect on the adsorption capacity of the adsorbent.

Method used

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  • Refining method and refining system of p-xylene crude product
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  • Refining method and refining system of p-xylene crude product

Examples

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Embodiment

[0109] The refining method and refining system of the present invention will be further illustratively explained and described below using examples in conjunction with the accompanying drawings, but the present invention is not limited to these examples.

[0110] In the following examples and comparative examples, in order to facilitate the understanding of those skilled in the art, the p-xylene crude product manufacturing unit, conversion unit, separation unit II and pre-refining steps are sometimes quoted, but these are all for the present invention optional. Those skilled in the art may not use these, or replace them with any other units or steps known in the art that can perform similar functions or achieve similar purposes.

[0111] In the following examples and comparative examples, the starting feed stream may be from one or more sources containing C8+ aromatics, including C8+ reformate, toluene shape-selective disproportionation, alkylation products, or C8-containing a...

Embodiment 1

[0118] Embodiment 1 is basically the same as Comparative Example 1, except that unit 141 is newly added, and unit 140 and unit 141 are operated according to the requirements of the present invention.

[0119] Such as figure 2 As shown, starting material stream 1 first enters fractionator 110 for light and heavy component cutting (i.e., pre-refining), containing C 6 -C 7 The material of the components enters the 120 extraction unit through the pipeline 2 as the extraction raw material, and the 120 extraction unit separates the extraction benzene (line 4), the intermediate material C7A (line 3) and the hydrogenated raffinate (line 5). The C8+-enriched component separated by the fractionation tower 110 is used as the raw material of the xylene unit (ie, a crude p-xylene product) and enters the unit 140 (ie, the separation unit I or the I-1 separation unit) through the line 10 . The pipeline 3 contains the extracted C7A stream, which is used as the reaction raw material of the ...

Embodiment 2

[0125] Embodiment 2 is basically the same as Comparative Example 1, except that unit 141 and unit 142 are newly added, and unit 140, unit 141 and unit 142 are operated according to the requirements of the present invention.

[0126] Such as image 3 As shown, starting material stream 21 first enters fractionator 110 for light and heavy component cutting (i.e., pre-refining), containing C 6 -C 7 The material of the components enters the 120 extraction unit through the pipeline 22 as the extraction raw material, and the extraction benzene (the pipeline 25), the intermediate material C7A (the pipeline 24) and the hydrogenated raffinate (the pipeline 26) are separated by the extraction unit; and The C8+-enriched component separated by the fractionation tower 110 is used as the raw material of the xylene unit (ie, a crude p-xylene product) and enters the 140 unit (ie, the separation unit I or the I-1 separation unit) for further processing. The C7A stream is extracted in the pipe...

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Abstract

The invention relates to a refining method and refining system of a p-xylene crude product. The refining method at least comprises the following steps of: (1) conducting first separation on a p-xylenecrude product as separation feed to obtain p-xylene-rich stream and p-xylene-poor stream; (2) repeating the step (1) for n-1 times, each time taking the p-xylene-poor stream obtained by a previous step as the separation feed for first separation respectively, thus obtaining p-xylene-rich stream of corresponding numbers and p-xylene-poor stream of corresponding numbers, wherein the number n represents arbitrary positive integer equal to or above 2; and (3) subjecting two or more of the first to the n-th p-xylene-rich stream jointly to second separation, thus obtaining p-xylene and first separation residue. The refining method has the advantages of increasing the production of p-xylene, etc.

Description

technical field [0001] The present invention relates to a method for refining hydrocarbons, in particular to a method for refining crude p-xylene. The invention also relates to a corresponding refining system. Background technique [0002] P-xylene is a basic organic chemical product, which is mainly obtained through separation of C8 aromatic hydrocarbons in industry. The so-called C8 aromatics generally refer to ethylbenzene or various isomers of xylene, such as p-xylene, m-xylene and ortho-xylene, but more generally refer to a mixture of two or more of these compounds. The physical and chemical properties of these compounds are similar, and Table 1 reflects the boiling point of each compound at normal pressure. As can be seen from Table 1, the difference between the boiling points of p-xylene and ethylbenzene is 2°C, and the difference between the boiling points of p-xylene and m-xylene is about 1°C. To achieve complete and effective separation between each other, a larg...

Claims

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Application Information

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IPC IPC(8): C07C7/00C07C7/148C07C15/08C07C5/22C07C15/04
CPCC07C7/005C07C7/14808C07C5/22C07C15/08C07C15/04
Inventor 刘建新周立进檀子娟周清池朱伟徐向荣李旭灿孟海
Owner CHINA PETROLEUM & CHEM CORP
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