Aryl ether polymer alloy and preparation method thereof
A polymer and alloy technology, applied in the field of aryl ether polymer alloy and its preparation, can solve the problems of unsatisfactory high temperature rutting resistance and poor cracking resistance, and achieve excellent high temperature rutting resistance and low temperature cracking resistance. Effect
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Embodiment 1
[0025] The polymer alloy, in parts by mass, has a proportioning relationship of: 10 parts of polyarylene sulfide, 30 parts of polystyrene and 97 parts of hydrogenated styrene-butadiene-styrene block copolymer containing extender oil; The polyarylene sulfide is polyphenylene sulfide, the extender oil is naphthenic oil, and the amount of the extender oil is 20% of the mass of the hydrogenated styrene-butadiene-styrene block copolymer.
[0026] The preparation method of described polymer alloy, concrete steps are:
[0027] (1) Put the powdery hydrogenated styrene-butadiene-styrene block copolymer into a horizontal stirring mixer, start stirring, slowly add filler oil, and stir at 25 rpm for 20 minutes; For powdered polyarylene sulfide and polystyrene, continue to stir for 25 minutes at 25 rpm;
[0028] (2) Add the powdery mixture obtained in step (1) into a twin-screw extruder preheated to 195°C, extrude, cool, and granulate to obtain the product.
Embodiment 2
[0030] The polymer alloy, in parts by mass, has a proportioning relationship of: 11 parts of polyarylene sulfide, 20 parts of polystyrene and 96 parts of hydrogenated styrene-butadiene-styrene block copolymer containing extender oil; The polyarylene sulfide is polyarylene sulfide sulfone, the extender oil is furfural oil, and the amount of the extender oil is 10% of the mass of the hydrogenated styrene-butadiene-styrene block copolymer.
[0031] (1) Put the powdery hydrogenated styrene-butadiene-styrene block copolymer into a horizontal stirring mixer, start stirring, slowly add filler oil, stir at 15 rpm for 24 minutes; For powdered polyarylene sulfide and polystyrene, continue to stir for 30 minutes at a speed of 15 rpm;
[0032] (2) Add the powdery mixture obtained in step (1) into a twin-screw extruder preheated to 195°C, extrude, cool, and granulate to obtain the product.
Embodiment 3
[0034] The polymer alloy, in parts by mass, has a proportioning relationship of: 12 parts of polyarylene sulfide, 10 parts of polystyrene and 90 parts of hydrogenated styrene-butadiene-styrene block copolymer containing extender oil; The polyarylene sulfide is polyphenylene sulfide, the extender oil is white mineral oil, and the amount of the extender oil is 5% of the mass of the hydrogenated styrene-butadiene-styrene block copolymer.
[0035] (1) Put the powdery hydrogenated styrene-butadiene-styrene block copolymer into a horizontal stirring mixer, start stirring, slowly add filler oil, and stir for 30 minutes at a speed of 30 rpm; For powdered polyarylene sulfide and polystyrene, continue to stir for 15 minutes at a speed of 30 rpm;
[0036] (2) Add the powdery mixture obtained in step (1) into a twin-screw extruder preheated to 195°C, extrude, cool, and granulate to obtain the product.
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