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Anti-collapse mud-resistant polycarboxylic acid and preparation method thereof

A polycarboxylic acid and anti-mud type technology, applied in the field of concrete, can solve the problems of insufficient cement particle dispersion retention ability, influence on concrete setting time and air content, concrete fluidity and plasticity discount, etc., and achieve strong cement particle dispersion Retention ability, good slump retention ability, effect of reducing bleeding and segregation

Inactive Publication Date: 2019-06-14
JIANGSU BAIRUIJI NEW MATERIAL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] With the vigorous development of my country's infrastructure construction, the performance of all aspects of concrete necessary for infrastructure construction is also constantly improving. At the same time, the requirements for concrete slump-retaining agents are also getting higher and higher. Polycarboxylic acid-based slump-retaining agents are The third-generation high-performance slump-retaining agent has the characteristics of low dosage, high water-reducing rate, small slump loss, and good adaptability to cement. Poor slump protection ability, the preparation process and the use of raw materials cannot meet the requirements of energy conservation and environmental protection, and the ability to maintain the dispersion of cement particles is insufficient, so that the concrete has high content, low water reduction rate, poor reinforcement effect, and insufficient durability. The disadvantages of poor cement dispersibility and low water-reducing rate also directly affect the setting time and air content of concrete, greatly reducing the fluidity and plasticity of concrete, and increasing the bleeding and segregation of concrete, so it can solve such problems. It is imperative to realize the anti-slump and mud-resistant polycarboxylic acid and its preparation method

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] Example 1: Add 250.0 parts of methallyl alcohol polyoxyethylene ether and isopentenyl alcohol polyoxyethylene ether in a four-neck flask with a weight ratio of 1.0:1.0, add 175.0 parts of pure water, and stir at a low speed Until it is completely dissolved, mix 4.0 parts of sodium sulfate, ammonium persulfate and potassium persulfate in a weight ratio of 1.0:1.0:1.0 with 60.0 parts of pure water until the solution is complete. 7.5 parts of methyl diallyl ammonium chloride and 30.0 parts of pure water are mixed to a complete solution, and 1.0 parts of sodium bisulfite, 3.0 parts of mercaptopropionic acid and 70.0 parts of pure water are mixed to a complete solution, and then prepared in step 2 The solution prepared above was added dropwise to the solution at the same time and kept stirring until the heat preservation was completed. Mix 5.0 parts of alkyl sulfonate and alkylbenzene sulfonate in a weight ratio of 1.0:1.0, 10.0 parts of desulfurization gypsum and sulfonate ...

Embodiment 2

[0020] Example 2: Add 280.0 parts of methallyl alcohol polyoxyethylene ether and isopentenyl alcohol polyoxyethylene ether in a four-neck flask with a weight ratio of 1.0:1.0, add 210.0 parts of pure water, and stir at a low speed Until it is completely dissolved, mix 6.0 parts of sodium sulfate, ammonium persulfate and potassium persulfate in a weight ratio of 1.0:1.0:1.0 with 70.0 parts of pure water until the solution is complete. 10.5 parts of methyl diallyl ammonium chloride and 40.0 parts of pure water are mixed to a complete solution, and 1.2 parts of sodium bisulfite, 3.5 parts of mercaptopropionic acid and 80.0 parts of pure water are mixed to a complete solution, and then prepared in step 2 The solution prepared above was added dropwise into the solution at the same time and kept stirring until the heat preservation was completed. Mix 8.0 parts of alkyl sulfonate and alkylbenzene sulfonate in a weight ratio of 1.0:1.0, 15.0 parts of desulfurization gypsum and sulfonat...

Embodiment 3

[0022] Example 3: Add 300.0 parts of a mixture of methallyl alcohol polyoxyethylene ether and isopentenol polyoxyethylene ether in a weight ratio of 1.0:1.0 to a four-neck flask of a certain capacity, add 210.0 parts of pure water, and stir at a low speed Until it is completely dissolved, mix 7.0 parts of sodium sulfate, ammonium persulfate and potassium persulfate in a weight ratio of 1.0:1.0:1.0 with 75.0 parts of pure water until the solution is complete. 15.0 parts of methyl diallyl ammonium chloride and 45.0 parts of pure water are mixed to a complete solution, and 1.5 parts of sodium bisulfite, 4.0 parts of mercaptopropionic acid and 85.0 parts of pure water are mixed to a complete solution. The solution prepared above was added dropwise to the solution at the same time and kept stirring until the heat preservation was completed. Mix 10.0 parts of alkyl sulfonate and alkylbenzene sulfonate in a weight ratio of 1.0:1.0, 20.0 parts of desulfurization gypsum and sulfonate A...

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PUM

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Abstract

The invention provides anti-collapse mud-resistant polycarboxylic acid and a preparation method thereof. The anti-collapse mud-resistant polycarboxylic acid is prepared from the following raw materialingredients in parts by weight: 250.0 to 300.0 parts of macromonomers, 5.0 to 10.0 parts of acrylic acid, 10.0 to 20.0 parts of hydroxypropyl acrylate, 7.5 to 15.0 parts of dimethyl diallyl ammoniumchloride, 1.0 to 1.5 parts of sodium hydrogen sulfite, 3.0 to 4.0 parts of mercaptopropionic acid, 4.0 to 7.0 parts of initiators, 400.0 to 500.0 parts of pure water, 10.0 to 20.0 parts of 30 percentsodium hydroxide, 10.0 to 20.0 parts of flue gas desulfurization gypsum, 5.0 to 10.0 parts of air entraining agents and 10.0 to 15.0 parts of water reducing agents. The anti-collapse mud-resistant polycarboxylic acid and the preparation method thereof have the beneficial effects that heating is not needed in a whole process; energy is saved; environment is protected; higher primary stage water reducing rate and better anti-collapse capability are realized; relatively strong cement particle dispersion maintaining capability is realized, so that concrete has the advantages of low doping quantity, high water reducing rate, good enhancing effect, strong durability and relatively good cement dispersibility; the setting time and gas content of the concrete are not influenced; the flowability andthe plasticity of the concrete can be improved; and the bleeding and separation of the concrete are reduced.

Description

technical field [0001] The invention relates to the technical field of concrete, in particular to a slump-preserving and mud-resistant polycarboxylic acid and a preparation method thereof. Background technique [0002] With the vigorous development of my country's infrastructure construction, the performance of all aspects of concrete necessary for infrastructure construction is also constantly improving. At the same time, the requirements for concrete slump-retaining agents are also getting higher and higher. Polycarboxylic acid-based slump-retaining agents are The third-generation high-performance slump-retaining agent has the characteristics of low dosage, high water-reducing rate, small slump loss, and good adaptability to cement. Poor slump protection ability, the preparation process and the use of raw materials cannot meet the requirements of energy conservation and environmental protection, and the ability to maintain the dispersion of cement particles is insufficient, ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B24/32C08F283/06C08F220/20
Inventor 王亚军卢祎
Owner JIANGSU BAIRUIJI NEW MATERIAL
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