Anti-collapse mud-resistant polycarboxylic acid and preparation method thereof
A polycarboxylic acid and anti-mud type technology, applied in the field of concrete, can solve the problems of insufficient cement particle dispersion retention ability, influence on concrete setting time and air content, concrete fluidity and plasticity discount, etc., and achieve strong cement particle dispersion Retention ability, good slump retention ability, effect of reducing bleeding and segregation
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Embodiment 1
[0018] Example 1: Add 250.0 parts of methallyl alcohol polyoxyethylene ether and isopentenyl alcohol polyoxyethylene ether in a four-neck flask with a weight ratio of 1.0:1.0, add 175.0 parts of pure water, and stir at a low speed Until it is completely dissolved, mix 4.0 parts of sodium sulfate, ammonium persulfate and potassium persulfate in a weight ratio of 1.0:1.0:1.0 with 60.0 parts of pure water until the solution is complete. 7.5 parts of methyl diallyl ammonium chloride and 30.0 parts of pure water are mixed to a complete solution, and 1.0 parts of sodium bisulfite, 3.0 parts of mercaptopropionic acid and 70.0 parts of pure water are mixed to a complete solution, and then prepared in step 2 The solution prepared above was added dropwise to the solution at the same time and kept stirring until the heat preservation was completed. Mix 5.0 parts of alkyl sulfonate and alkylbenzene sulfonate in a weight ratio of 1.0:1.0, 10.0 parts of desulfurization gypsum and sulfonate ...
Embodiment 2
[0020] Example 2: Add 280.0 parts of methallyl alcohol polyoxyethylene ether and isopentenyl alcohol polyoxyethylene ether in a four-neck flask with a weight ratio of 1.0:1.0, add 210.0 parts of pure water, and stir at a low speed Until it is completely dissolved, mix 6.0 parts of sodium sulfate, ammonium persulfate and potassium persulfate in a weight ratio of 1.0:1.0:1.0 with 70.0 parts of pure water until the solution is complete. 10.5 parts of methyl diallyl ammonium chloride and 40.0 parts of pure water are mixed to a complete solution, and 1.2 parts of sodium bisulfite, 3.5 parts of mercaptopropionic acid and 80.0 parts of pure water are mixed to a complete solution, and then prepared in step 2 The solution prepared above was added dropwise into the solution at the same time and kept stirring until the heat preservation was completed. Mix 8.0 parts of alkyl sulfonate and alkylbenzene sulfonate in a weight ratio of 1.0:1.0, 15.0 parts of desulfurization gypsum and sulfonat...
Embodiment 3
[0022] Example 3: Add 300.0 parts of a mixture of methallyl alcohol polyoxyethylene ether and isopentenol polyoxyethylene ether in a weight ratio of 1.0:1.0 to a four-neck flask of a certain capacity, add 210.0 parts of pure water, and stir at a low speed Until it is completely dissolved, mix 7.0 parts of sodium sulfate, ammonium persulfate and potassium persulfate in a weight ratio of 1.0:1.0:1.0 with 75.0 parts of pure water until the solution is complete. 15.0 parts of methyl diallyl ammonium chloride and 45.0 parts of pure water are mixed to a complete solution, and 1.5 parts of sodium bisulfite, 4.0 parts of mercaptopropionic acid and 85.0 parts of pure water are mixed to a complete solution. The solution prepared above was added dropwise to the solution at the same time and kept stirring until the heat preservation was completed. Mix 10.0 parts of alkyl sulfonate and alkylbenzene sulfonate in a weight ratio of 1.0:1.0, 20.0 parts of desulfurization gypsum and sulfonate A...
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