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Preparation process of formed foil

A preparation process and technology of forming foil, which is applied in the direction of anodic oxidation, electrolytic coating, surface reaction electrolytic coating, etc., can solve the problems of poor water resistance, other performance effects, increased concentration, etc., and achieve high formation efficiency and water resistance Effects of performance change and improvement of formation efficiency

Inactive Publication Date: 2019-06-07
CENT SOUTH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] Chinese patent literature (publication number: CN107799313A) discloses a chemical formation foil and its production process. The formation foil production process includes steps such as aluminum foil pretreatment, first to third-level formation, baking, four-level formation, curing, and drying. The chemical formation solutions obtained are all boric acid solutions, and the first to fourth grade chemical formation liquids all have a certain temperature, and their concentration gradually increases; the chemical formation is carried out in a direct current electric field, solidified in ammonium dihydrogen phosphate solution or ammonium dihydrogen phosphate and ammonium dihydrogen phosphate Phosphoric acid mixed solution; the forming foil process technology is environmentally friendly, but the water resistance is not very good, still needs further improvement
[0004] Chinese patent document (publication number: CN101425395A) discloses a manufacturing method of low-voltage, high-dielectric chemical forming foil for aluminum electrolytic capacitors, preparing sol-gel liquid, conducting direct current chemical forming treatment to form chemical forming foil, air-drying in air, heating and decomposing to remove organic matter and generate a high dielectric composite oxide film, the method has low cost and high efficiency; the method uses a sol-gel method to make a stable and uniformly dispersed colloid, and the colloid is attached to the surface of the foil foil. Although the foil electrostatic capacity is improved, However, the water resistance is still poor. For a long time, other properties will also be affected.

Method used

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Examples

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Comparison scheme
Effect test

Embodiment 1

[0023] A preparation process of a chemically formed foil in this embodiment includes the following steps:

[0024] Step 1, aluminum foil pretreatment: put the aluminum foil in water at 100°C for 1 hour, then put it in salt solution for 20 minutes, then activate it, then wash it repeatedly with deionized water once, and then send it to the drying box Dry at 60°C for 30 minutes and set aside;

[0025] Step 2: Put the aluminum foil spared in Step 1 into the first-level chemical formation solution, then put it into the secondary chemical formation solution, and then pass through the DC battery. The DC battery voltage is 100V, and the formation time is 10 minutes, and then undergo preheating treatment 20 minutes, then add ammonium dihydrogen phosphate solidification solution to solidify for 8 minutes, and then dry in a 100°C drying oven for 1 hour.

[0026] The salt solution of this embodiment is a sodium chloride solution with a mass fraction of 40%.

[0027] In the activation t...

Embodiment 2

[0033] A preparation process of a chemically formed foil in this embodiment includes the following steps:

[0034] Step 1, aluminum foil pretreatment: put the aluminum foil in water at 100°C for 2 hours, then put it in salt solution for 30 minutes, then activate it, and then wash it repeatedly with deionized water for 3 times, then put it into the drying box Dry at 70°C for 40 minutes and set aside;

[0035] Step 2: Put the aluminum foil spared in Step 1 into the first-level chemical formation solution, then put it into the secondary chemical formation solution, and then pass it through a DC battery. The voltage of the DC battery is 200V, and the formation time is 15 minutes, and then it is preheated. After 30 minutes, add ammonium dihydrogen phosphate solidification solution to solidify for 12 minutes, and then dry in a 120°C drying oven for 2 hours.

[0036] The salt solution in this embodiment is a sodium chloride solution with a mass fraction of 50%.

[0037] In the acti...

Embodiment 3

[0043] A preparation process of a chemically formed foil in this embodiment includes the following steps:

[0044] Step 1, aluminum foil pretreatment: put the aluminum foil in water at 100°C for 1.5 hours, then put it in salt solution for 25 minutes, then activate it, then wash it twice with deionized water, and then send it to the drying box Dry at 65°C for 35 minutes and set aside;

[0045] Step 2: Put the aluminum foil spared in Step 1 into the first-level chemical formation solution, then put it into the secondary chemical formation solution, and then pass through the DC battery. The DC battery voltage is 150V, and the formation time is 12.5 minutes, and then preheated Treat for 25 minutes, then add ammonium dihydrogen phosphate solidification solution to solidify for 10 minutes, and then dry in a 110°C drying oven for 1.5 hours.

[0046] The salt solution of the present embodiment is a sodium chloride solution with a mass fraction of 45%.

[0047] In the activation trea...

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Abstract

The invention relates to the technical field of formed foils, in particular to a preparation process of a formed foil. The preparation process comprises the following steps: S1, pre-treatment of an aluminum foil: first putting the aluminum foil in water at 100 DEG C to be left to stand for 1-2 hours; then sending the aluminum foil to a saline liquid to be treated for 20-30 min and the activating the aluminum foil; then repeatedly washing the aluminum foil with deionized water for 1-3 times; and then sending the aluminum foil to a drying box to be dried for 30-40 min at 60-70 DEG C for later use. By putting the aluminum foil in water at 100 DEG C to be left to stand for 1-2 hours and activating the aluminum foil, so that a formed liquid of the aluminum foil is more easily to react, and thecost is saved. Meanwhile, the formation efficiency is high. Compared with the prior art, the aluminum foil which is activated is better in water resistance and is more convenient for follow-up treatment.

Description

technical field [0001] The invention relates to the technical field of formed foil, in particular to a preparation process of formed foil. Background technique [0002] Formed foil is the product of special high-purity aluminum foil after electrochemical or chemical corrosion to expand the surface area, and then forms a layer of oxide film (aluminum oxide) on the surface through electrochemical formation. According to voltage, chemically formed aluminum foil is generally divided into There are four kinds of extremely low voltage, low voltage, medium and high voltage and high voltage, according to the thickness, ranging from 25-110 microns; according to the use, there are positive foil and negative foil, and there are also guide foils. High-voltage anode foil can be divided into two categories, one is high-quality High-voltage foil, one type is ordinary high-voltage foil, and the negative electrode foil is also divided into soft state and hard state. Japan mainly uses soft st...

Claims

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Application Information

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IPC IPC(8): C25D11/16C25D11/08C25D11/24
Inventor 贾明李立祥艾燕殷宝华刘宇
Owner CENT SOUTH UNIV
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