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Anti-microbial coating prepared from photon up-conversion material and preparation method thereof

A photon up-conversion and antibacterial coating technology, applied in the direction of luminescent materials, coatings, chemical instruments and methods, etc., can solve the problems of low ultraviolet light intensity and limit the application of titanium dioxide

Inactive Publication Date: 2019-03-01
HONG KONG PRODUCTIVITY COUNCIL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the indoor ultraviolet light intensity is generally low, and an additional ultraviolet light lamp must be installed to exert the function of titanium dioxide, which undoubtedly limits the application of titanium dioxide.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0049] The present embodiment provides a kind of preparation method of antibacterial coating, comprises the following steps:

[0050] (1) Up-conversion material NaYF 4 : Yb 3+ , Er 3+ Synthesis

[0051] Mix 12 mL of yttrium nitrate, 20 mL of ytterbium nitrate and 9 mL of erbium nitrate together and keep stirring for 30 minutes, wherein the concentration of yttrium nitrate is 0.2 mol / L, the concentration of ytterbium nitrate is 0.01 mol / L, and the concentration of erbium nitrate is 0.01 mol / L; 20 mL of sodium nitrate with a concentration of 2 mol / L was added to the obtained mixture, and continued stirring for 30 minutes; then, 30 mL of ammonium fluoride with a concentration of 2 mol / L was added to the mixture obtained through the previous step, and continued Stir for 15 minutes; add 0.05mol / L ethylenediammonium tetraacetic acid to the above mixture as a stabilizer, the volume of addition is 20mL, and continue stirring for 40 minutes; put the mixture obtained in the previous ...

Embodiment 2

[0057] The present embodiment provides a kind of preparation method of antibacterial coating, comprises the following steps:

[0058] (1) Up-conversion material NaYF 4 : Yb 3+ , Er 3+ Synthesis

[0059] Mix 12 mL of yttrium nitrate, 20 mL of ytterbium nitrate and 9 mL of erbium nitrate together and keep stirring for 30 minutes, wherein the concentration of yttrium nitrate is 0.5 mol / L, the concentration of ytterbium nitrate is 0.1 mol / L, and the concentration of erbium nitrate is 0.01 mol / L; 20 mL of sodium nitrate with a concentration of 2 mol / L was added to the obtained mixture, and continued stirring for 30 minutes; then, 30 mL of ammonium fluoride with a concentration of 2 mol / L was added to the mixture obtained through the previous step, and continued Stir for 15 minutes; add 0.5mol / L ethylenediammonium tetraacetic acid to the above mixture as a stabilizer, and add a volume of 10mL, and continue stirring for 40 minutes; put the mixture obtained in the previous step int...

Embodiment 3

[0065] The present embodiment provides a kind of preparation method of antibacterial coating, comprises the following steps:

[0066] (1) Up-conversion material NaYF 4 : Yb 3+ , Er 3+ Synthesis

[0067] Mix 12mL of yttrium nitrate, 20mL of ytterbium nitrate and 9mL of erbium nitrate together and keep stirring for 30 minutes, wherein the concentration of yttrium nitrate is 0.3mol / L, the concentration of ytterbium nitrate is 0.03mol / L, and the concentration of erbium nitrate is 0.01 mol / L; Add 20 mL of sodium nitrate with a concentration of 2 mol / L to the resulting mixture, and continue to stir for 30 minutes; then, add 25 mL of ammonium fluoride with a concentration of 2 mol / L to the above mixture, and continue to stir for 15 minutes; Add 0.4mol / L ethylenediammonium tetraacetic acid as a stabilizer to the above mixture, the added volume is 10mL, and keep stirring for 40 minutes; put the mixture obtained in the previous step into the autoclave, and seal the autoclave , maint...

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PUM

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Abstract

The invention discloses an anti-microbial coating prepared from a photon up-conversion material. The anti-microbial coating contains a photocatalyst TiO2 and an up-conversion material NaYF4:Yb3+, Er3;a heterogeneous structure is formed between TiO2 and NaYF4:Yb3+, Er3; a transparent coating prepared through a sol-gel process is arranged on the titanium dioxide-doped up-conversion material NaYF4:Yb3+, Er3. The invention also provides a preparation method for the anti-microbial coating. The preparation method comprises the following steps: (1) compounding the up-conversion material NaYF4:Yb3+,Er3; (2) compounding the titanium dioxide-doped up-conversion material NaYF4:Yb3+, Er3; (3) compounding a sol-gel coating. The anti-microbial coating disclosed by the invention can take effect under the condition of ordinary illumination and can avoid harm of ultraviolet light to human and livestock.

Description

technical field [0001] The invention relates to the technical field of antibacterial coatings, in particular to an antibacterial coating prepared by using a photon up-conversion material and a preparation method thereof. Background technique [0002] In the public transportation and medical systems of big cities, public health and environmental cleanliness are always issues of concern to the public and cannot be underestimated. Not only pollutants will exist in the air, but bacteria and viruses can also spread through various surfaces as media (such as: door handles, handrails, faucets and elevator buttons, etc.). At present, one of the most commonly used solutions for surface disinfection and pollutant treatment is deposition of photocatalytic coating (PCC), which is to coat the surface of the object with a coating with photocatalytic oxidation properties to oxidize the pollution in the air objects and eliminate microorganisms on objects. [0003] At present, a relatively...

Claims

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Application Information

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IPC IPC(8): C09D5/14C09D183/08C09D7/61C09K11/85
CPCC08K2003/2241C09D5/14C09D183/08C09K11/7773C09D7/61C08K3/22C08K3/16
Inventor 卢伟贤易敏龙谢贵麟潘志豪
Owner HONG KONG PRODUCTIVITY COUNCIL
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