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A modified cement engineering material with waterproof and anti-crack performance

An engineering material and cement technology, applied in the field of new functional materials, can solve the problems of water resistance, weak corrosion resistance, poor elongation, poor durability, etc., and achieve the effect of improving waterproof and corrosion resistance, reducing porosity and strong weather resistance.

Active Publication Date: 2020-12-15
温州合众混凝土有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] As a representative of commonly used building materials, cement has good constructability and excellent compressive strength. However, as the requirements for engineering materials become higher and higher, the shortcomings of cement are enlarged, such as poor brittleness, high self-weight, and easy construction after construction. Cracking, poor elongation, poor durability, water resistance, weak corrosion resistance and other shortcomings limit the application of cement in engineering materials

Method used

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  • A modified cement engineering material with waterproof and anti-crack performance

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Effect test

Embodiment 1

[0018] A modified cement engineering material with waterproof and anti-crack performance, which is made of the following components in parts by weight: 340 parts of cement, 15 parts of ammonium dihydrogen phosphate solution, 7.5 parts of polyethylene glycol, 2.0 parts of modifier, sulfuric acid 0.45 part of magnesium, 0.35 part of emulsifier, 0.25 part of solidifying agent, 0.15 part of defoamer, 200 parts of water; the preparation method of described modifying agent comprises the following steps:

[0019] (1) Add 35 ml of glycerin and 0.6 g of boron trifluoride to the three-necked flask, stir and mix for 30 minutes, then heat in a water bath to 70°C, add 28 g of epichlorohydrin dropwise to the flask, and control the dropping rate to 1.2 g / Minutes, after the dropwise addition, stir and react at a speed of 400 rpm for 55 minutes to obtain a viscous liquid, cool down to 60°C, add sodium carbonate solution to adjust the pH value in the range of 7.5-7.6, add 35 ml of absolute etha...

Embodiment 2

[0027] A modified cement engineering material with waterproof and anti-crack performance, which is made of the following components in parts by weight: 345 parts of cement, 16 parts of ammonium dihydrogen phosphate solution, 7.8 parts of polyethylene glycol, 2.2 parts of modifier, sulfuric acid 0.48 part of magnesium, 0.37 part of emulsifier, 0.28 part of solidifying agent, 0.18 part of defoamer, 205 parts of water; the preparation method of described modifying agent comprises the following steps:

[0028] (1) Add 38 ml of glycerin and 0.65 g of boron trifluoride to the three-necked flask, stir and mix for 35 minutes, then heat in a water bath to 72°C, add 29 g of epichlorohydrin dropwise to the flask, and control the dropping rate to 1.25 g / Minutes, after the dropwise addition, stir and react at a speed of 450 rpm for 58 minutes to obtain a viscous liquid, cool to 62°C, add sodium carbonate solution to adjust the pH value in the range of 7.5-7.6, add 38 ml of absolute ethanol...

Embodiment 3

[0036]A modified cement engineering material with waterproof and anti-crack performance, which is made of the following components in parts by weight: 350 parts of cement, 18 parts of ammonium dihydrogen phosphate solution, 8.0 parts of polyethylene glycol, 2.4 parts of modifier, sulfuric acid 0.50 part of magnesium, 0.38 part of emulsifier, 0.30 part of solidifying agent, 0.20 part of defoamer, 210 parts of water; the preparation method of described modifying agent comprises the following steps:

[0037] (1) Add 40 ml of glycerin and 0.7 g of boron trifluoride to a three-necked flask, stir and mix for 40 minutes, then heat in a water bath to 75°C, add 30 g of epichlorohydrin dropwise to the flask, and control the dropping rate to 1.3 g / Minutes, after the dropwise addition, stir and react at a speed of 500 rpm for 60 minutes to obtain a viscous liquid, cool down to 65°C, add sodium carbonate solution to adjust the pH value in the range of 7.5-7.6, add 40 ml of absolute ethanol...

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Abstract

The invention relates to the technical field of novel functional materials, and discloses a modified cement engineering material having waterproof and anti-cracking properties. The material is prepared from, by weight, 340-350 parts of cement, 15-18 parts of an ammonium dihydrogen phosphate solution, 7.5-8.0 parts of polyethylene glycol, 2.0-2.4 parts of a modifier, 0.45-0.50 part of magnesium sulfate, 0.35-0.38 part of an emulsifier, 0.25-0.30 part of a curing agent, 0.15-0.20 part of a defoamer and 200-210 parts of water. The modifier is added in a cement hydration reaction to achieve crosslinking and curing to form a film, a network structure is formed by utilizing the modifier, and gaps of cement particles are filled so that the prepared material has stable physical and chemical structures, improvement effects are not influenced by outer environment, a cement structure is more compact and crack formation is prevented. Compared with present cement products, the material is significantly improved in waterproof and corrosion resistant properties and obviously reduced in porosity.

Description

technical field [0001] The invention belongs to the technical field of new functional materials, and in particular relates to a modified cement engineering material with waterproof and anti-crack performance. Background technique [0002] In 1756, British engineer J. Smeaton discovered when studying the characteristics of some lime hardening in water: to obtain hydraulic lime, limestone containing clay must be used for firing; The ideal composition is composed of hydraulic lime and volcanic ash. This important discovery laid a theoretical foundation for the research and development of modern cement. [0003] Cement is a powdery hydraulic inorganic gelling material. After adding water and stirring, it becomes a slurry, which can be hardened in the air or better hardened in water, and can firmly bind sand, stone and other materials together. In the early years the mixture of lime and volcanic ash is very similar to lime pozzolanic cement, use it to glue concrete which made ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B28/00C04B111/20C04B111/23C04B111/27
CPCC04B28/00C04B2111/20C04B2111/23C04B2111/27C04B2201/50C04B22/16C04B24/32C04B22/142C04B24/02C04B24/121C04B24/281C04B2103/0068C04B2103/50
Inventor 邹浩谦金琼瑶郭平
Owner 温州合众混凝土有限公司
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