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Preparation method of graphene-toughened-resin-based carbon fiber composite

A technology for toughening resins and composite materials, applied in the field of composite materials, can solve the problems of easy agglomeration, affecting the performance of composite materials, uneven dispersion of graphene, etc., to improve strength and toughness, improve dispersion, and improve conjugation. Effect

Inactive Publication Date: 2018-11-20
SHANGHAI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the existence of π-π bonds and large van der Waals forces between graphenes, graphene is prone to agglomeration when it is used as a reinforcement phase of composite materials, which makes the dispersion of graphene in the prepared composite materials uneven, which seriously affects the composite material. Material properties

Method used

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  • Preparation method of graphene-toughened-resin-based carbon fiber composite
  • Preparation method of graphene-toughened-resin-based carbon fiber composite

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Embodiment 1

[0040] Please join the attached figure 1 , 2, 3, 4, a preparation method of graphene toughened resin-based carbon fiber composite material, first graphene and low-viscosity reactive dispersant are ultrasonically dispersed to prepare graphene dispersion, and then the dispersion is mixed with resin Mix and prepare a certain concentration of toughening resin, and then adopt the preparation process of carbon fiber prepreg, prepare graphene toughened carbon fiber prepreg through continuous impregnation and drying, and prepare the required carbon fiber prepreg through laying, molding and curing. Graphene toughened resin-based carbon fiber composite material; its specific steps are as follows:

[0041] Step 1: Preparation of pre-product

[0042] In a nitrogen atmosphere, take tetramethylcyclotetrasiloxane and styrene as raw materials, control the molar ratio of tetramethylcyclotetrasiloxane and styrene to be 1: 2.15, and use the isopropanol solution of chloroplatinic acid as Cataly...

Embodiment 2

[0070] A method for preparing a graphene-toughened resin-based carbon fiber composite material. First, graphene and a low-viscosity reactive dispersant are ultrasonically dispersed to prepare a graphene dispersion, and then the dispersion is mixed with a resin to prepare a certain concentration. Toughening resin, and then using the preparation process of carbon fiber prepreg, the graphene toughened carbon fiber prepreg is prepared by continuous impregnation and drying, and the required graphene toughened resin based carbon fiber is prepared by laying, molding and curing Composite material; its specific steps are as follows:

[0071] Step 1: Preparation of pre-product

[0072] In a nitrogen atmosphere, take tetramethylcyclotetrasiloxane and styrene as raw materials, control the molar ratio of tetramethylcyclotetrasiloxane and styrene to be 1: 2.20, and use the isopropanol solution of chloroplatinic acid as Catalyst: Mix the catalyst and styrene to prepare styrene catalytic liq...

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Abstract

The invention relates to a preparation method of a graphene-toughened-resin-based carbon fiber composite. According to the method, firstly, graphene and a low-viscosity reactive dispersing agent are subjected to ultrasonic dispersion, a graphene dispersing solution is prepared and then is mixed with resin, toughened resin in certain concentration is formed through mixing, then graphene-toughened carbon fiber prepreg is prepared through continuous impregnation and drying with the carbon fiber prepreg preparation technology, and the required graphene-toughened-resin-based carbon fiber compositeis prepared through laying, mold pressing and solidifying. The graphene-toughened-resin-based carbon fiber composite is high in toughness, the graphene dispersion performance is good, the structure iscomplete, the dispersing agent has the low viscosity and the characteristic of capability of cross-linking reaction, so that graphene can enter the space among carbon fiber bundles along with the resin, the binding force among the fibers can be increased, and the method is widely applied in the field of reinforced resin composites.

Description

【Technical field】 [0001] The invention relates to the field of composite materials. The intercalation effect of graphene is utilized, and the low viscosity and reactivity characteristics of the dispersant are used to allow graphene to infiltrate between carbon fiber fibers, thereby improving the strength of the composite material, especially the effect of toughening, specifically In other words, it is a preparation method of graphene toughened resin-based carbon fiber composite material. 【Background technique】 [0002] Graphene is a carbon atom sp 2 Composed of hybrid orbitals, the hexagonal honeycomb lattice planar film has a thickness of only 0.334nm, and the quasi-two-dimensional planar crystal structure of graphene with only one atom thickness and the in-plane conjugated π electron system make graphene have excellent properties. Electrical, thermal and mechanical properties. However, due to the existence of π-π bonds and large van der Waals forces between graphenes, gr...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L63/00C08L77/00C08L67/00C08L69/00C08K7/06C08K3/04C08J5/04C08G77/38C08G77/06C08G77/04
CPCC08G77/04C08G77/06C08G77/38C08G77/80C08J5/042C08J2363/00C08J2367/00C08J2369/00C08J2377/00C08K3/042
Inventor 刘立起李爱军彭雨晴张方舟张亚萍石磊
Owner SHANGHAI UNIV
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