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A kind of halogen-free black sand and preparation method thereof

A black and carbon black technology, which is applied in the field of halogen-free black sand and its preparation, can solve the problems of poor thermal stability and coloring ability, poor pigment dispersion and fluidity, poor dispersion of color points and color lines, etc., to reduce the number of workshops Site pollution, enhanced blackness and brightness, and good fluidity

Active Publication Date: 2020-06-19
东莞市从墨塑胶材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Today's black sand generally has poor dispersion of color points and color lines, and its pigment dispersion and fluidity are poor, thermal stability and coloring ability are also poor, so that the performance of the plastic will be reduced after adding it to the plastic.
At the same time, due to the small size of carbon black particles, most manufacturers use simple open machines to operate in the process of processing in order to save costs, resulting in relatively large carbon black dust pollution. These problems need to be solved urgently

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] A kind of halogen-free black sand, the weight ratio of each component is:

[0029] Carbon black: 30%; Montan wax: 15%; Diatomaceous earth: 30%; Epoxy soybean oil: 5%; Fatty alcohol polyoxyethylene ether: 7%; Polyammonium polyphosphate: 3%; Fatty acid calcium salt: 5% %; inorganic salt copper sulfate: 0.5%; coupling agent: 4.5%.

[0030] Preferably, the average particle size of carbon black is 30 μm.

[0031] Preferably, the coupling agent is a silane coupling agent.

[0032] A kind of halogen-free black sand, comprises the following steps:

[0033] a Weigh the raw materials according to the formula and set aside;

[0034] b. Put the raw materials of the above formula into the internal mixer successively and banbury for 20 minutes. The banbury process is to stir the raw materials for 5 minutes and then pressurize for 10 to 20 minutes to obtain the mixture. The pressure value set in the pressurization process is 500~1500KN;

[0035] c Transfer the mixture to a three-...

Embodiment 2

[0039] A kind of halogen-free black sand, the weight ratio of each component is:

[0040] Carbon black: 35%; Montan wax: 15%; Diatomaceous earth: 25%; Epoxy soybean oil: 5%; Fatty alcohol polyoxyethylene ether: 7%; Polyammonium polyphosphate: 3%; Fatty acid calcium salt: 5% %; inorganic salt copper sulfate: 0.5%; coupling agent: 4.5%.

[0041] Preferably, the average particle size of carbon black is 30 μm.

[0042] Preferably, the coupling agent is a silane coupling agent.

[0043] A preparation method of halogen-free black sand, comprising the following steps:

[0044] a Weigh the raw materials according to the formula and set aside;

[0045] b. Put the raw materials of the above formula into the internal mixer successively and banbury for 20 minutes. The banbury process is to stir the raw materials for 5 minutes and then pressurize for 10 to 20 minutes to obtain the mixture. The pressure value set in the pressurization process is 500~1500KN;

[0046] c Transfer the mixt...

Embodiment 3

[0050] A kind of halogen-free black sand, the weight ratio of each component is:

[0051] Carbon black: 45%; Montan wax: 5%; Diatomaceous earth: 25%; Epoxidized soybean oil: 5%; Fatty alcohol polyoxyethylene ether: 7%; Polyammonium polyphosphate: 3%; Fatty acid calcium salt: 5% %; inorganic salt copper sulfate: 0.5%; coupling agent: 4.5%.

[0052] Preferably, the average particle size of carbon black is 30 μm.

[0053] Preferably, the coupling agent is a silane coupling agent.

[0054] A preparation method of halogen-free black sand, comprising the following steps:

[0055] a Weigh the raw materials according to the formula and set aside;

[0056] b. Put the raw materials of the above formula into the internal mixer successively and banbury for 20 minutes. The banbury process is to stir the raw materials for 5 minutes and then pressurize for 10 to 20 minutes to obtain the mixture. The pressure value set in the pressurization process is 500~1500KN;

[0057] c Transfer the ...

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Abstract

The invention provides halogen-free black sand and a preparation method thereof. The halogen-free black sand is prepared from the following ingredients in percentage by weight: 30 to 50 percent of carbon black, 5 to 15 percent of lignite wax, 25 to 40 percent of diatomite, 5 to 10 percent of epoxidized soybean oil, 3 to 7 percent of fatty alcohol-polyoxyethylene ether, 3 to 5 percent of ammonium polyphosphate, 2 to 5 percent of fatty acid calcium salt, 0.1 to 0.5 percent of inorganic salt copper sulfate and 3 to 5 percent of coupling agents. A preparation process comprises the following stepsof sequentially adding formula raw materials into an internal mixer to be mixed for 20 minutes; obtaining a pre-finished product after the heating and grinding; transferring the pre-finished product into a butterfly type low-speed stirring machine for shearing and shaping the pre-finished product; obtaining a particular primary finished product of the black sand; filtering the particular primary finished product of the black sand to obtain a finished product. The black slurry produced by the method has the advantages of color spreading performance, high coloring capability and good flowability; the blackness degree and the brightness degree of the plastic products can be enhanced; a halogen-free and environment-friendly formula is used; phenomena of color spots, poor color vein dispersionand the like cannot occur; in the processing process, the mixing is firstly performed, and then, the grinding is repeatedly performed for three times, so that the carbon black, plasticizers and the like are uniformly scattered; the obtained black sand has the uniformly scattered color and luster and pigment figure.

Description

technical field [0001] The invention relates to the technical field of pigment dyes, in particular to a halogen-free black sand and a preparation method thereof. Background technique [0002] In the process of PVC plastic processing, in order to improve the stability, solid content, color, etc. of the plastic, it is necessary to add some additives in the molding process to change the performance of the plastic. Colored sand is usually composed of colorant, carrier, dispersant and other additives. When processing, a small amount of colored sand is mixed with colored resin to design products with different colors and properties. The use of colored sand can avoid problems caused by weighing accuracy, uneven mixing, and dust pollution when adding colored pigments. [0003] Carbon black is widely used in plastics due to its excellent colorability and heat resistance, as well as its excellent chemical stability. Black sand is a post-processed product of carbon black. Because bla...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L91/06C08L91/00C08L71/02C08K13/02C08K3/04C08K3/34C08K3/32C08K5/098C08K3/30C08J3/20
CPCC08J3/20C08J2300/00C08J2471/02C08J2491/00C08J2491/06C08K3/04C08K3/32C08K3/34C08K5/098C08K13/02C08K2003/3045C08K2201/003
Inventor 周宇
Owner 东莞市从墨塑胶材料有限公司
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