CNT/three-dimensional grapheme composite material, preparation method and application thereof
A technology of carbon nanotubes and composite materials, applied in the field of supercapacitor preparation, can solve the problems of reducing the load of electrochemical active materials, limiting the application of electrodes, complex processes, etc., and achieves low cost, high working stability and simple preparation method. Effect
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[0039] The embodiment of the present application provides a method for preparing a carbon nanotube / three-dimensional graphene composite material including:
[0040] A three-dimensional graphene airgel is provided, and at least the surface of the three-dimensional graphene airgel and the inner walls of the holes contained are loaded with catalytically active metal ions;
[0041] The three-dimensional graphene airgel is placed in a chemical vapor growth equipment, and a non-ionic polymer compound is used as a carbon source, and carbon nanotubes are grown on the surface and inside of the three-dimensional graphene airgel by chemical vapor deposition , preparing the carbon nanotube / three-dimensional graphene composite material.
[0042] In some preferred embodiments, the preparation method includes:
[0043] The carbon source and the three-dimensional graphene airgel are respectively placed in the first area and the second area in the chemical vapor growth equipment, and the firs...
Embodiment 1
[0086] Firstly, three-dimensional graphene airgel is prepared, and the steps include:
[0087] Nickel acetate (Ni(AC) 2 ) and graphene aqueous solution (GO) and according to different mass ratios (m Ni / m GO =1wt%, 2wt%, 3wt%) were ultrasonically mixed, and then a three-dimensional graphene hydrogel was obtained by hydrothermal synthesis (100°C, 5h).
[0088] The aforementioned three-dimensional graphene hydrogel was freeze-dried at -30° C. and 2 Pa for 6 hours to obtain a three-dimensional graphene aerogel.
[0089] Using polyvinylpyrrolidone (PVP) as a solid carbon source, put the carbon source and the three-dimensional graphene airgel into the quartz tube of the chemical vapor phase growth equipment respectively, and make the distance between the two about 5-10cm, and pass through the tube before the reaction starts. Enter the carrier gas (10-30min) to remove the air in the growth equipment and keep the airflow at the same speed (about 10-30sccm) throughout the reaction ...
Embodiment 2
[0094] Firstly, the airgel of three-dimensional graphene is prepared, and the specific steps are as follows:
[0095] Nickel acetate (Ni(AC) 2 ) and graphene aqueous solution (GO) and according to different mass ratios (m Ni / m GO =4wt%, 6wt%, 8wt%) were ultrasonically mixed, and then the three-dimensional graphene hydrogel was obtained by hydrothermal synthesis (120°C, 8h).
[0096] The aforementioned three-dimensional graphene hydrogel was freeze-dried at -10° C. and 5 Pa for 8 hours to obtain a three-dimensional graphene aerogel.
[0097] Using polyvinylpyrrolidone (PVP) as a solid carbon source, put the carbon source and the three-dimensional graphene airgel into the quartz tube of the chemical vapor phase growth equipment respectively, and make the distance between the two about 5-10cm, and pass through the tube before the reaction starts. Enter the carrier gas (10-30min) to remove the air in the growth equipment and keep the airflow at the same speed (about 10-30sccm) t...
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