Spherical carrier and olefin polymerization catalyst, preparation method and application thereof, and olefin polymerization method
A spherical carrier, olefin polymerization technology, applied in the field of olefin polymerization, can solve the problems of poor propylene polymerization performance and easily broken catalyst
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[0045] In a second aspect, the present invention provides a method for preparing a spherical carrier, wherein the method includes the following steps:
[0046] (1) The general formula is MgR m x 2-m A magnesium compound, an inorganic oxide and / or an inorganic oxide precursor, a diether compound and an electron donor solvent are mixed to prepare a slurry;
[0047] (2) In an inert atmosphere, the slurry obtained in step (1) is spray-dried to obtain a spherical carrier;
[0048] Wherein, X is halogen, R is selected from C 1 -C 14 Alkyl, C 1 -C 14 Alkoxyl, C 6 -C 14 Aryl or C 6 -C 14 A group consisting of aryloxy groups, m is an integer of 0-2.
[0049] In the present invention, in step (1), the inorganic oxide may be silicon oxide and / or aluminum oxide, preferably silicon oxide, more preferably silicon dioxide. The inorganic oxide precursor may be silica sol and / or aluminum sol, preferably silica sol.
[0050] In the present invention, in step (1), the halogen element...
Embodiment 1
[0102] This example is used to illustrate the preparation of the spherical carrier and olefin polymerization catalyst and the method of olefin polymerization in the present invention.
[0103] 1. Vector preparation
[0104] Add 9.5 g (0.1 mol) of magnesium chloride and 58 mL (1 mol) of ethanol into a stirred 500 mL glass reactor fully replaced by nitrogen, raise the temperature to 70° C. and keep for 1 h. The temperature was lowered to 0° C., then raised to 70° C., and 0.8 mL (0.003 mol) of 2-isopentyl-2-isopropyl-1,3-dimethoxypropane was added during the temperature rise. Maintained at 70°C for 2h, then lowered to 40°C and added 3.5g of silica gel, maintained at 40°C for 2h to obtain a slurry. The slurry was spray-dried, and the spray-drying conditions were: the inlet temperature was 200°C, and the outlet temperature was 103°C. The spherical carrier Z1 was prepared, and it was found that Z1 was basically spherical by optical microscope observation, and the results were as f...
Embodiment 2
[0112] This example is used to illustrate the preparation of the spherical carrier and olefin polymerization catalyst and the method of olefin polymerization in the present invention.
[0113] 1. Vector preparation
[0114] Add 9.5 g (0.1 mol) of magnesium chloride and 46 mL (0.79 mol) of ethanol into a stirred 500 mL glass reactor fully replaced by nitrogen, raise the temperature to 70° C. and keep for 1 h. The temperature was lowered to 0° C., then raised to 70° C., and 0.5 mL (0.002 mol) of 2-isopentyl-2-isopropyl-1,3-dimethoxypropane was added during the temperature rise. Maintained at 70°C for 2h, then lowered to 40°C and added 2.8g of silica gel, maintained at 40°C for 2h to obtain a slurry. The slurry was spray-dried, and the spray-drying conditions were as follows: the inlet temperature was 200°C, and the outlet temperature was 107°C. The spherical carrier Z2 was prepared, and observed by an optical microscope, it was found that Z2 was basically spherical.
[0115] ...
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