High-performance fluorosilicone modified finish-coat paint
A technology of fluorosilicon modification and finishing paint, which is applied in the direction of biocide-containing paint, antifouling/underwater paint, coating, etc. Whitening and other problems, to achieve good dispersion, strong adhesion, improve the effect of adhesion
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Embodiment 1
[0031] A high-performance fluorosilicon-modified finish paint, the preparation method of the fluorosilicon-modified acrylate is the preparation of isooctyl methacrylate, acrylic acid, tetrafluoropropyl methacrylate, polyoxyethylene octylphenol ether OP -10. Mix sodium dodecylbenzenesulfonate and deionized water evenly, add dicumyl peroxide, heat up to 80°C, keep warm for 8 minutes, then add disodium ethoxylated alcohol sulfosuccinate and acrylamide formaldehyde Sodium propane sulfonate was mixed evenly, cooled to 30°C, then added ammonia water to adjust the pH of the system to 7, filtered and cooled to room temperature to obtain material A; add material A and γ-(methacryloyloxy)propyltrimethoxysilane Add N,N dimethylethanolamine to deionized water to adjust the pH of the system to 8, raise the temperature to 60°C, stir for 40 minutes, and discharge to obtain fluorosilicon-modified acrylate.
[0032] The epoxy silane modified silica sol includes the following components by weig...
Embodiment 2
[0040]A high-performance fluorosilicon-modified finish paint, the preparation method of the fluorosilicon-modified acrylate is the preparation of isooctyl methacrylate, acrylic acid, tetrafluoropropyl methacrylate, polyoxyethylene octylphenol ether OP -10. Mix sodium dodecylbenzenesulfonate and deionized water evenly, add dicumyl peroxide, heat up to 90°C, keep warm for 12 minutes, then add disodium ethoxylated alcohol sulfosuccinate and acrylamide formaldehyde Sodium propane sulfonate was mixed evenly, cooled to 40°C, then added ammonia water to adjust the pH of the system to 8, filtered and cooled to room temperature to obtain material A; add material A and γ-(methacryloyloxy)propyltrimethoxysilane Add N,N dimethylethanolamine to deionized water to adjust the pH of the system to 10, raise the temperature to 70°C, stir for 80 minutes, and discharge to obtain fluorosilicon-modified acrylate.
[0041] The epoxy silane modified silica sol includes the following components by wei...
Embodiment 3
[0049] A high-performance fluorosilicon-modified finish paint, the preparation method of the fluorosilicon-modified acrylate is the preparation of isooctyl methacrylate, acrylic acid, tetrafluoropropyl methacrylate, polyoxyethylene octylphenol ether OP -10. Mix sodium dodecylbenzenesulfonate and deionized water evenly, add dicumyl peroxide, heat up to 85°C, keep warm for 10 minutes, then add disodium ethoxylated alcohol sulfosuccinate and acrylamide formaldehyde Sodium propane sulfonate was mixed evenly, cooled to 35°C, then added ammonia water to adjust the pH of the system to 7.5, filtered and cooled to room temperature to obtain material A; add material A and γ-(methacryloyloxy)propyltrimethoxysilane Add N,N dimethylethanolamine to deionized water to adjust the pH of the system to 9, raise the temperature to 65°C, stir for 60 minutes, and discharge to obtain fluorosilicon-modified acrylate.
[0050] The epoxy silane modified silica sol includes the following components by w...
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