Method and device for measuring dissolved oxygen based on dual-channel lock-in amplifying technique
A technology of lock-in amplification and measurement device, which is applied in measurement device, material analysis by optical means, instrument, etc., can solve the problems of multiplier and low-pass filter output influence, easy failure, instability and other problems, and achieves convenient use. , the effect of improving anti-pollution ability, high detection accuracy and test data stability
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Embodiment 1
[0029] As shown in the figure, the dissolved oxygen measurement device based on dual-channel lock-in amplification technology includes an oxygen sensitive film, an optical detection module, a signal modulation and demodulation module, a signal processing module, a system control module, a communication module, and a power management module.
[0030] Oxygen sensitive membrane is dissolved in water oxygen content detection module, such as figure 1 The black part of the oxygen-sensitive film shown is the light-shielding film that mainly shields external light interference, and the white part is the quenched fluorescent substance. When the excitation light generated by the LED lamp of the optical detection module is irradiated on the oxygen-sensitive film, it will excite fluorescence, and the oxygen dissolved in water will promote the quenching of fluorescence, resulting in a shortened lifetime of fluorescence, so the fluorescence excited by the different oxygen content The lifesp...
Embodiment 2
[0044] Stern-Volmer constant It needs to be obtained by fitting the data measured through a large number of experiments in the laboratory. When the temperature is 25°C and the salinity is 0, the experimental fitting is 0.007824345. When the dissolved oxygen is 8.335μmol / L, the measured phase value of the blue LED is 63.443 degrees, and the phase value of the red LED is 8.1 degrees. The phase delay caused by dissolved oxygen is 55.343 degrees. The above-mentioned fluorescence delay phase and dissolved oxygen The concentration relationship formula is a linear equation, so the phase 55.343 degrees when the dissolved oxygen is 8.335 μmol / L can be taken here as the phase when there is no oxygen . Then measuring the phase delay under different dissolved oxygen concentrations can calculate the corresponding dissolved oxygen concentration. When the phase difference measured by the experimental test is 49.836 degrees, the dissolved oxygen content calculated by the formula is 30.7...
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