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Aqueous gravure ink for tipping paper and preparation method thereof

A technology of gravure ink and tipping paper, which is applied in the field of water-based gravure ink for tipping paper and its preparation, and can solve problems such as excessive water absorption by tipping paper, great influence on cigarette smoking, and uneven dilution of smoke, etc. , to achieve the effect of loose film formation, small extensibility, and soft odor absorption

Active Publication Date: 2017-11-24
JIANGSU TANGCAI PRINTING INK SCI TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, the main problem of water-based gravure ink for printing on tipping paper is: because the water-based ink uses a large amount of water as a solvent, and the tipping paper is thin, has large pores, and absorbs quickly, causing the tipping paper to absorb too much water. If there are too many, the paper will suffer from serious shrinkage deformation, decrease in tensile strength, and paper becomes brittle.
Since the perforated tipping paper only has high air permeability in the fixed perforated area, the air permeability of ordinary tipping paper without perforation is very low, usually only 2 CU~10 CU, so the dilution of smoke is not uniform , which has a great influence on the taste of cigarettes

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0049] Table 1 Formula of modified casein solution

[0050] Substance name

[0051] Add 52.9g of deionized water and casein into the reaction kettle, heat up to 65°C, add dropwise borax, sodium silicate and triethanolamine dissolved in 10g of deionized water, stir until the casein is completely dissolved, and adjust the pH to 7.5; Raise the temperature to 75°C, add dropwise the mixed monomer of N-vinylpyrrolidone, acrylonitrile and trimethylolpropane triacrylate, and drop potassium persulfate dissolved in 5g deionized water at the same time, react for 4h, add 1,2 -benzisothiazol-3-one to obtain a modified casein solution.

[0052] Table 2 water-based gravure ink formula for tipping paper

[0053] Substance name

[0054]Wetting and dispersing agent, defoamer, 15g deionized water, modified casein solution of Example 1, iron oxide yellow, iron oxide red and calcium carbonate were put into the reaction kettle in sequence, and dispersed at a high speed at a sti...

Embodiment 2

[0056] Table 3 Formula of modified casein solution

[0057] Substance name

[0058] Add 46.4g of deionized water and casein into the reaction kettle, heat up to 55°C, add dropwise borax and triethanolamine dissolved in 10g of deionized water, stir until the casein is completely dissolved, and adjust the pH to 7.9; heat up to 80°C , add dropwise the mixed monomer of N-vinylpyrrolidone, acrylonitrile and trimethylolpropane triacrylate, and dropwise add sodium persulfate dissolved in 5g deionized water at the same time, react for 4h, add 2-(4-thiazolyl ) benzimidazole and 1,2-benzisothiazol-3-one to obtain a modified casein solution.

[0059] Table 4 water-based gravure ink formula for tipping paper

[0060] Substance name

[0061] Put defoamer, modified casein solution of Example 2, iron oxide yellow, iron oxide red, iron oxide black and barium sulfate in the reaction kettle in turn, disperse at a high speed at a stirring speed of 800r / min, and then pass thr...

Embodiment 3

[0063] Table 5 Formula of modified casein solution

[0064] Substance name

[0065] Add 44.9g of deionized water and casein into the reaction kettle, heat up to 60°C, add dropwise borax and ethanolamine dissolved in 10g of deionized water, stir until the casein is completely dissolved, and adjust the pH value to 7.9; heat up to 80°C, Add dropwise the mixed monomer of N-vinylpyrrolidone, acrylonitrile and trimethylolpropane triacrylate, and dropwise add tert-butyl hydroperoxide dissolved in 5g deionized water at the same time, react for 4.5h, add 2-n-octyl Base-4-isothiazolin-3-one to obtain a modified casein solution.

[0066] Table 6 water-based gravure ink formula for tipping paper

[0067] Substance name

[0068] Drop into lubricating dispersant, defoamer, 22g deionized water, the modified casein solution of embodiment 3, iron oxide yellow, iron oxide black, calcium carbonate and talcum powder successively in the reaction kettle, with the stirring speed...

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PUM

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Abstract

The invention discloses aqueous gravure ink for tipping paper and a preparation method thereof. The aqueous gravure ink for tipping paper is prepared from pigments, filler, a modified casein solution, stearyl alcohol polyoxyethylene ether, 1,2-pentanediol, a wetting dispersant, a defoamer, a cosolvent and deionized water. The modified casein solution synthesized by the invention plays an anchoring role on the pigments, so that the dispersing stability and leveling property of the ink can be improved, and casein is loose to form a film, so that the ink film is good in ventilating property, and the effects of reducing tar and harmful components in the smoke is achieved; N-vinyl pyrrolidone is excellent in moisturizing property and is used together with stearyl alcohol polyoxyethylene ether and 1,2-pentanediol to effectively prevent printing paper from being crimped and deformed as the printing paper absorbs excessive water; by introducing trimethylolpropane triacrylate, a polymer can form a three-dimensional netty structure, so that the film-forming ventilating property is improved and the adhesive force is enhanced. The aqueous gravure ink for tipping paper prepared by the method is non-toxic and odorless, and good in dispersing stability, and a printed product which is dried does not deform and crimp, and is excellent in ventilating property.

Description

technical field [0001] The invention relates to the fields of fine chemical technology and printing raw materials, in particular to a water-based gravure ink for tipping paper and a preparation method thereof. Background technique [0002] Tipping paper is "tipping paper for cigarettes", which is a special paper for connecting cigarettes and filters. At present, most tipping paper printing factories use alcohol-soluble and ester-soluble inks to print tipping paper. The large amount of volatile organic solvents involved in the printing process and the solvent residues in the printed matter will have a certain impact on the environment and people's physical and mental health. . With the promulgation of mandatory standards such as "Limits of Volatile Organic Compounds in Cigarette Rod and Packing Paper" YC263-2008 in 2008, the use of products that do not comply with industrial policies is restricted and phased out. Tipping paper printing The use of environmentally friendly wa...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D11/04C09D11/102C09D11/037C09D11/03C08F289/00C08F226/10C08F220/44C08F220/20
CPCC08F289/00C09D11/03C09D11/037C09D11/04C09D11/102C09D11/106C08F226/10C08F220/44C08F220/20
Inventor 孟召杰余佩玉范道侠
Owner JIANGSU TANGCAI PRINTING INK SCI TECH CO LTD
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