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Method for preparing graphene-like material from furfural resin, graphene-like material and use thereof

A furfural resin, graphene technology, applied in the preparation/purification of graphene, graphite, carbon, etc., can solve the problems of incompatibility, difficulty in mass production, graphene hinders graphene from realizing potential value, etc., and achieves high thermal stability. , excellent performance, low cost effect

Active Publication Date: 2019-01-08
SHIJIAZHUANG WORLDWIDE FURFURAL & FURFURYL ALCOHOL CO LTD
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] As a "miracle material", graphene has very attractive application prospects. my country's research progress on graphene materials is at the forefront of the world. In recent years, in the fields of flexible touch screens and composite materials, graphene materials have first appeared in the industry. In the dawn of time, research hotspots have formed in the fields of energy storage, sensors, chips and other electronic devices. However, in the field of graphene batteries, due to the nature of the hexagonal two-dimensional graphene material itself with nanometer high specific surface area and other properties, it is incompatible with the technical system of the current lithium-ion battery industry. incompatibility issues, resulting in limited applications in lithium-ion batteries
[0004] In addition, the technical difficulty in the preparation of graphene is the biggest "stumbling block" preventing graphene from realizing its potential value
Professors at the University of Manchester have extracted graphene for the first time, directly from graphite, but this primitive method is impossible for large-scale industrial production; recently Heim and team members have accidentally discovered a simple and easy A new method of preparing graphene, by placing graphite flakes in plastic tape, folding the tape to stick to both sides of the graphite flakes, tearing the tapes, the flakes are then divided into two, and repeating this process, you can get more and more thinner graphite flakes, but this method is difficult to achieve mass production

Method used

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  • Method for preparing graphene-like material from furfural resin, graphene-like material and use thereof
  • Method for preparing graphene-like material from furfural resin, graphene-like material and use thereof

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Embodiment

[0023] This embodiment relates to a graphene-like material and its preparation method and application.

[0024] The method for preparing graphene-like material by furfural resin comprises the following steps:

[0025] a. Add furfural resin to the reaction kettle, add boron phosphate, monoamine phosphate, aluminum phosphate and curing agent, preheat to 26-38°C with a solar water heater and stir for 10-12 minutes to obtain a well-mixed furfural mixture;

[0026] b. Put the furfural mixture into the mold and push it into the greenhouse, raise the temperature to 60-100°C, keep it warm for 8 hours, then raise the temperature to 100-130°C, keep it warm for 6 hours, and then solidify;

[0027] c. Put the fully solidified furfural mixture into a vacuum carbonization furnace for vacuum carbonization: vacuumize, under a vacuum degree of -0.1MPa, slowly raise the temperature, and raise the temperature from room temperature to 200°C at a rate of 1-2°C in 4 minutes. Keep warm for 8-10 min...

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Abstract

The invention discloses a method for preparing a graphene-like material from a furfural resin. Through a pyrolysis method, the recyclable and degradable bio-resin furfural resin obtained from plants as a raw material, under the action of additives and curing agents, After a specific pyrolysis process, a graphene-like material is prepared. By adopting the technical scheme of the present invention, a graphene-like material with a hexagonal or pentagonal network two-dimensional three-dimensional crystal structure is obtained, because the specific atomic structure has an ultra-high mechanical strength comparable to graphene, and excellent performance beyond graphene , its application can not only replace graphene materials in the fields of heat insulation materials, buffer materials, electronic and mechanical devices, but also solves a major problem that plagues graphene lithium battery materials, especially suitable for lithium metal and lithium ion battery electrodes. Material. The preparation method can realize the low-cost and mass production of the graphene material, so that the material can be applied in batches and has significant economic benefits.

Description

technical field [0001] The invention relates to the technical field of material preparation, in particular to a method for preparing a graphene-like material from furfural resin, and at the same time, it also relates to the graphene-like material obtained by the method and its application. Background technique [0002] Graphene is a two-dimensional crystal that is stripped from graphite materials and composed of carbon atoms with only one atomic thickness. Love, successfully separated graphene from graphite, confirming that it can exist alone. Graphene is currently the thinnest and highest-strength material in nature. Its breaking strength is 200 times higher than that of the best steel. It is completely transparent, absorbs only 2.3% of light, and is so dense that even the smallest gas atoms (helium atoms) cannot penetrate, so it is widely used in electronics, optics, magnetism, biomedicine, energy storage One of the cutting-edge materials with the most application potent...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C01B32/20C01B32/19
CPCC01P2002/20C01P2002/30C01P2006/40Y02E60/10C01B32/05H01M4/587
Inventor 王志军信利敏梁军良孙敬立王立辉刘莎
Owner SHIJIAZHUANG WORLDWIDE FURFURAL & FURFURYL ALCOHOL CO LTD
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