Hydrogenation and deoxygenation process of biodiesel

Abstract

The invention disclsoes a hydrogenation and deoxygenation process of biodiesel. The hydrogenation and deoxygenation process is characterized in that the process adopts a fixed bed reactor; the fixed bed reactor is filled with a hydrogenation and deoxygenation catalyst; the catalyst comprises a carrier and an active component; the carrier is a compound or mixture of MSU-G, SBA-15 and HMS (Hexagonal Mesoporous Silica); the active component is a mixture of dimolybdenum nitride (MO2N), tungsten nitride (W2N), molybdenum carbide (Mo2C) and tungsten carbide (WC); the catalyst further contains a catalytic auxiliary agent; the catalytic auxiliary agent is a mixture of Cr2O3, ZrO2, CeO2, V2O5 and NbOPO4; reaction conditions of the fixed bed reactor are as follows: the reaction temperature is 300 DEG C to 450 DEG C, the hydrogen pressure is 2.5MPa to 3.5MPa, the hydrogen-oil volume ratio is 500 to 800 and the volume space velocity is 1.0h<-1> to 2.5h<-1>. By adopting the process provided by the invention, the hydrogenation and deoxygenation of the biodiesel can be controlled to be a relatively high deoxygenation rate (99.8 percent or more) and the catalytic activity does not fall significantly after 500 hours of continuous operation.

Description

technical field [0001] The invention relates to biodiesel hydrodeoxygenation process. Background technique [0002] In the 21st century, the demand and use of fuel oil have increased significantly, and the environmental pollution caused by sulfur compounds in it has attracted people's attention. Sulfur oxides (SO x ) into the air, producing acid rain and sulfuric acid smog pollution, etc., resulting in air pollution. [0003] In order to solve the increasingly serious environmental problems and reduce the environmental pollution caused by fossil fuels, it has recently become a hot spot to use vegetable oil as the basis and make full use of renewable resources as fuel. [0004] In the 1980s, American Graham Quick introduced linseed oil and cottonseed oleate methyl ester into diesel engines for the first time. After that, he defined fatty acid monoester compounds obtained through transesterification as biodiesel. This fatty acid monoester compound can be used alone or mixed...

AI Technical Summary

Problems solved by technology

However, with the wide application of biodiesel, more and more defects are found: animal and vegetable oils and fats contain different types of fatty acids, and the production process will not change the degree of unsaturation, which is high, such as Biodiesel produced from cottonseed oil, rapeseed oil, etc., contains a large number of carbon-carbon unsaturated bonds in the molecular structure, which is easy to oxidize and cause deterioration during storage, transportation and use. If the unsaturation is low, such as industrial lard and tallow The freezing point of the biodiesel produced by biodiesel is much higher than that of petrochemical diesel. Even if it is mixed with petrochemical diesel in a lower proportion, it is easy to precipitate in low temperature seasons such as autumn and winter, resulting in pipeline blockage, and even damage to the engine in severe cases.

Despite a lot of research and improvements, the molecular structure of biodiesel has not changed, so its defects still exist