A high-voltage-resistant supercapacitor electrode pole piece and its preparation method and application
A technology of supercapacitors and electrode pole pieces, applied in hybrid capacitor electrodes, hybrid/electric double layer capacitor manufacturing, nanotechnology for materials and surface science, etc., can solve poor conductivity, increase active material impedance, and affect capacitor work Performance and other issues, to achieve the effect of improving durability, avoiding instability, and avoiding the decline of electrochemical performance
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Embodiment 1
[0019] The active material graphene and activated carbon powder (graphene weight ratio 10%) are evenly mixed and then subjected to ALD deposition treatment, pre-coated with a layer of Al 2 o 3 cladding layer with a thickness of 2nm,
[0020] After testing, the specific surface area of the active material has not changed after coating;
[0021] Weigh the total weight of the above-mentioned coated active material, conductive graphite, conductive carbon black, CMC, and SBR 200g, and the weight ratio is 88:2:3:3:4, and use water as a solvent to make a slurry through high-speed stirring, and then coat Clothed on aluminum foil, dried, and then made into positive and negative electrodes through rolling, cutting, and vacuum drying;
[0022] Use the above-mentioned positive electrode sheet and negative electrode sheet and weld the tabs respectively, select a commercially available paper diaphragm as the diaphragm, wind the positive and negative electrode sheets into a battery cell,...
Embodiment 2
[0025] The active material graphene and activated carbon powder (5% by weight of graphene) are evenly mixed and then subjected to ALD deposition treatment, pre-coated with a layer of ZrO 2 cladding layer with a thickness of 1.5nm,
[0026] After testing, the specific surface area of the active material has not changed after coating;
[0027] Weigh the above-mentioned coated active material, conductive graphite, conductive carbon black, and LA132 with a total weight of 200g, and the weight ratio is 87:2:3:8, and use water as a solvent to make a slurry through high-speed stirring, and then coat it on aluminum foil. , dried, and then made into positive and negative electrodes through rolling, cutting, and vacuum drying;
[0028] Use the above-mentioned positive electrode sheet and negative electrode sheet and weld the tabs respectively, select a commercially available paper diaphragm as the diaphragm, wind the positive and negative electrode sheets into a battery cell, put it ...
Embodiment 3
[0031] Weigh activated carbon powder, graphene, conductive graphite, conductive carbon black, and PVDF with a total mass of 200g and mix them in a mass ratio of 85:5:3:2:5, and use NMP as a solvent to stir at a high speed to form a slurry, and then coat On the aluminum foil, dry, put the pole piece into the ALD equipment for atomic layer deposition Al 2 o 3 , deposited Al 2 o 3 The thickness is 2nm, and the deposited pole pieces are rolled, cut, and vacuum dried to make positive and negative pole pieces;
[0032] Use the above-mentioned positive electrode sheet and negative electrode sheet and weld the tabs respectively, select a commercially available paper diaphragm as the diaphragm, wind the positive and negative electrode sheets into a battery cell, put it into a cylindrical aluminum shell, and inject the solvent as acetonitrile, solute The electrolyte solution is 1mol / L tetraethylammonium tetrafluoroborate, and the capacitor is aged overnight after being sealed.
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