Aftertreatment separation method of aromatic hydroxycarboxylic acid intermediate 3,6-dichloro-2-methoxybenzoic acid
A technology of methoxybenzoic acid and sodium methoxybenzoate, which is applied in the field of post-treatment separation of 3,6-dichloro-2-methoxybenzoic acid, can solve the problem of high production cost, low content of reaction products, Difficult to deal with and other problems, to achieve the effects of reduced emissions, good appearance, and reduced use of acid and alkali
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Examples
Embodiment 2
[0022] Put 232g of crude 3,6-dichloro-2-hydroxybenzoic acid whose content has been detected in a 500ml reactor, put in 192g of 50% liquid caustic soda, heat up to 70°C, add ethanol, start to add dimethyl sulfate dropwise, add auxiliary Catalyst 9.9g trifluoromethanesulfonic acid, reacted at a temperature of 70°C for 5 hours, added liquid alkali, then evaporated the organic solvent and filtered to obtain the intermediate 3,6-dichloro-2-methoxybenzoic acid sodium salt and Mother liquor, the mother liquor is reused as liquid caustic soda.
[0023] The solid intermediate 3,6-dichloro-2-methoxybenzoic acid sodium salt was dissolved in water, and activated carbon was added, wherein the weight ratio of 3,6-dichloro-2-methoxybenzoic acid sodium salt: activated carbon was 1: 0.04, Decolorize and stir at 90°C for 4 hours, filter to obtain the sodium salt of 3,6-dichloro-2-methoxybenzoic acid, and then analyze with acid to obtain 3,6-dichloro-2-methoxybenzoic acid. The product content i...
Embodiment 3
[0025] Put 232g of the crude product of 3,6-dichloro-2-hydroxybenzoic acid whose content has been detected in a 500ml reactor, put in 192g of 50% liquid caustic soda, heat up to 60°C, add methanol, start to drop dimethyl sulfate, add sulfuric acid Potassium dihydrogen 11.2g, react at a temperature of 60°C for 3 hours, add liquid alkali, then distill off the organic solvent and filter to obtain the intermediate 3,6-dichloro-2-methoxybenzoic acid sodium salt and mother liquor, mother liquor Utilize and reuse as liquid caustic soda.
[0026] The solid intermediate 3,6-dichloro-2-methoxybenzoic acid sodium salt was dissolved in water, and activated carbon was added, wherein the weight ratio of 3,6-dichloro-2-methoxybenzoic acid sodium salt: activated carbon was 1: 0.04, Decolorize and stir at 80°C for 2 hours, filter to obtain the sodium salt of 3,6-dichloro-2-methoxybenzoic acid, and analyze with acid to obtain 3,6-dichloro-2-methoxybenzoic acid. The product content is 99.4%, an...
Embodiment 4
[0028] Put 232g of crude 3,6-dichloro-2-hydroxybenzoic acid whose content has been detected in a 500ml reactor, put in 192g of 50% liquid caustic soda, heat up to 80°C, add xylene, start to drop dimethyl sulfate, add Sodium dodecylbenzenesulfonate 11.6g, react at 80°C for 6 hours, add liquid alkali, then evaporate the organic solvent and filter to obtain the intermediate 3,6-dichloro-2-methoxybenzoic acid sodium Salt and mother liquor, the mother liquor is reused as liquid caustic soda.
[0029] The solid intermediate 3,6-dichloro-2-methoxybenzoic acid sodium salt was dissolved in water, and activated carbon was added, wherein the weight ratio of 3,6-dichloro-2-methoxybenzoic acid sodium salt: activated carbon was 1: 0.06, Decolorize and stir at 80°C for 3 hours, filter to obtain the sodium salt of 3,6-dichloro-2-methoxybenzoic acid, and then analyze with acid to obtain 3,6-dichloro-2-methoxybenzoic acid. The product content is 99.3%, and the waste water volume is 1050ml.
PUM
Abstract
Description
Claims
Application Information
- R&D Engineer
- R&D Manager
- IP Professional
- Industry Leading Data Capabilities
- Powerful AI technology
- Patent DNA Extraction
Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.
© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com