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Biophysical Treatment Process of Electroplating Wastewater

A technology of electroplating wastewater and biophysics, which is applied in the direction of metallurgical wastewater treatment, biological water/sewage treatment, multi-stage water treatment, etc., can solve the problems such as difficulty in ensuring sewage discharge up to standard, difficulty in meeting discharge standards, large dosage of drugs, etc. Achieve the effects of improving biological treatment efficiency, reducing operating costs, and speeding up precipitation

Active Publication Date: 2019-04-19
FUYANG HUAIBANG MACHINERY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0014] Physicochemical + biochemical methods are used for treatment. Since hypophosphite is used as a reducing agent in electroplating wastewater, it is difficult to effectively precipitate, resulting in the concentration of total phosphorus in the biochemical tail water is usually 2-5mg / L, and after precipitation with calcium salt, it usually contains High concentration of fluoride ions, the concentration range is 10-20mg / L, it is difficult to meet the increasingly stringent emission standards
[0015] The Ministry of Environmental Protection requires the electroplating industry to discharge in accordance with GB21900-2008 "Electroplating Pollutant Discharge Standard". Conventional treatment methods are used to treat electroplating wastewater with complex components. Level treatment, etc., so that the dosage of drugs is large, the process repeats to produce a lot of sludge, the cost is high, and it is difficult to ensure that the discharge of sewage meets the standard

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] A biophysical treatment process for electroplating wastewater, characterized in that it comprises the following steps:

[0040] (1) Solid-liquid separation of electroplating wastewater can effectively prevent clogging and damage to equipment during wastewater transportation;

[0041] (2) Pass the liquid obtained in step (1) through the micro-electrolysis reactor, which can effectively break the cyanide-containing complexes and heavy metal complexes in the wastewater, and reduce the hexavalent chromium in the wastewater to trivalent chromium, Play the role of pretreatment;

[0042] (3) Adjust the pH value of the wastewater passing through the micro-electrolysis reactor to 10, then add sodium hypochlorite accounting for 0.2% of the wastewater weight, react for 30 minutes, control the pH value of the wastewater at 6, react for another 20 minutes, and then follow the 0.1g / L The proportion of flocculant was added, flocculation treatment was carried out, and then static prec...

Embodiment 2

[0056] A biophysical treatment process for electroplating wastewater, characterized in that it comprises the following steps:

[0057] (1) Solid-liquid separation of electroplating wastewater can effectively prevent clogging and damage to equipment during wastewater transportation;

[0058] (2) Pass the liquid obtained in step (1) through the micro-electrolysis reactor, which can effectively break the cyanide-containing complexes and heavy metal complexes in the wastewater, and reduce the hexavalent chromium in the wastewater to trivalent chromium, Play the role of pretreatment;

[0059] (3) Adjust the pH value of the wastewater passing through the micro-electrolysis reactor to 10, then add sodium hypochlorite accounting for 0.2% of the wastewater weight, react for 40 minutes, control the pH value of the wastewater at 7, react for another 30 minutes, and then follow the 0.1g / L Proportional addition of flocculant, flocculation treatment, and then static precipitation for 6 hou...

Embodiment 3

[0073] The treatment process of Example 1 was used to treat the electroplating sewage of a certain factory, and the results are shown in Table 1.

[0074] Table 1

[0075]

[0076] Through the method of the present invention, the electroplating wastewater is further treated. In the wastewater after treatment, the total phosphorus concentration is less than 0.5mg / L, the fluoride is less than 10mg / L, and the total cyanide content is less than 0.2mg / L. Emission Standard", has a good treatment effect.

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PUM

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Abstract

The invention relates to a biophysical treatment process of electroplating wastewater. The biophysical treatment process of the electroplating wastewater comprises the following steps: (1) carrying out solid-liquid separation on the electroplating wastewater; (2) enabling liquid obtained from the step (1) to pass through a micro-electrolysis reactor; (3) adjusting pH of the wastewater passing through the micro-electrolysis reactor to be 10, then adding sodium hypochlorite, adjusting the pH value to be 6-7 after reaction, then performing reaction again for 20 minutes, adding a flocculating agent, carrying out flocculating treatment, and then standing to precipitate for 4-6 hours so as to obtain clear supernate; (4) discharging the supernate obtained by treatment in the step (3) to a microorganism reaction tank, adjusting the PH value to be 7-8, feeding 10 g of a biological agent in every cubic meter of liquid, and standing for a week. By the process, the quantity and the quality of treated water are increased, running cost is reduced, and the quality of drained water is promoted to reach the standard.

Description

technical field [0001] The invention belongs to the technical field of sewage treatment, and in particular relates to a biophysical treatment process for electroplating wastewater. Background technique [0002] The sources of electroplating wastewater are generally: (1) plating cleaning water; (2) waste electroplating solution; (3) other wastewater, including washing the floor of the workshop, scrubbing plate washing water, condensed water from ventilation equipment, and leakage from plating tanks. Or various tank liquids and drainages of "running, popping, dripping, and leaking" caused by improper operation and management; (4) Equipment cooling water, which has not been polluted except for the temperature rise during use. The water quality and quantity of electroplating wastewater are related to the process conditions of electroplating production, production load, operation management and water use methods and other factors. The water quality of electroplating wastewater i...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F9/14C02F3/34C02F101/14C02F101/22C02F103/16C02F101/10C02F1/52C02F1/66C02F1/74C02F1/76C02F1/461
CPCC02F1/461C02F1/52C02F1/66C02F1/74C02F1/76C02F3/348C02F9/00C02F2101/105C02F2101/14C02F2101/22C02F2103/16C02F2301/08
Inventor 李为
Owner FUYANG HUAIBANG MACHINERY
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