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Preparation method of functional magnesium hydroxide flame retardant and flame retardant prepared through method

A magnesium hydroxide, functional technology, applied in the field of flame retardants, can solve the problems of high cost, magnesium hydroxide flame retardant combination, large filling amount, etc. Effect

Inactive Publication Date: 2016-08-17
FOSHAN JUCHENG BIOCHEM TECH RES & DEV CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The magnesium hydroxide flame retardant prepared by the conventional preparation method cannot be well combined with plastics, so it needs a large filling amount in application, and often requires a large cost to significantly improve the flame retardant performance of the material

Method used

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Effect test

preparation example Construction

[0023] The invention provides a method for preparing a functional magnesium hydroxide flame retardant, the method comprising: a. mixing water, ethanol and ethylene glycol according to a mass ratio of 1: (0.1-0.3): (0.05-0.2), Obtain a solvent; b, dissolve the magnesium salt in the solvent to obtain a magnesium salt solution with a mass concentration of 2-10%; c, be 100:(0.5-5) to the magnesium salt according to the mass ratio of the magnesium salt and the surfactant A surfactant is added to the magnesium salt solution to obtain the first liquid, and the first liquid is ultrasonically placed into a water bath container with a constant temperature, while the first liquid is kept stirring at a constant speed, and the water bath container maintains a water bath temperature of 15- 35 degrees Celsius; d, the mass concentration of 2-10% ammonia solution is added dropwise to the first liquid under stirring until the pH of the mixed solution is 9.5-10, and the mixed solution is kept und...

Embodiment 1

[0036] a. Mix water, ethanol and ethylene glycol according to the mass ratio of 1:0.1:0.05 to obtain a solvent; b. Dissolve magnesium nitrate in the solvent to obtain a magnesium salt solution with a mass concentration of 2%; c. The mass ratio of magnesium salt and surfactant is 100:0.5. Add surfactant PEG-800 to the magnesium salt solution to obtain the first liquid. After the first liquid is subjected to ultrasound at a frequency of 25KHZ for 20 minutes, it is placed in a temperature of 15 degrees Celsius. Keep stirring at a constant speed of 600 rpm in a water bath container; d. Add ammonia solution with a mass concentration of 2% to the first liquid under stirring until the pH of the mixed solution is 9.5, and adjust the water bath while the mixed solution is kept stirring. The temperature of the container is 40 degrees Celsius, and the second liquid is obtained after reacting for 30 minutes; e. After the second liquid is left to stand at room temperature for 1 hour, it is ...

Embodiment 2

[0038]a. Mix water, ethanol and ethylene glycol according to the mass ratio of 1:0.3:0.2 to obtain a solvent; b. Dissolve magnesium chloride in the solvent to obtain a magnesium salt solution with a mass concentration of 10%; c. The mass ratio of salt to surfactant is 100:5. Add surfactant PEG-1000 to the magnesium salt solution to obtain the first liquid. After the first liquid is ultrasonicated at 130KHZ for 1 hour, it is placed in a water bath container with a temperature of 35 degrees Celsius. and keep stirring at a constant speed of 1500 rev / min; d, adding the ammonia solution with a mass concentration of 10% dropwise into the first liquid under stirring until the pH of the mixed solution is 10, and keep the mixed solution under stirring to adjust the water bath container The temperature is 90 degrees centigrade, and the second liquid is obtained after reacting for 2 hours; e, the second liquid is left to stand at room temperature for 6 hours and then washed with water for...

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PUM

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Abstract

The invention relates to a preparation method of a functional magnesium hydroxide flame retardant and the flame retardant prepared through the method. The preparation method comprises the steps that 1, water, ethyl alcohol and ethylene glycol are mixed to obtain a solvent; 2, magnesium salt is dissolved into the solvent to obtain a magnesium salt solution; 3, a surfactant is added into the magnesium salt solution to obtain first liquid, and the first liquid is subjected to ultrasound and then placed in a water bath container with the constant temperature and keeps to be stirred at uniform velocity; 4, an ammonia water solution is dropwise added into the stirred first liquid until the pH of mixed liquid is 9.5-10, and after reacting is conducted, second liquid is obtained; 5, after standing is conducted on the second liquid at room temperature, the second liquid is washed with water and ethyl alcohol sequentially under vacuum filtration and then dried and ground to obtain the functional magnesium hydroxide flame retardant. The functional magnesium hydroxide flame retardant prepared through the method can be better combined with plastic, and the good flame retardance can be significantly achieved only needing a little filling amount of the flame retardant.

Description

technical field [0001] The invention relates to a flame retardant, in particular to a preparation method of a functional magnesium hydroxide flame retardant and a flame retardant prepared by the method. Background technique [0002] With the development of the polymer material industry, the three major synthetic materials (plastic, synthetic rubber, synthetic fiber) are more and more widely used in various fields of production and life. The fires caused by the flammability of these organic polymers have also caused heavy casualties and huge economic losses. Therefore, the flame retardancy of polymer materials has attracted global attention. Since the 1960s, some industrially developed countries have begun to produce and apply flame-retardant plastics, flame-retardant rubber and flame-retardant textiles. With the development of electrical appliances, electronics, machinery, automobiles, ships, aviation, aerospace and chemical industry, the requirements for flame retardant of...

Claims

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Application Information

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IPC IPC(8): C08K9/00C08K9/04C08K3/22
CPCC08K9/00C08K3/22C08K9/08C08K2003/2224
Inventor 不公告发明人
Owner FOSHAN JUCHENG BIOCHEM TECH RES & DEV CO LTD
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