Modified mineral material and method for preparing farmland soil ecological preparation
A mineral material and modification technology, which is applied in the field of farmland soil ecological restoration, can solve the problems of not being significant enough to deal with heavy metal pollution, unable to completely remove heavy metal ions, and unable to completely remove heavy metals in the soil, so as to achieve the restoration of heavy metal pollution, rich reserves, The effect of improving the ecosystem
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[0030] A kind of preparation method of modified mineral material of the present invention, it comprises the following steps:
[0031] (a) adding palygorskite to deionized water to prepare a mixed solution, and ultrasonically dispersing for 10-30 minutes under the action of ultrasonic waves, the ratio of deionized water: palygorskite is 10ml:1g-30ml:1g;
[0032] (b) sending the mixed solution into a homogenizer to disperse for 5-15 minutes to form a gel, and the speed of the homogenizer is 10000-12000 rpm;
[0033] (c) Weigh 3-mercaptopropyltriethoxysilane and 3-aminopropyltriethoxysilane and add them to the mixed solution in the homogenizer to disperse for 10-20 minutes, and the speed of the homogenizer is 10000-12000 Revolution / minute, described 3-mercaptopropyltriethoxysilane: 3-aminopropyltriethoxysilane: the mass ratio of palygorskite is 3:3:10-5:5:10;
[0034] (d) Send the mixed liquid in the homogenizer to a four-necked bottle, raise the temperature to about 50-60°C, re...
Embodiment 1
[0046] Prepare the modified mineral material, the specific steps are:
[0047] (a) 10.0g palygorskite was added to 100ml of deionized water to prepare a mixed solution, and ultrasonically dispersed for 10 minutes under the action of ultrasonic waves;
[0048] (b) transfer the mixed solution into a homogenizer for dispersion for 5 minutes to form a gel, and the homogenizer speed is 10000 rpm;
[0049] (c) Weigh 3.0g of 3-mercaptopropyltriethoxysilane and 3.0g of 3-aminopropyltriethoxysilane and add them to the mixed solution in the homogenizer to disperse for 10 minutes, and the speed of the homogenizer is 10000 rpm ;
[0050] (d) Send the mixed solution in the homogenizer to a four-necked bottle, heat up to about 50°C, react for 30 minutes, then cool to 20°C, filter with suction to obtain a solid, rinse with distilled water until the pH is 6;
[0051] (e) drying the solid to obtain a modified mineral material.
[0052] To prepare farmland soil ecological preparations, the s...
Embodiment 2
[0065] Prepare the modified mineral material, the specific steps are:
[0066] (a) 10.0g palygorskite was added to 200ml of deionized water to prepare a mixed solution, and ultrasonically dispersed for 20 minutes under the action of ultrasonic waves;
[0067] (b) transfer the mixed solution into a homogenizer to disperse for 10 minutes to form a gel, and the homogenizer speed is 11000 rpm;
[0068] (c) Weigh 4.0g of 3-mercaptopropyltriethoxysilane and 4.0g of 3-aminopropyltriethoxysilane and add them to the mixed solution in the homogenizer to disperse for 15 minutes, and the speed of the homogenizer is 11000 rpm ;
[0069] (d) Send the mixed solution in the homogenizer to a four-necked bottle, heat up to about 55°C, react for 45min, then cool to 25°C, filter with suction to obtain a solid, rinse with distilled water until the pH is 7;
[0070] (e) drying the solid to obtain a modified mineral material.
[0071] To prepare farmland soil ecological preparations, the specific...
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