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Modified mineral material and method for preparing farmland soil ecological preparation

A mineral material and modification technology, which is applied in the field of farmland soil ecological restoration, can solve the problems of not being significant enough to deal with heavy metal pollution, unable to completely remove heavy metal ions, and unable to completely remove heavy metals in the soil, so as to achieve the restoration of heavy metal pollution, rich reserves, The effect of improving the ecosystem

Inactive Publication Date: 2016-05-04
TIANJIN UNIV
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] At present, there are still few technical patents that can effectively remove heavy metal pollution in soil without damaging the soil ecological environment and at the same time effectively enhance soil fertility
The Chinese patent with the publication number CN104984992A discloses a method for repairing heavy metal-contaminated soil by pressure filtration and leaching. The amount is large, the processing cost is high, and it is easy to cause secondary pollution
The Chinese patent with publication number CN104907329A discloses a method for solidification / stabilization treatment of heavy metal contaminated soil in mining areas. The method uses apatite, fly ash and quicklime as raw materials to prepare a solidification stabilizer. The stabilizer raw material It has a wide range of sources and is cheap. It wraps heavy metal ions in gel particles through adsorption, precipitation, complexation, etc., and has a good adsorption effect. However, as the soil environment changes, these heavy metal ions may form anti-solution
The Chinese patent with the publication number CN104927871A discloses a heavy metal stabilizer and a method for using the heavy metal stabilizer. The stabilizer uses phosphate, quicklime, zeolite powder and potassium chloride as raw materials, and the cost is relatively low, which can realize the high concentration of heavy metals. Stabilization, effectively preventing the inversion and seepage of heavy metal ions, but this method cannot completely remove heavy metal ions in the soil
The Chinese patent with the publication number CN104959109A discloses a preparation method of a sulfuric acid lignin-modified sepiolite adsorbent. A kind of adsorbent is prepared by using sepiolite with relatively abundant reserves and lignin, a by-product of papermaking industry, as raw materials. Simple operation, low cost, green and pollution-free, can be used to adsorb a variety of heavy metal elements, and has a wide range of applications, but this adsorbent still cannot completely remove heavy metals in the soil, the repair period is long, and there is currently no good recycling method
The Chinese patent with publication number CN104892324A discloses an organic fertilizer that can improve the microenvironment of plant rhizosphere soil. It can also reduce soil salinization, enhance soil fertility, and improve the living environment of microorganisms. However, this method has a long fertilizer fermentation cycle and the effect of dealing with heavy metal pollution is not significant enough.

Method used

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  • Modified mineral material and method for preparing farmland soil ecological preparation
  • Modified mineral material and method for preparing farmland soil ecological preparation
  • Modified mineral material and method for preparing farmland soil ecological preparation

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preparation example Construction

[0030] A kind of preparation method of modified mineral material of the present invention, it comprises the following steps:

[0031] (a) adding palygorskite to deionized water to prepare a mixed solution, and ultrasonically dispersing for 10-30 minutes under the action of ultrasonic waves, the ratio of deionized water: palygorskite is 10ml:1g-30ml:1g;

[0032] (b) sending the mixed solution into a homogenizer to disperse for 5-15 minutes to form a gel, and the speed of the homogenizer is 10000-12000 rpm;

[0033] (c) Weigh 3-mercaptopropyltriethoxysilane and 3-aminopropyltriethoxysilane and add them to the mixed solution in the homogenizer to disperse for 10-20 minutes, and the speed of the homogenizer is 10000-12000 Revolution / minute, described 3-mercaptopropyltriethoxysilane: 3-aminopropyltriethoxysilane: the mass ratio of palygorskite is 3:3:10-5:5:10;

[0034] (d) Send the mixed liquid in the homogenizer to a four-necked bottle, raise the temperature to about 50-60°C, re...

Embodiment 1

[0046] Prepare the modified mineral material, the specific steps are:

[0047] (a) 10.0g palygorskite was added to 100ml of deionized water to prepare a mixed solution, and ultrasonically dispersed for 10 minutes under the action of ultrasonic waves;

[0048] (b) transfer the mixed solution into a homogenizer for dispersion for 5 minutes to form a gel, and the homogenizer speed is 10000 rpm;

[0049] (c) Weigh 3.0g of 3-mercaptopropyltriethoxysilane and 3.0g of 3-aminopropyltriethoxysilane and add them to the mixed solution in the homogenizer to disperse for 10 minutes, and the speed of the homogenizer is 10000 rpm ;

[0050] (d) Send the mixed solution in the homogenizer to a four-necked bottle, heat up to about 50°C, react for 30 minutes, then cool to 20°C, filter with suction to obtain a solid, rinse with distilled water until the pH is 6;

[0051] (e) drying the solid to obtain a modified mineral material.

[0052] To prepare farmland soil ecological preparations, the s...

Embodiment 2

[0065] Prepare the modified mineral material, the specific steps are:

[0066] (a) 10.0g palygorskite was added to 200ml of deionized water to prepare a mixed solution, and ultrasonically dispersed for 20 minutes under the action of ultrasonic waves;

[0067] (b) transfer the mixed solution into a homogenizer to disperse for 10 minutes to form a gel, and the homogenizer speed is 11000 rpm;

[0068] (c) Weigh 4.0g of 3-mercaptopropyltriethoxysilane and 4.0g of 3-aminopropyltriethoxysilane and add them to the mixed solution in the homogenizer to disperse for 15 minutes, and the speed of the homogenizer is 11000 rpm ;

[0069] (d) Send the mixed solution in the homogenizer to a four-necked bottle, heat up to about 55°C, react for 45min, then cool to 25°C, filter with suction to obtain a solid, rinse with distilled water until the pH is 7;

[0070] (e) drying the solid to obtain a modified mineral material.

[0071] To prepare farmland soil ecological preparations, the specific...

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Abstract

The present invention discloses a modified mineral material and a method for preparing a farmland soil ecological preparation, the method for preparing the farmland soil ecological preparation comprises the following steps: (a) the modified mineral material, animal and poultry manure and straw powder are mixed in the mass ratio of 1: 3: 3-1: 5: 5 to obtain a mixture; (b) a thermophilic complex microbial agent accounting for 3%-5% by mass of the mixture is added into the mixture for full stirring and even mixing; (c) the mixed material is put into high-temperature fermentation equipment, electrically-heated to 80-100 DEG C, and thermally insulated for 4-8h; and (d) the fully fermented dried material is prepared into particles by a pelletizer and then packed to obtain a farmland soil ecological preparation finished product. The prepared farmland soil ecological preparation is high in fertility, and easily absorbed by crops, and the fertilizer utilization can be increased by 10%-20%.

Description

technical field [0001] The invention belongs to the field of farmland soil ecological restoration, and in particular relates to a modified mineral material and a preparation method of farmland soil ecological preparations. Background technique [0002] Since the founding of the People's Republic of China, especially over the past 30 years of reform and opening up, my country's crop production has achieved breakthrough development. In recent years, China's total grain output has ranked first in the world. With less than 10% of the world's arable land, we have solved the problem of feeding the Chinese, who account for about 22% of the world's population. Planting production has played an important supporting role in the steady and rapid development of my country's economy, and the most direct factor affecting planting production is the quality of cultivated land soil. It can be seen that the importance of soil for the development of our national economy and social stability. ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C05G3/04C01B33/22C09K17/40C09K101/00C09K109/00C05G3/80
CPCC01B33/22C05D9/00C05G3/80C09K17/40C09K2101/00C09K2109/00C05F3/00C05F11/00C05F11/08
Inventor 丁辉叶微
Owner TIANJIN UNIV
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