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A graded absorption desulfurization device using ammonia-ammonium sulfate method

A technology of ammonium sulfate method and desulfurization device, which is applied in the direction of combination device, separation method, dispersed particle separation, etc., can solve the problems of increasing aerosol, high content of flue gas aerosol, and tailing of smoke plume, so as to improve oxidation efficiency, Improve the utilization rate of ammonia, improve the uniformity of distribution and the effect of mixing effect

Active Publication Date: 2017-11-14
SINOPEC NANJING ENG & CONSTR +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The ammonia consumption of currently operating ammonia-ammonium sulfate desulfurization devices is generally about 1.05 to 1.15 times the theoretical calculation. Considering that a 240t / h boiler burns coal with 1% sulfur content (the annual operating time is 8000 hours), The annual desulfurization agent (ammonia water) dosage in the desulfurization device is higher than the theoretical value, and the increased operating cost is about 700,000 yuan; at the same time, the excessive dosage of desulfurization agent (ammonia water) increases the generation of aerosols
[0006] 2) The smoke aerosol content is high, and the smoke plume is seriously tailed

Method used

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  • A graded absorption desulfurization device using ammonia-ammonium sulfate method
  • A graded absorption desulfurization device using ammonia-ammonium sulfate method
  • A graded absorption desulfurization device using ammonia-ammonium sulfate method

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Embodiment 1

[0050]Treat 240t / h pulverized coal boiler flue gas, the flue gas volume is 280000Nm under rated working conditions 3 / h, the raw flue gas temperature at the flue inlet 11 is 125°C, SO 2 Concentration 2500mg / Nm 3 , Dust content 20mg / Nm 3 . The flue gas desulfurization absorption tower 1 is made of carbon steel-lined glass flakes, 32m high and 7.2m in diameter, in which the liquid level of the concentrated slurry circulation tank 4 is controlled at 5.5m~6m, and the jet stirring distribution pipe 9 made of FRP and the absorption tower are arranged below Oxidation air distribution pipe 10, the oxidation air volume is 1800Nm 3 / h. The concentrated pre-absorption section is equipped with a concentrated slurry spray layer 12, the material is 2205 duplex stainless steel, and the flow rate is 400m 3 / h, the spray coverage rate is 150%; above the concentrated slurry spray layer 12, a layer of concentrated pre-absorption backwash layer is set as the backwash spray layer of the absor...

Embodiment 2

[0056] The hierarchical absorption desulfurization device of the ammonia-ammonium sulfate method of embodiment 1 is transformed. During the transformation, only the swirl defogging liquid collector is adjusted, and it is respectively transformed into a device (device A ), the device (device B) that is neither provided with the absorption liquid cyclone demister liquid collector 13 nor the dilute slurry cyclone demist liquid collector 15 is respectively introduced into the flue gas, and the flue gas volume is 270000Nm 3 / h, SO in flue gas 2 Concentration 2000mg / Nm 3 . Compared with device B, the air resistance of device A increased by 180Pa, the amount of ammonium sulfate carried from the concentrated pre-absorption section to the absorption section was reduced from 2t / h to 0.4t / h, and the concentration of the slurry in the absorption section was reduced from 30% to 12%. The total aerosol (dust) content in the net flue gas is increased from 40mg / Nm 3 Reduced to 20mg / Nm 3 . ...

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Abstract

The invention discloses a hierarchical absorption desulfurization device using the ammonia-ammonium sulfate method, which includes a flue gas desulfurization absorption tower, an absorption liquid circulation tank, a slurry circulation tank and a wet electrostatic precipitator; the flue gas desulfurization absorption tower includes a bottom-up The concentrated slurry circulation tank, concentrated pre-absorption section, absorption section, thin slurry water washing section and demister section; the concentrated slurry section includes at least one concentrated slurry spray layer, and the absorption section includes an absorption liquid cyclone mist collector and There is at least one absorbing liquid spray layer. The slurry liquid washing section includes a slurry liquid cyclone demister collector and a slurry liquid spray layer. The demister section includes a demister and a demister flushing spray layer. The present invention completes the processes of flue gas cooling, graded defogging and absorption, and segmented oxidation in the absorption tower. It improves ammonia utilization by adjusting the position of the ammonia adding point, and solves the problem that although the traditional desulfurization absorption tower is segmented, each segment carries serious slurry, resulting in The slurry concentration control in each section is not ideal, and the aerosol content of the net flue gas aerosol is too high.

Description

technical field [0001] The invention relates to a desulfurization device, in particular to a hierarchical absorption desulfurization device of an ammonia-ammonium sulfate method, and is a flue gas desulfurization device suitable for the ammonia-ammonium sulfate method. Background technique [0002] Ammonia-ammonium sulfate method flue gas desulfurization technology is a mainstream desulfurization process in the chemical industry, which effectively solves the problem of waste ammonia water (with a concentration of about 5%) in the enterprise, and is used to produce ammonium sulfate, realizing "treatment with waste". Waste, comprehensive utilization". [0003] The current ammonia-ammonium sulfate desulfurization technology has the following shortcomings in engineering application: [0004] 1) The utilization rate of ammonia is not high, and the escape of ammonia is high. [0005] The ammonia consumption of currently operating ammonia-ammonium sulfate desulfurization devices ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01D53/78B01D53/50B01D53/96B01D50/00
Inventor 李军东周亮
Owner SINOPEC NANJING ENG & CONSTR
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