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Gel breaker with high-efficiency positioning double-effect and preparation method thereof

A dual-action, gel-breaker technology, applied in the direction of chemical instruments and methods, drilling compositions, etc., can solve the problems of reducing bottom flow conductivity, retention damage, and difficulty in fracturing fluid flowback, so as to improve the production stimulation effect , reduce damage, improve the effect of reflow effect

Inactive Publication Date: 2015-09-23
SHAANXI UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The liquid also maintains a high viscosity, and the high-viscosity fracturing fluid is enriched in a large amount on the proppant diversion bed, which causes the fracturing fluid residue to cause retention damage to the formation, making it difficult to flow back the fracturing fluid, thereby greatly reducing the diversion of the bottom layer ability

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] The gel breaker of the present invention is prepared by uniformly mixing 30 g of ethyl acetate, 19.5 g of petroleum ether, and 0.5 g of ferrocene at a temperature of 60° C. to form component A and component B hydrogen peroxide 50 g. A high-efficiency positioning dual-action breaker is obtained.

[0035] Mixture A and mixture B of the present invention are added to 100kg of fracturing fluid hydrogel at the same time, quickly mixed and stirred evenly, and injected downhole with a pump. When the downhole temperature is 60°C, after 3 hours of gel breaking, the gel breaking fluid The viscosity dropped to 5mPa.s.

Embodiment 2

[0037] The gel breaker of the present invention is prepared by uniformly mixing 30 g of ethyl acetate, 19.0 g of petroleum ether, and 1 g of ferrocene at a temperature of 90° C. to form component A and component B hydrogen peroxide 50 g. A high-efficiency positioning dual-action breaker is obtained.

[0038] Mixture A and mixture B of the present invention are added to 100kg of fracturing fluid hydrogel at the same time, quickly mixed and stirred evenly, and injected downhole with a pump. When the downhole temperature is 90°C, after 1.5 hours of gel breaking, Liquid viscosity dropped to 4mPa.s.

Embodiment 3

[0040] The gel breaker of the present invention is prepared by uniformly mixing 24 g of ethyl acetate, 15.6 g of petroleum ether, and 0.4 g of ferrocene at a temperature of 60° C. to form component A and 60 g of hydrogen peroxide for component B. A high-efficiency positioning dual-action breaker is obtained.

[0041] Mixture A and mixture B of the present invention are added to 100kg of fracturing fluid hydrogel at the same time, quickly mixed and stirred evenly, and injected downhole with a pump. When the downhole temperature is 60°C, after 3 hours of gel breaking, the gel breaking fluid The viscosity dropped to 4mPa.s.

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PUM

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Abstract

The invention discloses a gel breaker with high-efficiency positioning double-effect. The gel breaker is formed by mixing a mixture A and a mixture B according to a mass ratio of 1:1.5, the mixture A is composed of organic iron, fluxing agent and esters, the organic iron accounts for 1% of total mass of the mixture A, the esters account for 50-70% of the total mass of the mixture A, the rest is the fluxing agent, the organic iron is ferrocene, and the fluxing agent is petroleum ether; the mixture B is hydrogen peroxide, and the mixture B accounts for 50-60% of total mass of the gel breaker. The invention further discloses a preparation method of the gel breaker. Fracturing liquid after gel breaking by the gel breaker is low in molecular weight and little in residue, secondary damage to a bottom layer is reduced, and adding amount of the gel breaker is small, so that construction cost is saved; a unique gel breaking mode has higher oxidation and degrading capability, so that the gel breaking process is easy to control, and damage to a formation is reduced to greatest extent.

Description

technical field [0001] The invention belongs to the field of oilfield chemical fracturing fluids, and in particular relates to a high-efficiency positioning dual-function gel breaker and a preparation method thereof. Background technique [0002] In the process of oil and natural gas exploration and development, fracturing is a major measure for increasing production of oil and gas wells and increasing injection of water wells. The main purpose of adding a gel breaker to the fracturing fluid during fracturing construction is that after the liquid carries sand into the fracture, the gel breaker can quickly reduce the viscosity of the fracturing fluid, so that the polymer macromolecules can be decomposed and discharged from the fracture. Small molecules minimize damage to oil caused by water-based gels or emulsified fracturing fluids. However, in conventional fracturing, when the gel breaker is directly in contact with the jelly fracturing fluid, the viscosity of the jelly bo...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/68
CPCC09K8/68C09K2208/26
Inventor 杨晓武王刚霄秋列维李培枝
Owner SHAANXI UNIV OF SCI & TECH
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