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Water-borne composite organic wood preservative, preparation method and application thereof

A wood preservative, water-borne technology, applied in the field of wood preservatives, can solve the problems of high production costs, environmental pollution, etc., achieve the effects of low usage, avoiding large-scale use, and reducing toxicity

Inactive Publication Date: 2015-08-05
NANJING FORESTRY UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

1. In order to solve the problems of high production cost and environmental pollution caused by the existing water-borne wood preservatives that cause environmental pollution due to metal content, and the large use of volatile organic compounds (volatile organic compounds, VOCs) in organic solvent-based wood preservatives; 2. In order to reduce the toxicity to bees and fish, etc., it is more friendly to the environment; 3. The modified triazole compound is used as a fungicide, thereby improving the anti-loss performance and making the use of organic wood preservatives more extensive. Better use effect and longer use time

Method used

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  • Water-borne composite organic wood preservative, preparation method and application thereof
  • Water-borne composite organic wood preservative, preparation method and application thereof
  • Water-borne composite organic wood preservative, preparation method and application thereof

Examples

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Effect test

Embodiment 1

[0023] The water-borne composite organic wood preservative of this embodiment includes the following components in mass percentage: propiconazole 7.18%, tebuconazole 7.22%, imidacloprid 0.72%, cyclohexanone 15%, dimethylformamide 8%, xylene 6%, tristyrylphenol polyoxyethylene ether 11.2%, calcium dodecylbenzenesulfonate 3.8%, and the rest is water.

[0024] The preparation method of embodiment 1: dissolve 37g 97% propiconazole, 38g 95% tebuconazole and 3.7g 97% imidacloprid in 75g cyclohexanone, 40g dimethylformamide and 30g xylene, stir until completely dissolved , add 56g tristyrylphenol polyoxyethylene ether and 19g calcium dodecylbenzenesulfonate, mix uniformly, add 201g water under stirring, continue to stir until material is homogeneous transparent liquid, promptly gets 15.12% (with propane The sum of cycloconazole, tebuconazole and imidacloprid) organic wood preservative (referred to as PTI).

Embodiment 2

[0026] The water-borne composite organic wood preservative of the present embodiment comprises the following components in mass percentage: 14.75% of hexaconazole derivatives, 4.86% of fuconazole derivatives, 0.48% of imidacloprid, 25% of cyclohexanone, 10% of methyl formamide, 5% of xylene, 16% of tristyrylphenol polyoxyethylene ether and 4% of calcium dodecylbenzenesulfonate, and the rest is water.

[0027] The preparation method of embodiment 2: 25g 95% hexaconazole derivative 1, 27g 90% fuconazole derivative and 2.4g 97% imidacloprid are dissolved in 125g cyclohexanone, 50g dimethylformamide and 25g xylene , stir until completely dissolved, add 80g tristyrylphenol polyoxyethylene ether and 20g calcium dodecylbenzenesulfonate, mix evenly, add 156g water under stirring, continue stirring until the material is a homogeneous transparent liquid, to obtain 10.09% (based on the sum of hexaconazole derivative 1, triconazole derivative and imidacloprid) organic wood preservative (H...

Embodiment 3

[0029] The waterborne composite organic wood preservative of this embodiment includes the following components in mass percentage: 22.52% of hexaconazole derivatives, 2.52% of diniconazole derivatives, 0.24% of permethrin, and 15% of cyclohexanone , 10% of dimethylformamide, 5% of xylene, 7.5% of nonylphenol polyoxyethylene ether, 7.5% of castor oil polyoxyethylene ether and 5% of calcium dodecylbenzenesulfonate, and the rest is water.

[0030] The preparation method of embodiment 3: 14g 90% hexaconazole derivative 2, 14g 90% diniconazole derivative and 1.2g 97% permethrin are dissolved in 75g cyclohexanone, 50g dimethylformamide and 25g dimethicone In toluene, stir until completely dissolved, add 37.5g nonylphenol polyoxyethylene ether, 37.5g castor oil polyoxyethylene ether and 25g calcium dodecylbenzenesulfonate, mix well, add 221g water under stirring, continue stirring Until the material is a homogeneous transparent liquid, 6.24% (based on the sum of hexaconazole derivati...

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Abstract

The invention relates to a water-borne composite organic wood preservative, a preparation method and application thereof. The wood preservative comprises the following components by mass: 5-15% of an organic insecticide and bactericide, 25-40% of an organic solvent, 15-20% of a surfactant, and the balance water. The organic insecticide and bactericide is at least one of a triazole compound, 3-iodo-2-propynyl-butyl-carbamate (called IPBC for short), imidacloprid and pyrethroid substances. The organic solvent is at least one of cyclohexanone, dimethylformamide (DMF), and xylene. The wood preservative provided by the invention has good antiseptic and mould proof effects, low dosage, good loss resistance and environmental friendliness, and can be widely used in indoor furniture, indoor decoration materials, outdoor gardens, constructions and the like.

Description

technical field [0001] The invention belongs to the field of wood preservatives, and relates to a water-borne composite organic wood preservative, a preparation method thereof, and an application in wood preservatives. Background technique [0002] Water-borne preservatives are the most widely used wood preservatives in the world. Commonly used are chromium copper arsenate (CCA), copper quaternary ammonium (ACQ), copper azole (CA), etc., but they contain chromium, arsenic and Copper and other elements will cause certain environmental pollution during the production and use of preservative wood, and its preservative wood products are not suitable for contact with humans and animals, and many countries have restricted their use. Therefore, metal-free water-borne organic wood preservatives have become the focus of development of new wood preservatives. Compared with CCA, ACQ, etc., water-borne organic wood preservatives are environmentally friendly and easy to recycle. However...

Claims

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Application Information

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IPC IPC(8): A01N51/00A01N53/08A01N53/04A01P3/00B27K3/50A01N43/653
Inventor 程康华顾晓利张丽丽王蓓王丽何深远
Owner NANJING FORESTRY UNIV
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