Fluorine-containing iodo-hydrocarbon composition and preparation method thereof

A technology of composition and iodocarbon, which is applied in the field of refrigerant composition and its preparation, can solve the problems of poor compatibility, uneven dispersion, and poor flame retardant effect of tetrafluoropropene, achieve good flame retardant effect, and simplify preparation Process, the effect of a wide range of dissolution

Inactive Publication Date: 2015-05-06
JUHUA GROUP TECH CENT
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Existing methods all use the addition of flame retardants or non-flammable components to improve flame retardancy, because the compatibility between flame retardants and HFO1234yf tetrafluoropropene is poor, the dispersion is uneven, and the flame retardant effect is poor. At the same time, the prepared Refrigerant products have a higher GWP than HFO1234yf single working substance, and still have a great impact on the environment

Method used

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  • Fluorine-containing iodo-hydrocarbon composition and preparation method thereof
  • Fluorine-containing iodo-hydrocarbon composition and preparation method thereof
  • Fluorine-containing iodo-hydrocarbon composition and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] A kind of fluorine-containing iodohydrocarbon composition, by every part of 1Kg, its raw material formula is as follows:

[0031]

[0032] Its preparation method is as follows:

[0033] The preparation of step (1) ionic liquid flame retardant:

[0034] According to the ratio, add 18.4 parts of heptafluoro-2-butene and 1.6 parts of 1-butyl-3-methylimidazolium tetrafluoroborate ionic liquid into a 200L reactor, and mix them in the liquid state for 15 hours to obtain the ionic liquid flame retardant.

[0035] Step (2) mixing:

[0036] Add the ionic liquid flame retardant prepared in step (1) into a 200L turbulent flow circulating tank, then add 70 parts of 2,3,3,3-tetrafluoropropene (HFO1234yf), 9.97 parts of trifluoroiodomethane, 0.03 parts of 1 , 5-hexadienol, mixed in turbulent flow in liquid state for 8h to obtain the product. The number is WN-1.

Embodiment 2

[0038] A kind of fluorine-containing iodohydrocarbon composition, by every part of 1Kg, its raw material formula is as follows:

[0039]

[0040]

[0041] Its preparation method is as follows:

[0042] The preparation of step (1) ionic liquid flame retardant:

[0043] According to the ratio, add 27 parts of heptafluoro-2-butene and 2.99 parts of 1-butyl-3-methylimidazolium tetrafluoroborate ionic liquid into a 200L reactor, and mix them in the liquid state for 10 hours to obtain the ionic liquid flame retardant.

[0044] Step (2) mixing:

[0045] Add the ionic liquid flame retardant prepared in step (1) into a 200L turbulent flow circulating tank, then add 60 parts of 2,3,3,3-tetrafluoropropene (HFO1234yf), 10 parts of trifluoroiodomethane, 0.01 part of 1 , 5-hexadienol, mixed in turbulent flow circulation for 5h in the liquid state to obtain the product, numbered WN-2.

Embodiment 3

[0047] A kind of fluorine-containing iodohydrocarbon composition, by every part of 1Kg, its raw material formula is as follows:

[0048]

[0049] Its preparation method is as follows:

[0050] The preparation of step (1) ionic liquid flame retardant:

[0051] According to the ratio, add 16.1 parts of heptafluoro-2-butene and 2.85 parts of 1-butyl-3-methylimidazolium tetrafluoroborate ionic liquid into a 200L reactor, and mix them in the liquid state for 20 hours to obtain the ionic liquid flame retardant.

[0052] Step (2) mixing:

[0053] Add the ionic liquid flame retardant prepared in step (1) into a 200L turbulent flow circulating kettle, then add 80 parts of 2,3,3,3-tetrafluoropropene (HFO1234yf), 1 part of trifluoroiodomethane, 0.05 part of 1 , 5-hexadienol, mixed in turbulent flow circulation for 10h in the liquid state to obtain the product, numbered WN-3.

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Abstract

The invention discloses a fluorine-containing iodo-hydrocarbon composition. The composition comprises the following components in parts by weight: 16.1-27.6 parts of heptafluoro-2-butene, 1.6-3.6 parts of 1-butyl-3-methylimidazolium tetrafluoroborate ionic liquid, 60-80 parts of 2,3,3,3-tetrafluoropropene, 0-10 parts of iodotrifluoromethane and 0-0.06 part of 1,5-hexadienol. The invention also discloses a preparation method of the fluorine-containing iodo-hydrocarbon composition. The fluorine-containing iodo-hydrocarbon composition has the advantages of simple process, low cost, environment friendliness and good product flame retardance.

Description

technical field [0001] The invention relates to a refrigerant composition and a preparation method thereof, in particular to a fluorine-containing iodohydrocarbon composition and a preparation method thereof. Background technique [0002] As a single refrigerant, HFO-1234yf has excellent environmental parameters, its global warming potential (GWP) is 4, ozone depletion potential (ODP) is 0, and its life cycle climate performance (LCCP) is lower than that of HFC-134a. Atmospheric decomposition products are the same as HFC-134a. And its system performance is better than HFC-134a. If HFO-1234yf is used to replace HFC-134a refrigerant, automobile manufacturers can continue to use the original mobile air-conditioning (Mobile Air-Conditioning, MAC) system. Therefore, HFO-1234yf is considered to be a potential substitute for a new generation of automotive refrigerants. It has been accepted by automakers in Western Europe and will be gradually promoted in 2011. The GWP and atmosp...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K5/04
CPCC09K5/04
Inventor 王金明沈凌云吴四清
Owner JUHUA GROUP TECH CENT
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