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Visible light responded photocatalyst Li2La3NdSb2O12 and preparation method thereof

A photocatalyst and visible light technology, which is applied in the field of inorganic photocatalytic materials, can solve the problems of limited photocatalyst types, low photoconversion efficiency, and difficult synthesis, and achieve a wide range of visible light response frequencies, simple preparation methods, and high photoconversion efficiency. Effect

Inactive Publication Date: 2015-03-25
GUILIN UNIVERSITY OF TECHNOLOGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For example, niobate photocatalyst Pb 3 Nb 4 o 13 、BiNbO 4 and Bi 2 MbO 7 (M=Al, Ga, In, Y, rare earth elements and Fe) etc. and niobium potassium composite oxide photocatalysts such as KNbO 3 , KNb 3 o 8 、K 4 Nb 6 o 17 and K 6 Nb 10.6 o 30 have good photocatalytic performance, but their intrinsic photocatalytic effect is weak or inactive in the visible light range.
[0005] Although photocatalysis research has been carried out for several years, most of the exploration and development of visible light-responsive photocatalysts are based on experience summaries obtained through a large number of experiments. Therefore, the types of photocatalysts reported to respond to visible light are still limited, and there are problems such as low photoconversion efficiency, difficult synthesis, poor stability, and narrow spectral response range. Research and development of new preparations High-efficiency photocatalysts with simple methods and broad-band visible light response are difficult problems that scientists in the field have been eager to solve but have always been difficult to achieve, which largely limits the wide application and development of photocatalysts.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] (1) 99.9% analytically pure chemical raw material Li 2 CO 3 、La 2 o 3 、Nd 2 o 3 and Sb 2 o 5 The raw powder of Li 2 La 3 NdSb 2 o 12 The composition weighs the ingredients.

[0020] (2) Mix the raw materials prepared in step (1), put them into a ball mill jar, add zirconia balls and absolute ethanol, ball mill for 8 hours, mix and grind until fine, take it out and dry it, and pass through a 200-mesh sieve.

[0021] (3) Pre-fire the uniformly mixed powder in step (2) at 700°C, keep it warm for 6 hours, cool it down to room temperature naturally, and then pulverize it through a ball mill to make the average particle diameter smaller than 2 μm, that is, Li 2 La 3 NdSb 2 o 12 powder.

[0022] The prepared photocatalyst can remove 97.1% of methyl orange in 60 minutes under the irradiation of visible light with a wavelength greater than 420nm.

Embodiment 2

[0024] (1) 99.9% analytically pure chemical raw material Li 2 CO 3 、La 2 o 3 、Nd 2 o 3 and Sb 2 o 5 The raw powder of Li 2 La 3 NdSb 2 o 12 The composition weighs the ingredients.

[0025] (2) Mix the raw materials prepared in step (1), put them into a ball mill jar, add zirconia balls and absolute ethanol, ball mill for 8 hours, mix and grind until fine, take it out and dry it, and pass through a 200-mesh sieve.

[0026](3) Pre-fire the uniformly mixed powder in step (2) at 730°C, keep it warm for 6 hours, cool it down to room temperature naturally, and then pulverize it through a ball mill to make the average particle diameter smaller than 2 μm, that is, Li 2 La 3 NdSb 2 o 12 powder.

[0027] The prepared photocatalyst can remove 97.9% of methyl orange in 60 minutes under the irradiation of visible light with a wavelength greater than 420nm.

Embodiment 3

[0029] (1) 99.9% analytically pure chemical raw material Li 2 CO 3 , La 2 o 3 、Nd 2 o 3 and Sb 2 o 5 The raw powder of Li 2 La 3 NdSb 2 o 12 The composition weighs the ingredients.

[0030] (2) Mix the raw materials prepared in step (1), put them into a ball mill jar, add zirconia balls and absolute ethanol, ball mill for 8 hours, mix and grind until fine, take it out and dry it, and pass through a 200-mesh sieve.

[0031] (3) Pre-fire the uniformly mixed powder in step (2) at 750°C, keep it warm for 6 hours, cool it down to room temperature naturally, and then pulverize it through a ball mill to make the average particle diameter smaller than 2 μm, that is, Li 2 La 3 NdSb 2 o 12 powder.

[0032] The prepared photocatalyst can remove 97.6% of methyl orange in 60 minutes under the irradiation of visible light with wavelength greater than 420nm.

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Abstract

The invention discloses a wideband and efficient visible light responded photocatalyst Li2La3NdSb2O12 and the preparation method thereof. The chemical constitution formula of the photocatalyst is Li2La3NdSb2O12. The invention further discloses a preparation method of the aforementioned material. The obtained photocatalyst has the advantages of wide spectral response range, high light conversion efficiency, good stability, and the like. Under the irradiation of visible light, the photocatalyst has effects of resolving harmful chemical substances, organic biomass, and sterilization; additionally, the preparation method is simple, the synthesizing temperature is low, and the photocatalyst is applicable to industrial production and application.

Description

technical field [0001] The invention relates to a photocatalyst Li with visible light response 2 La 3 NdSb 2 o 12 The invention and a preparation method thereof belong to the field of inorganic photocatalytic materials. Background technique [0002] With the development of society and economy, people pay more and more attention to energy and ecological environment. Solving the problems of energy shortage and environmental pollution is an urgent need to achieve sustainable development, improve people's quality of life and ensure national security. [0003] Since the late 1970s, people have proposed the use of photocatalysts to decompose organic substances such as pesticides and odorous substances in water and the atmosphere, and self-cleaning of solid surfaces coated with photocatalysts. The principle of photocatalytic reaction is that after the photocatalyst absorbs photons higher than its bandgap energy, holes and electrons are generated, and these holes and electrons u...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J23/18
Inventor 巩美露苏聪学覃杏柳
Owner GUILIN UNIVERSITY OF TECHNOLOGY
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