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Visible light-responsive photocatalyst licu 3 nbwo 9 and its preparation method

A photocatalyst and visible light technology, applied in chemical instruments and methods, physical/chemical process catalysts, metal/metal oxide/metal hydroxide catalysts, etc., can solve the problem of limited types of photocatalysts, low light conversion efficiency and difficult synthesis and other problems, to achieve the effects of wide visible light response frequency range, simple preparation method and high light conversion efficiency

Active Publication Date: 2016-08-24
SHANDONG XINGQIANG CHEM IND TECH RES INST CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For example, niobate photocatalyst Pb 3 Nb 4 o 13 、BiNbO 4 and Bi 2 MbO 7 (M=Al, Ga, In, Y, rare earth elements and Fe) etc. and niobium potassium composite oxide photocatalysts such as KNbO 3 , KNb 3 o 8 、K 4 Nb 6 o 17 and K 6 Nb 10.6 o 30 have good photocatalytic performance, but their intrinsic photocatalytic effect is weak or inactive in the visible light range.
[0005] Although photocatalysis research has been carried out for several years, most of the exploration and development of visible light-responsive photocatalysts are based on experience summaries obtained through a large number of experiments. Therefore, the types of photocatalysts reported to respond to visible light are still limited, and there are problems such as low photoconversion efficiency, difficult synthesis, poor stability, and narrow spectral response range. Research and development of new preparations High-efficiency photocatalysts with simple methods and broad-band visible light response are difficult problems that scientists in the field have been eager to solve but have always been difficult to achieve, which largely limits the wide application and development of photocatalysts.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] (1) 99.9% analytically pure chemical raw material Li 2 CO 3 , CuO, Nb 2 o 5 and WO 3 The raw powder of LiCu 3 wxya 9 The composition weighs the ingredients.

[0019] (2) Mix the raw materials prepared in step (1), put them into a ball mill jar, add zirconia balls and absolute ethanol, ball mill for 8 hours, mix and grind until fine, take it out and dry it, and pass through a 200-mesh sieve.

[0020] (3) Pre-fire the uniformly mixed powder in step (2) at 1000°C, keep it warm for 6 hours, cool it down to room temperature naturally, and then pulverize it with a ball mill to make the average particle diameter smaller than 2 μm, that is, LiCu 3 wxya 9 powder.

[0021] The prepared photocatalyst can remove 97.9% of methyl orange in 60 minutes under the irradiation of visible light with a wavelength greater than 420nm.

Embodiment 2

[0023] (1) 99.9% analytically pure chemical raw material Li 2 CO 3 , CuO, Nb 2 o 5 and WO 3 The raw powder of LiCu 3 wxya 9 The composition weighs the ingredients.

[0024] (2) Mix the raw materials prepared in step (1), put them into a ball mill jar, add zirconia balls and absolute ethanol, ball mill for 8 hours, mix and grind until fine, take it out and dry it, and pass through a 200-mesh sieve.

[0025] (3) Pre-fire the uniformly mixed powder in step (2) at 1020°C, keep it warm for 6 hours, cool it down to room temperature naturally, and then pulverize it with a ball mill to make the average particle diameter smaller than 2μm, that is, LiCu 3 wxya 9 powder.

[0026] The prepared photocatalyst can remove 98.9% of methyl orange in 60 minutes under the irradiation of visible light with a wavelength greater than 420nm.

Embodiment 3

[0028] (1) 99.9% analytically pure chemical raw material Li 2 CO 3 , CuO, Nb 2 o 5 and WO 3 The raw powder of LiCu 3 wxya 9 The composition weighs the ingredients.

[0029] (2) Mix the raw materials prepared in step (1), put them into a ball mill jar, add zirconia balls and absolute ethanol, ball mill for 8 hours, mix and grind until fine, take it out and dry it, and pass through a 200-mesh sieve.

[0030] (3) Pre-fire the uniformly mixed powder in step (2) at 1050°C, keep it warm for 6 hours, cool it down to room temperature naturally, and then pulverize it with a ball mill to make the average particle diameter smaller than 2 μm, and then you can get LiCu 3 wxya 9 powder.

[0031]The prepared photocatalyst can remove 98.6% of methyl orange in 60 minutes under the irradiation of visible light with a wavelength greater than 420nm.

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Abstract

The invention discloses a wide-frequency and efficient photocatalyst LiCu3NbWO9 with visible light response and a preparation method thereof. The chemical composition formula of the photocatalyst is LiCu3NbWO9. The invention further discloses a preparation method of the material. The photocatalyst obtained by the preparation method disclosed by the invention has the advantages of wide spectral response range, high photoconversion efficiency, good stability and the like. The photocatalyst has the effects of decomposing harmful chemical substances and organic biomass, and sterilizing under the irradiation of visible light; and in addition, the preparation method is simple, the synthesis temperature is low, the cost is low, and the preparation method is suitable for industrial production and application.

Description

technical field [0001] The invention relates to a photocatalyst LiCu responsive to visible light 3 wxya 9 The invention and a preparation method thereof belong to the field of inorganic photocatalytic materials. Background technique [0002] With the development of society and economy, people pay more and more attention to energy and ecological environment. Solving the problems of energy shortage and environmental pollution is an urgent need to achieve sustainable development, improve people's quality of life and ensure national security. [0003] Since the late 1970s, people have proposed the use of photocatalysts to decompose organic substances such as pesticides and odorous substances in water and the atmosphere, and self-cleaning of solid surfaces coated with photocatalysts. The principle of photocatalytic reaction is that after the photocatalyst absorbs photons higher than its bandgap energy, holes and electrons are generated, and these holes and electrons undergo oxi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J23/888
Inventor 方维双苏和平李洁
Owner SHANDONG XINGQIANG CHEM IND TECH RES INST CO LTD
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