Thin Polarizer, method for manufacturing same, and polarizing plate and display device comprising thin polarizer
A technology for display devices and polarizers, applied in optics, optical elements, polarizing elements, etc., can solve problems such as difficulty in achieving uniform physical properties, deterioration of physical properties of polyvinyl alcohol films, etc., and achieve excellent productivity and excellent optical properties.
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Embodiment 1
[0100] Three sheets of unstretched polyvinyl alcohol-based film and two sheets of unstretched polyurethane film were alternately stacked on each other without using a medium material, thereby forming an unstretched film laminate having the following structure : Unstretched polyvinyl alcohol-based film / unstretched polyurethane film / unstretched polyvinyl alcohol-based film / unstretched polyurethane film / unstretched polyvinyl alcohol-based film.
[0101] In this case, as the unstretched polyvinyl alcohol-based film, a PE30-grade polyvinyl alcohol-based film (thickness: 30 μm) of Kuraray Corporation was used, and allowed to stand in a pure solution at 25° C. Swelling was performed for 15 seconds, and then a dyeing process was performed at a temperature of 25°C for 60 seconds using an iodine solution having a concentration of 0.3 wt%.
[0102] On the other hand, as the unstretched polyurethane film, a film produced by a thermoplastic polyurethane resin obtained by reacting diphenylm...
Embodiment 2
[0105] Two sheets of unstretched polyvinyl alcohol-based films and two sheets of unstretched polyurethane films were alternately stacked on each other without using a medium material, and in addition to forming an unstretched polyvinyl alcohol-based film with In addition to the unstretched film laminate of the structure of / unstretched polyurethane film / unstretched polyvinyl alcohol-based film / unstretched polyurethane film, by the same method as in Example 1, Two thin-film polarizers with a thickness of 5 to 7 μm.
Embodiment 3
[0107] A 4 wt% aqueous solution was prepared by dissolving polyvinyl alcohol (average degree of polymerization: 2000, saponification degree: 94%, manufactured by Nippon Synthetic Chemicals Co., Ltd.) containing acetoacetyl group (5 wt%) in pure water. Here, with respect to 100 parts by weight of polyvinyl alcohol, 6.7 parts by weight of a titanium amine complex crosslinking agent (TYZOR TE produced by DuPont) was added and stirred to mix, whereby an adhesive A was produced.
[0108] Coating adhesive A to a thickness of 100 nm on both side surfaces of an unstretched polyurethane film, and then bonding two unstretched polyvinyl alcohol-based films to produce an unstretched polyvinyl alcohol-based Film laminate 1 of the structure of vinyl alcohol film / unstretched polyurethane film / unstretched polyvinyl alcohol-based film. Adhesive A is coated to a thickness of 100 nm on one side surface of another unstretched polyurethane film, and then a piece of unstretched polyvinyl alcohol-ba...
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