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Reinforced ABS resin composition suitable for electroplating, and preparation method and application thereof

A technology of ABS resin and composition, applied in the polymer field, can solve the problems of low rigidity of ABS plastic and complicated processing process, and achieve the effects of good dimensional stability, high mechanical strength and improved processing efficiency

Active Publication Date: 2014-09-17
KINGFA SCI & TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, since ABS plastic is a non-conductor, a conductive layer must be attached to ABS plastic before electroplating, which requires several steps such as roughening, neutralization, sensitization, activation, and chemical plating, and the processing process is relatively complicated.
In addition, due to the low rigidity of ABS plastic, for some plastic electroplating parts with high mechanical strength requirements, such as electroplated car door handles and TV support bases and other plastic electroplating parts, it is difficult for ordinary ABS plastic substrates to meet the increasingly high requirements. Performance requirements for plastic electroplating products

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1~6 and comparative example 1~2

[0037] Weigh the ABS resin, dispersant, lubricant, primary antioxidant and auxiliary antioxidant according to the weight percentage in Table 1, mix them uniformly in a high-speed mixing mixer or enter the twin-screw extrusion through a metering feeder separately In the extruder, the carbon fiber is added in the sixth zone of the screw through the side feeding system of the twin-screw extruder; The temperature of the head is preferably the first zone temperature 80 o C. The temperature in the second zone is 140 o C. The temperature in the third zone is 200 o C. The temperature in the fourth zone is 210 o C. The temperature in the fifth zone is 220 o C. The temperature in the sixth zone is 230 o C. The temperature in the seventh zone is 220 o C. The temperature in the eighth zone is 230 o C. The temperature in the ninth zone is 230 o C, head temperature 230 o C, the screw speed is preferably 350rpm, and the aspect ratio of the twin-screw extruder is 40. Under the conveyi...

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PUM

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Abstract

The invention discloses a reinforced ABS resin composition suitable for electroplating. The composition comprises 85-96wt% of an ABS resin, 3-10wt% of a carbon fiber, 0.1-1.0wt% of a dispersant, 0.01-1.0wt% of a lubricant, 0.1-1.0wt% of a main antioxidant and 0.5-2.0wt% of an auxiliary antioxidant. The reinforced ABS resin composition suitable for electroplating can reduce the linear thermal expansion coefficient of a plastic electroplating product, has an above 50% lower linear thermal expansion coefficient than a common ABS resin, and can well meet the performance requirements of the plastic electroplating product. The adoption of the carbon fiber enhances the conductivity of the ABS resin, effectively increases the bonding force between the ABS resin and an electroplating layer, shortens the pretreatment time of electroplating, improves the electroplating production processing efficiency, and is in favor of the electroplating production. The reinforced ABS resin composition suitable for electroplating has high mechanical strength and good dimensional stability.

Description

technical field [0001] The invention relates to the field of macromolecules, in particular to a reinforced ABS resin composition suitable for electroplating, a preparation method and application thereof. Background technique [0002] In recent years, plastic electroplating has been widely used in the decoration of plastic parts, and ABS plastic is the most widely used one in plastic electroplating parts. ABS plastic is a terpolymer of acrylonitrile (A), butadiene (B), and styrene (S). For electroplating-grade ABS plastics, the content of butadiene has a great influence on electroplating, and generally should be controlled at 18% to 23%, and the binding force with the electroplating layer is the best. However, since ABS plastic is a non-conductor, a conductive layer must be attached to ABS plastic before electroplating, which requires several steps such as roughening, neutralization, sensitization, activation, and electroless plating, and the processing process is relatively...

Claims

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Application Information

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IPC IPC(8): C08L55/02C08K7/06C08K3/04C08K5/134C08K5/526B29C47/92B29C48/92
CPCB29B9/12B29C2947/92761B29C2947/9298B29B7/46B29B9/06B29B9/14B29C2947/92485B29C47/92B29B7/72B29C2947/92266B29C48/40B29C48/92B29C2948/92266B29C2948/92485B29C2948/9259B29C2948/92704B29C2948/92761B29C2948/92895B29C2948/92904B29C2948/9298
Inventor 何超雄王亮程庆袁绍彦付锦锋陈日平王林
Owner KINGFA SCI & TECH CO LTD
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