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Synthesis of sustained-release fertilizer by resource utilization of phosphorus wastewater

A technology of resource utilization and wastewater, applied in the field of chemical fertilizer industry and functional nanometer, can solve the problems of general treatment effect and difference in treatment effect, and achieve the effect of good environmental protection effect.

Active Publication Date: 2014-09-10
JIANGSU LONGCHANG CHEM +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are many types of phosphorus removal agents used in chemical methods, and the treatment effects are also quite different.
[0004] At present, there are a lot of domestic research on the properties and effects of phosphorus removal agents and the development and utilization of new agents, but there are few studies on the effective treatment of high-concentration phosphorus-containing pesticide wastewater, and the treatment effect is average.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] Recycled utilization of phosphorus-containing wastewater to synthesize slow-release fertilizers: using phosphorus in phosphorus-containing wastewater as the measurement standard, input calcium chloroaluminate hydrate with a calcium-to-aluminum ratio of 2 to 4:1 according to the molar ratio, and set phosphorus and water The molar ratio of calcium chloroaluminate input is phosphorus: calcium chloroaluminate hydrate=1:0.2~5, the reaction is stirred at room temperature, the reaction time is controlled to be 8 to 96 hours, the column is passed at room temperature, and the residence time is controlled to 4 After ~24 hours, the precipitate is separated, and the precipitate is directly drained and discharged and dried. The drying time is set to 4 hours and the drying temperature is 80 to 500°C to obtain the superphosphate sustained-release agent.

[0020] According to the characteristics of hydrated calcium chloroaluminate and the phosphorus content of 200mg / l in water, it is deter...

Embodiment 2

[0022] Use phosphorus wastewater as a resource to synthesize slow-release fertilizers: take the phosphorus in the phosphorus wastewater as the measurement standard, and input the hydrated calcium chloroaluminate with a calcium-to-aluminum ratio of 1.5-6:1 according to the molar ratio, and set the phosphorus and water in the phosphorus-containing wastewater The molar ratio of calcium chloroaluminate input is phosphorus: calcium chloroaluminate hydrate=1:1~3, the reaction is stirred at room temperature, the reaction time is controlled to be 12 to 48 hours, the column is passed at room temperature, and the residence time is controlled to 8 After ~12 hours, the precipitate is separated, and the precipitate is directly drained and discharged and dried. The drying time is set to 8 hours and the drying temperature is 120 to 270°C to obtain the superphosphate sustained-release agent.

[0023] Based on the superphosphate slow-release fertilizer of this embodiment, the waste water is treate...

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Abstract

The invention discloses synthesis of a sustained-release fertilizer by resource utilization of phosphorus wastewater. The synthesis is characterized by comprising the following steps: by taking the content of phosphorus in phosphorus-containing wastewater as a measuring standard, feeding hydrated calcium chloroaluminate according to a mole ratio, stirring to react at normal temperature while controlling the reaction time to be 8-96 hours, passing through a column at normal temperature while controlling the retaining time to be 4-24 hours, separating precipitate, directly draining off the precipitate, discharging, and drying while setting the drying time to be 4-12 hours and the drying temperature to be 80-500 DEG C, thereby preparing the sustained-release fertilizer, namely, a calcium superphosphate sustained-release agent. According to the synthesis, hydrated calcium chloroaluminate is adopted to treat the phosphorus-containing wastewater to prepare the novel high-efficiency sustained-release fertilizer, namely, the calcium superphosphate sustained-release agent, a good environment-friendly effect is achieved, the wastewater is reused, the treated phosphorus-containing wastewater can be discharged without pollution, the content of phosphorus in supernatant of the treated wastewater is about 2.0mg / L, and the removal rate can be greater than 99%.

Description

technical field [0001] The invention relates to a slow-release chemical fertilizer synthesized by utilizing phosphorus-containing waste water as a resource, and belongs to the fields of environmental protection, reclaimed water reuse, chemical fertilizer industry, and functional nanometer technology. Background technique [0002] Pesticides have made an important contribution to improving crop yields, but a large amount of high-concentration wastewater will be produced during the production of pesticides, among which phosphorus-containing pesticide wastewater will be directly discharged into water bodies without treatment, which will lead to eutrophication of water bodies and cause water pollution. , water pollution has become a global environmental problem. Therefore, the treatment of phosphorus-containing pesticide wastewater should be strengthened. [0003] There is no mature treatment process in China that can effectively treat high-concentration phosphorus-containing p...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B15/16C05B1/02C05G3/00
Inventor 赵雪松胡程奕佘卫民郑南峰佘道才
Owner JIANGSU LONGCHANG CHEM
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