Synthesis of sustained-release fertilizer by resource utilization of phosphorus wastewater
A technology of resource utilization and wastewater, applied in the field of chemical fertilizer industry and functional nanometer, can solve the problems of general treatment effect and difference in treatment effect, and achieve the effect of good environmental protection effect.
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Embodiment 1
[0019] Recycled utilization of phosphorus-containing wastewater to synthesize slow-release fertilizers: using phosphorus in phosphorus-containing wastewater as the measurement standard, input calcium chloroaluminate hydrate with a calcium-to-aluminum ratio of 2 to 4:1 according to the molar ratio, and set phosphorus and water The molar ratio of calcium chloroaluminate input is phosphorus: calcium chloroaluminate hydrate=1:0.2~5, the reaction is stirred at room temperature, the reaction time is controlled to be 8 to 96 hours, the column is passed at room temperature, and the residence time is controlled to 4 After ~24 hours, the precipitate is separated, and the precipitate is directly drained and discharged and dried. The drying time is set to 4 hours and the drying temperature is 80 to 500°C to obtain the superphosphate sustained-release agent.
[0020] According to the characteristics of hydrated calcium chloroaluminate and the phosphorus content of 200mg / l in water, it is deter...
Embodiment 2
[0022] Use phosphorus wastewater as a resource to synthesize slow-release fertilizers: take the phosphorus in the phosphorus wastewater as the measurement standard, and input the hydrated calcium chloroaluminate with a calcium-to-aluminum ratio of 1.5-6:1 according to the molar ratio, and set the phosphorus and water in the phosphorus-containing wastewater The molar ratio of calcium chloroaluminate input is phosphorus: calcium chloroaluminate hydrate=1:1~3, the reaction is stirred at room temperature, the reaction time is controlled to be 12 to 48 hours, the column is passed at room temperature, and the residence time is controlled to 8 After ~12 hours, the precipitate is separated, and the precipitate is directly drained and discharged and dried. The drying time is set to 8 hours and the drying temperature is 120 to 270°C to obtain the superphosphate sustained-release agent.
[0023] Based on the superphosphate slow-release fertilizer of this embodiment, the waste water is treate...
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