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A kind of plant modified polymeric putty adhesive and preparation method thereof

An adhesive and putty technology, which is used in the field of plant-modified polymer putty adhesive and its preparation, can solve the problem of bonding strength (the adhesion cannot meet the requirements, the construction performance of the putty powder is affected, and the bonding strength has little effect). And other problems, to achieve the effect of not easy to empty drum to remove powder, improve lubricity, good environmental performance

Active Publication Date: 2016-06-08
湖北优力帮生态涂料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Adhesive is an indispensable part of putty mixing. It plays a decisive role in the strength, construction and durability of putty powder. The quality of adhesive determines the quality of putty powder. The existing adhesive There are mainly two kinds of liquid and powder. The powdery adhesive is commonly used tapioca starch or corn starch. Although tapioca starch has a strong bonding effect, if the amount added is large, it will affect the construction performance of the putty powder, and it is not easy to scrape. If the amount of addition is small, the bonding strength (adhesion) will not meet the requirements, which is not conducive to compounding; while corn starch has little effect on the bonding strength, the putty powder made with these two rubber powders will either have a short service life, It is easy to remove powder from empty drums, or the construction performance is poor; liquid adhesives are generally more effective than rubber powders in use, and are easy to use, but the existing liquid adhesives are troublesome in manufacturing process, high in cost, and difficult to process. Complex, formaldehyde pollution, low environmental performance

Method used

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  • A kind of plant modified polymeric putty adhesive and preparation method thereof
  • A kind of plant modified polymeric putty adhesive and preparation method thereof
  • A kind of plant modified polymeric putty adhesive and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] A kind of preparation method of plant-modified polymerization putty adhesive is specifically as follows:

[0030] (1) Using konjac and potato as the main ingredients, first wash them to remove impurities and peel them, weigh 33 kg of konjac and 67 kg of potato, grind and mix them to form a mixed plant material of konjac and potato, and then Add 0.1 kg of monochloroacetic acid, 0.1 kg of soda ash and 180 kg of deionized water in sequence, and react for 20 to 40 minutes at 1 to 2 atmospheres and 100 to 130°C to form a mixed glue;

[0031] (2) Mix polyvinyl alcohol and deionized water at a mass ratio of 2:98, boil at 95-98°C for 1-2 hours, and then cool naturally to form a transparent gel-like liquid, that is, polyvinyl alcohol with a concentration of 2%. Aqueous solution of vinyl alcohol;

[0032] (3) Add 10 kilograms of 2% polyvinyl alcohol aqueous solution, 0.11 kilograms of food-grade preservatives and 3 kilograms of carboxymethyl cellulose to the mixed solution forme...

Embodiment 2

[0034] A kind of preparation method of plant-modified polymerization putty adhesive is specifically as follows:

[0035] (1) Using konjac and potato as the main ingredients, first wash them to remove impurities and peel them, weigh 50 kg of konjac and 150 kg of potato, grind and mix them to form a mixed plant material of konjac and potato, and then Add 0.6 kg of trichloroacetic acid, 0.6 kg of soda ash and 440 kg of deionized water in sequence, and react for 20 to 40 minutes at 1 to 2 atmospheres and 100 to 130°C to form a mixed glue;

[0036] (2) Mix polyvinyl alcohol and deionized water at a mass ratio of 2:98, boil at 95-98°C for 1-2 hours, and then cool naturally to form a transparent gel-like liquid, that is, polyvinyl alcohol with a concentration of 2%. Aqueous solution of vinyl alcohol;

[0037] (3) Add 50 kilograms of 2% polyvinyl alcohol aqueous solution, 0.42 kilograms of food-grade preservatives and 3 kilograms of carboxymethyl cellulose to the mixed solution forme...

Embodiment 3

[0039] A kind of preparation method of plant-modified polymerization putty adhesive is specifically as follows:

[0040] (1) Using konjac and potato as the main ingredients, first wash them to remove impurities and peel them, weigh 25 kg of konjac and 75 kg of potato, grind and mix them to form a mixed plant material of konjac and potato, and then Add 0.2 kg of monochloroacetic acid, 0.2 kg of soda ash and 200 kg of deionized water in sequence, and react for 20 to 40 minutes at 1 to 2 atmospheres and 100 to 130 ° C to form a mixed glue;

[0041] (2) Mix polyvinyl alcohol and deionized water at a mass ratio of 2:98, boil at 95-98°C for 1-2 hours, and then cool naturally to form a transparent gel-like liquid, that is, polyvinyl alcohol with a concentration of 2%. Aqueous solution of vinyl alcohol;

[0042] (3) Add 18 kg of 2% polyvinyl alcohol aqueous solution, 0.16 kg of food-grade preservative and 1 kg of carboxymethyl cellulose to the mixed solution formed in step (1) and mi...

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Abstract

The invention provides a putty adhesive for plant modified polymerization and a preparation method thereof. The putty adhesive is prepared by the following steps: by taking konjac and potatoes as main materials, respectively cleaning and removing impurities, weighing according to the mass ratio of 1:(2-3) after shelling; orderly adding a crosslinker, sodium carbonate and water after crushing and mixing, and reacting under 1-2 atmosphere at 100-130 DEG C for 20-40 minutes to form a mixed adhesive solution; orderly adding polyvinyl alcohol aqueous solution of which the concentration is 2%, a preservative and carboxymethyl cellulose to mix and stir, wherein 0.1-0.3 parts of crosslinkers, 0.1-0.3 parts of sodium carbonate, 180-220 parts of water, 10-25 parts of 2% polyvinyl alcohol aqueous solution, 0.11-0.21 parts of preservatives and 1-3 parts of carboxymethyl cellulose are added to per 100 parts of mixed plant raw materials; the obtained putty adhesive for plant modified polymerization takes natural plants as raw materials, and is free of poison, free of formaldehyde pollution, free of harm to a human body, low in cost, simple in procedure, and convenient to use.

Description

technical field [0001] The invention relates to a novel putty powder adhesive, in particular to a plant-modified polymerized putty adhesive and a preparation method thereof. Background technique [0002] Putty is a kind of building material used in a large amount in architectural decoration. It is a decoration material that can repair and smooth the wall surface to achieve a smooth and delicate effect. It is mainly composed of filler (calcium carbonate), binder (glue or powder), solvent ( water or other solvents) and additives (auxiliary). At present, the putty materials used for decoration mainly include on-site mixed putty powder (such as polyvinyl urea-formaldehyde glue + calcium carbonate powder + cooked rubber powder, etc.), finished water and type putty powder (putty powder + water), etc.; The matching putty powder is generally prepared by boiling polyvinyl alcohol, formaldehyde, urea, etc. at high temperature into a glue solution (some manufacturers specially manufac...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J103/02C09J129/04C09J101/26C09J11/06C09J11/04C09D5/34
Inventor 段建明
Owner 湖北优力帮生态涂料有限公司
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