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Luminescent solar concentrator comprising disubstituted benzoselenadiazole compounds

A technology of benzoselenodiazole and solar energy, which is applied in the direction of luminescent materials, chemical instruments and methods, photovoltaic power generation, etc., and can solve the problems of little absorption and inability to convert photovoltaic cells, etc.

Inactive Publication Date: 2014-04-16
ENI SPA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0016] Although 4,7-bis-(thiophen-2'-yl)-2,1,3-benzothiadiazole (DTB) absorbs most of the solar spectrum, however, in contrast to yellow radiation and Red radiation corresponds to its higher spectral region which has little absorption, so yellow and red radiation cannot be converted into other radiations that are more efficiently utilized by photovoltaic cells

Method used

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  • Luminescent solar concentrator comprising disubstituted benzoselenadiazole compounds
  • Luminescent solar concentrator comprising disubstituted benzoselenadiazole compounds
  • Luminescent solar concentrator comprising disubstituted benzoselenadiazole compounds

Examples

Experimental program
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Effect test

example 1

[0058] Dissolve 6 g of polymethyl methacrylate Altuglas VSUVT100 (PMMA) and 57.2 mg of 4,7-di-(thiophen-2'-yl)-2,1,3-benzoselenadiazole in 30 ml of 1,2 -in dichlorobenzene. The obtained solution was uniformly deposited on a sheet (90×90×6 mm) of polymethylmethacrylate Altuglas VSUVT100 (PMMA) using a medical blade film coater, and the solvent was heated at room temperature (25° C.) at Evaporate for 24 hours in a small air stream. A red transparent tablet (sheet 1) was obtained, the color being imparted by a film whose thickness proved to be in the range of 300 μm to 350 μm.

[0059] Then set the surface area to 1.2cm 2 The photovoltaic cell IXYS-XOD17 was applied to one edge of the polymer sheet.

[0060] Then use a power of 1sun (1000W / m 2 ) light source illuminates the main side of the polymer sheet (covered by a thin film containing 4,7-bis-(thiophen-2'-yl)-2,1,3-benzoselenadiazole) and measures the Electric power.

[0061] The power measurement is achieved by coverin...

example 2

[0064] Example 2 (comparison)

[0065] Dissolve 6g of polymethylmethacrylate Altuglas VSUVT100 (PMMA) and 49.5mg of 4,7-di-(thiophen-2'-yl)-2,1,3-benzothiadiazole (DTB) in 30ml of 1,2-Dichlorobenzene. Then, the obtained solution was uniformly deposited on a sheet (size 90×90×6 mm) of polymethyl methacrylate Altuglas VSUUT100 (PMMA) using a medical blade film coater, and the solvent was heated at room temperature (25° C.) , Evaporate for 24 hours in a small air stream. A red transparent tablet (sheet 2) was obtained, the color being imparted by a film whose thickness proved to be in the range of 300 μm to 350 μm.

[0066] Then set the surface area to 1.2cm 2 The photovoltaic cell IXYS-XOD17 was applied to one edge of the polymer sheet.

[0067] Then use a power of 1sun (1000W / m 2 ) light source illuminates the main side of the polymer sheet (covered by a film containing 4,7-bis-(thiophen-2'-yl)-2,1,3-benzothiadiazole) and measures the effect by illumination generated el...

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Abstract

Luminescent solar concentrator (LSC) comprising at least one disubstituted benzoselenadiazole compound having general formula (I): R1, R2, R3, R4 and R5, equal to or different from each other, represent a hydrogen atom; or they are selected from linear or branched C1-C20, preferably C1-C10, alkyl groups, cycloalkyl groups optionally substituted, aryl groups optionally substituted, linear or branched C1-C20, preferably C1-C10, alkoxyl groups, optionally substituted; or R1 and R2, can be possibly bound to each other so as to form, together with the carbon atoms to which they are bound, a cycle or a polycyclic system containing from 3 to 14 carbon atoms, preferably from 4 to 6 carbon atoms, saturated, unsaturated, or aromatic, possibly containing one or more heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorous, selenium; or R3 and R4, can be possibly bound to each other so as to form, together with the carbon atoms to which they are bound, a cycle or a polycyclic system containing from 3 to 14 carbon atoms, preferably from 4 to 6 carbon atoms, saturated, unsaturated, or aromatic, possibly containing one or more heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorous, selenium; or R4 and R5, can be possibly bound to each other so as to form, together with the carbon atoms to which they are bound, a cycle or a polycyclic system containing from 3 to 14 carbon atoms, preferably from 4 to 6 carbon atoms, saturated, unsaturated, or aromatic, possibly containing one or more heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorous, selenium.(img file=DPA0000183055600000011.tif wi=970 he=408 / ).

Description

technical field [0001] The present invention relates to a luminescent concentrator (LSC) comprising at least one disubstituted benzoselenodiazole compound. [0002] The invention also relates to the use of at least one disubstituted benzoselenodiazole compound for the construction of luminescent concentrators (LSCs). [0003] The invention also relates to a photovoltaic device selected from, for example, a photovoltaic cell, a photovoltaic module, a solar cell, a solar module on a rigid substrate and a flexible substrate, the photovoltaic device comprising a luminescent solar concentrator (LSC), The luminescent solar concentrator (LSC) comprises at least one disubstituted benzoselenadiazole compound. Background technique [0004] It is known that single junction photovoltaic cells cannot efficiently utilize all solar radiation. In fact, single-junction photovoltaic cells have maximum efficiency only in a certain spectral range (including a part of visible radiation and a p...

Claims

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Application Information

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IPC IPC(8): C09K11/06H01L31/055C07D421/14
CPCH01L51/0068H01L51/0071C09B57/00Y02E10/50H01L31/055Y02E10/52Y02E10/549Y02P70/50H10K85/655H10K85/657
Inventor 塞缪尔·桑塔伦里罗伯托·福斯科安东尼奥·普罗托卢西亚诺·卡恰诺蒂
Owner ENI SPA
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