Sodium carboxymethyl starch for drilling fluid and preparation method thereof
A technology of sodium carboxymethyl starch and drilling fluid, which is applied in the field of biopolymer preparation, can solve the problems of unfavorable drilling fluid maintenance and treatment, high drilling fluid viscosity, and high drilling fluid cost, and achieve the advantages of carrying drill cuttings, easy crushing, The effect of improving the economic efficiency of enterprises
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Embodiment 1
[0014] A kind of carboxymethyl starch sodium salt for drilling fluid, it is made of the following substances by weight, including: 60-70 parts of starch, 8-15 parts of ethanol, 18-33 parts of etherification agent, sodium hydroxide 5-8 parts, 1-5 parts of borax.
[0015] A preparation method of carboxymethyl starch sodium salt for drilling fluids, comprising the following steps: first prepare etherification agent by mixing 8-15 parts of chloroacetic acid and 10-18 parts of anhydrous sodium carbonate for 2 hours; Add starch into the interlayer mixer, add ethanol while stirring, then add alkalizing agent and antioxidant, heat up to 25-35°C, seal the reaction for 2-3 hours, extract excess ethanol under vacuum, and finally add etherifying agent, Airtight reaction for 30-40 minutes, heat up to 80-90°C and vacuumize, dry until the baking loss ≤ 10%, discharge the material, cool to room temperature, and pulverize into 60-100 mesh fine powder and granules through a pulverizer, that is,...
Embodiment 2
[0017] A kind of carboxymethyl starch sodium salt for drilling fluid, it is made of the following substances by weight, including: 60-65 parts of starch, 10-15 parts of ethanol, 18-25 parts of etherification agent, sodium hydroxide 5-8 parts, 1-5 parts of borax.
[0018] A preparation method of carboxymethyl starch sodium salt for drilling fluids, comprising the following steps: first prepare an etherifying agent by mixing 8-12 parts of chloroacetic acid and 10-15 parts of anhydrous sodium carbonate for 2 hours; Add starch into the interlayer mixer, add ethanol while stirring, then add alkalizing agent and antioxidant, heat up to 25-35°C, seal the reaction for 2-3 hours, extract excess ethanol under vacuum, and finally add etherifying agent, Airtight reaction for 30-40 minutes, heat up to 80-90°C and vacuumize, dry until the baking loss ≤ 10%, discharge the material, cool to room temperature, and pulverize into 60-100 mesh fine powder and granules through a pulverizer, that is...
Embodiment 3
[0020] A kind of preparation method of carboxymethyl starch sodium salt for drilling fluid:
[0021] (1) Weigh 100kg of chloroacetic acid and 150kg of anhydrous sodium carbonate into a mixer, stir and react for 2 hours to obtain an etherifying agent;
[0022] (2) Add 600kg of wheat starch into a blender with interlayer, then add 80kg of ethanol, stir well, add 50kg of sodium hydroxide and 10kg of borax, keep the temperature at 35°C for 3 hours, and draw out excess ethanol in a vacuum state, then Add 180kg of etherification agent and seal the reaction for 40 minutes, then heat up to 90°C and vacuum-dry until the loss on bakeout is ≤10%. Methyl starch sodium salt.
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