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Sodium carboxymethyl starch for drilling fluid and preparation method thereof

A technology of sodium carboxymethyl starch and drilling fluid, which is applied in the field of biopolymer preparation, can solve the problems of unfavorable drilling fluid maintenance and treatment, high drilling fluid viscosity, and high drilling fluid cost, and achieve the advantages of carrying drill cuttings, easy crushing, The effect of improving the economic efficiency of enterprises

Active Publication Date: 2015-07-08
河南海洋化工科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] With the continuous expansion of China's oil and gas exploration field, the drilling formation is becoming more and more complex. During the drilling process, it is often necessary to use a large amount of drilling fluid treatment agent to reduce the friction between the well wall and the drilling tool, the drilling tool and the casing, and prevent the well wall. Collapse, improve the ability of drilling fluid to carry cuttings, reduce downhole complex situations, improve the geological structure, and timely discover reservoirs, especially the geological conditions of saline-alkali wells with high salinity and high PH value, although great achievements have been made. Research progress, but there are still some problems; such as high drilling fluid viscosity, increased shear force, low cuttings carrying capacity, high cost of drilling fluid, not conducive to the maintenance and treatment of drilling fluid on site, difficult to biodegrade, environmental pollution when drilling fluid is discarded Serious, especially saline-alkali wells with high salinity and high PH value have higher and higher requirements for environmental protection

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0014] A kind of carboxymethyl starch sodium salt for drilling fluid, it is made of the following substances by weight, including: 60-70 parts of starch, 8-15 parts of ethanol, 18-33 parts of etherification agent, sodium hydroxide 5-8 parts, 1-5 parts of borax.

[0015] A preparation method of carboxymethyl starch sodium salt for drilling fluids, comprising the following steps: first prepare etherification agent by mixing 8-15 parts of chloroacetic acid and 10-18 parts of anhydrous sodium carbonate for 2 hours; Add starch into the interlayer mixer, add ethanol while stirring, then add alkalizing agent and antioxidant, heat up to 25-35°C, seal the reaction for 2-3 hours, extract excess ethanol under vacuum, and finally add etherifying agent, Airtight reaction for 30-40 minutes, heat up to 80-90°C and vacuumize, dry until the baking loss ≤ 10%, discharge the material, cool to room temperature, and pulverize into 60-100 mesh fine powder and granules through a pulverizer, that is,...

Embodiment 2

[0017] A kind of carboxymethyl starch sodium salt for drilling fluid, it is made of the following substances by weight, including: 60-65 parts of starch, 10-15 parts of ethanol, 18-25 parts of etherification agent, sodium hydroxide 5-8 parts, 1-5 parts of borax.

[0018] A preparation method of carboxymethyl starch sodium salt for drilling fluids, comprising the following steps: first prepare an etherifying agent by mixing 8-12 parts of chloroacetic acid and 10-15 parts of anhydrous sodium carbonate for 2 hours; Add starch into the interlayer mixer, add ethanol while stirring, then add alkalizing agent and antioxidant, heat up to 25-35°C, seal the reaction for 2-3 hours, extract excess ethanol under vacuum, and finally add etherifying agent, Airtight reaction for 30-40 minutes, heat up to 80-90°C and vacuumize, dry until the baking loss ≤ 10%, discharge the material, cool to room temperature, and pulverize into 60-100 mesh fine powder and granules through a pulverizer, that is...

Embodiment 3

[0020] A kind of preparation method of carboxymethyl starch sodium salt for drilling fluid:

[0021] (1) Weigh 100kg of chloroacetic acid and 150kg of anhydrous sodium carbonate into a mixer, stir and react for 2 hours to obtain an etherifying agent;

[0022] (2) Add 600kg of wheat starch into a blender with interlayer, then add 80kg of ethanol, stir well, add 50kg of sodium hydroxide and 10kg of borax, keep the temperature at 35°C for 3 hours, and draw out excess ethanol in a vacuum state, then Add 180kg of etherification agent and seal the reaction for 40 minutes, then heat up to 90°C and vacuum-dry until the loss on bakeout is ≤10%. Methyl starch sodium salt.

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Abstract

The invention discloses sodium carboxymethyl starch for drilling fluid and a preparation method thereof. The preparation method comprises the following steps: firstly, adding 60-70 parts of starch into a blender with an interlayer, adding 8-15 parts of ethanol while stirring, adding 5-8 parts of basifier and 1-5 parts of antioxidant, heating up to 25-35 DEG C, hermetically reacting for 2-3 hours, sucking out excessive ethanol under a vacuum state, finally adding 18-33 parts of etherifying agent, hermetically reacting for 30-40 minutes, heating up to 80-90 DEG C, vacuumizing, drying until the drying loss is not greater than 10%, discharging, cooling to the normal temperature, and crushing the product into fine powder of 60-100 meshes and granules in a crusher to obtain the sodium carboxymethyl starch. The sodium carboxymethyl starch for drilling fluid disclosed by the invention belongs to biopolymers and is degradable, and the performance of the drilling fluid is stable to beneficially carry drilling chips; compared with wet process production, the production method is simple; compared with dry process production, the preparation method has the advantages that no raw material phenomenon is generated and the product quality and performance are stable.

Description

technical field [0001] The invention relates to a drilling fluid sodium carboxymethyl starch used as an oil and natural gas drilling fluid treatment agent and a preparation method thereof, belonging to the technical field of biopolymer preparation. Background technique [0002] With the continuous expansion of China's oil and gas exploration field, the drilling formation is becoming more and more complex. During the drilling process, it is often necessary to use a large amount of drilling fluid treatment agent to reduce the friction between the well wall and the drilling tool, the drilling tool and the casing, and prevent the well wall. Collapse, improve the ability of drilling fluid to carry cuttings, reduce downhole complex situations, improve the geological structure, and timely discover reservoirs, especially the geological conditions of saline-alkali wells with high salinity and high PH value, although great achievements have been made. Research progress, but there are ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08B31/12C09K8/035
Inventor 郑树坤
Owner 河南海洋化工科技股份有限公司
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