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Fire-retardant polyurethane foam and preparation method thereof

A technology of polyurethane foam and flame retardant, which is applied in the field of flame-retardant polyurethane foam and its preparation, can solve problems such as unsatisfactory effects, and achieve the effects of improving flame retardancy and reducing environmental pollution

Active Publication Date: 2014-04-02
BEIJING RECHSAND SCI & TECH GRP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The traditional flame retardant method is to add a flame retardant to the raw material to achieve the flame retardant effect, or to improve the flame retardancy by introducing a flame retardant group into the polyether polyol, but the effect is not ideal, and the oxygen index does not exceed "27 "

Method used

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  • Fire-retardant polyurethane foam and preparation method thereof
  • Fire-retardant polyurethane foam and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] Polyurethane foam, the specific formula is shown in Table 1.

[0035] At room temperature, a certain amount of polyether polyol 4110, polyether polyol 403, polyester polyol 400A, sodium silicate, flame retardant DMMP, graphite milk, foam stabilizer AK-8805, dibutyl dilauric acid Put tin and triethylenediamine in a container and mechanically mix and stir for 20-30 minutes to form a uniform polyether system, which is white material.

[0036] Then mix and react the white material with polymethylene polyphenyl polyisocyanate (PAPI) PM-200 at room temperature, stir at 1500r / min for 10s, then pour it into a constant temperature vertical climbing mold for foaming and solidification. After the foam is matured, This was removed from the mold to obtain a polyurethane foam. Carry out pattern cutting in accordance with the requirements of the national standard, and measure various properties of the foam body, see Table 2.

Embodiment 2

[0038] Polyurethane foam was prepared according to the method of Example 1. The specific formula is shown in Table 1.

[0039] Wherein, the stirring time is 5s; the stirring speed is 1800r / min.

Embodiment 3

[0041] Polyurethane foam was prepared according to the method of Example 1. The specific formula is shown in Table 1.

[0042] Wherein, the stirring time is 20s; the stirring speed is 1200r / min.

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PUM

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Abstract

The invention relates to fire-retardant polyurethane foam which is characterized by being prepared by foaming of a black material and a white material with a mass ratio of 1:1.2-1.4. The black material is isocyanate; the white material comprises the following components by weight: 5-15 parts of water glass; 40-55 parts of polyether polyol; 40-60 parts of polyester polyol; 0.1-0.5 parts of catalysts; 2-5 parts of foam stabilizers; 5-15 parts of halogen-free fire retardants; and 5-15 parts of graphite fire retardants. The invention also provides a preparation method of the fire-retardant polyurethane foam. According to the invention, water glass instead of chlorofluorocarbon foaming agents is added into existing polyurethane foam formulae, which effectively reduces environment pollution; the combined effect of water glass, halogen-free fire retardants, and graphite fire retardants improves the fire retardance of polyurethane, and the fire-retardant polyurethane foam is applicable to fields of building materials, furniture, insulation materials, automobile seat cushions and interior trims, and the like.

Description

technical field [0001] The invention relates to a flame-retardant polyurethane foam and a preparation method thereof, in particular to adding graphite on the basis of water glass foamed polyurethane to improve flame retardancy and a preparation method thereof. Background technique [0002] Polyurethane foam is a resin-based body made of numerous small pores inside it by chemical or physical methods. According to its application, it can be divided into soft foam, hard foam and semi-hard foam. [0003] Ordinary polyurethane is combustible, and it burns and decomposes in case of fire to produce a large amount of toxic smoke, which brings difficulties to fire extinguishing. Especially polyurethane soft foam has a high opening rate, many combustible components, is flammable and not easy to self-extinguish. However, the current application fields of polyurethane foam, such as building materials, mattresses, furniture, insulation materials, car seat cushions and interior materials...

Claims

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Application Information

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IPC IPC(8): C08G18/76C08G18/48C08G18/42C08K3/04C08J9/04
CPCC08G18/4018C08J9/04C08K3/04C08K3/34C08G2101/00C08J2375/08C08J2375/06C08G18/00C08L75/00C08J9/0038C08J9/0061C08J9/0066C08J9/0095C08J9/125C08J2201/022C08J2203/10C08J2483/12C08K5/5333C08L75/04
Inventor 秦升益贾屹海张雪芳
Owner BEIJING RECHSAND SCI & TECH GRP
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