Lithium hexafluoride calcium aluminium material with hollow tetrakaidecahedron structure
A technology of hexafluorolithium calcium aluminum and tetradecahedron, which is applied in the field of inorganic micro-nano materials, can solve the problems of hollow structure collapse and insufficient mechanical strength, and achieve the effects of low cost, simple and controllable method, and mild reaction conditions
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[0029] Weigh 0.2362g calcium nitrate hydrate, 0.1380g lithium nitrate hydrate, and 0.3752g aluminum nitrate hydrate and dissolve them in 25mL of deionized water, stir and dissolve to obtain a clear solution. %) and dilute ammonia water (5%) to adjust the pH of the solution to 3.0, then add 10mL ammonium fluoride solution with a mass fraction of 2.18% at room temperature, and stir vigorously for 10 minutes to obtain a milky white solution, then transfer the solution to 45mL polytetrafluoroethylene Put it in a reaction kettle with vinyl fluoride liner and seal it, and react at 225°C for 24 hours. After the reaction kettle is cooled to room temperature, the obtained yellow precipitate is collected by centrifugation at 5000 rpm and cleaned with deionized water. First, it is ultrasonically 5 Minutes, then centrifuged at 5000 rpm for 10 minutes, repeated three times, then washed once with absolute ethanol, ultrasonic for 5 minutes, centrifuged at 5000 rpm for 10 minutes, and finally ...
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