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Lithium hexafluoride calcium aluminium material with hollow tetrakaidecahedron structure

A technology of hexafluorolithium calcium aluminum and tetradecahedron, which is applied in the field of inorganic micro-nano materials, can solve the problems of hollow structure collapse and insufficient mechanical strength, and achieve the effects of low cost, simple and controllable method, and mild reaction conditions

Inactive Publication Date: 2014-02-12
NORTHEAST FORESTRY UNIVERSITY +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

These methods must adopt appropriate methods to remove the template when obtaining inorganic materials with a hollow structure, such as hydrofluoric acid erosion, high temperature sintering, photocatalysis, etc. to decompose the template, but in the process of removing the template, it is easy because the material wall is too thin Insufficient mechanical strength leading to collapse of hollow structures

Method used

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  • Lithium hexafluoride calcium aluminium material with hollow tetrakaidecahedron structure
  • Lithium hexafluoride calcium aluminium material with hollow tetrakaidecahedron structure
  • Lithium hexafluoride calcium aluminium material with hollow tetrakaidecahedron structure

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Embodiment 1

[0029] Weigh 0.2362g calcium nitrate hydrate, 0.1380g lithium nitrate hydrate, and 0.3752g aluminum nitrate hydrate and dissolve them in 25mL of deionized water, stir and dissolve to obtain a clear solution. %) and dilute ammonia water (5%) to adjust the pH of the solution to 3.0, then add 10mL ammonium fluoride solution with a mass fraction of 2.18% at room temperature, and stir vigorously for 10 minutes to obtain a milky white solution, then transfer the solution to 45mL polytetrafluoroethylene Put it in a reaction kettle with vinyl fluoride liner and seal it, and react at 225°C for 24 hours. After the reaction kettle is cooled to room temperature, the obtained yellow precipitate is collected by centrifugation at 5000 rpm and cleaned with deionized water. First, it is ultrasonically 5 Minutes, then centrifuged at 5000 rpm for 10 minutes, repeated three times, then washed once with absolute ethanol, ultrasonic for 5 minutes, centrifuged at 5000 rpm for 10 minutes, and finally ...

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Abstract

The invention discloses a multi-element fluoride material with a hollow tetrakaidecahedron structure. The multi-element fluoride material is prepared by adopting the following steps: stirring three metal nitrate solvents in deionized water so as to obtain a clear aqueous solution; adjusting the pH value of the solution by using dilute nitric acid and ammonia water to a certain value, then adding a fluoride solution, violently stirring for 10 minutes, finally transferring the mixture to a reaction kettle, heating the mixture for 2-4 hours at a certain temperature, collecting a product, and drying the product for 10 hours at the temperature of 80 DEG C. The multi-element fluoride material has internal pore diameters, thin crystal walls and enormous application prospect; the preparation technology is simple and is suitable for industrial production; the raw materials are inexpensive and easily available.

Description

technical field [0001] The invention belongs to the field of inorganic micro-nano materials, in particular to a lithium calcium aluminum hexafluoride material with a hollow tetradecahedron structure. Background technique [0002] Inorganic materials with a hollow structure with a high specific surface area have excellent performance and great application prospects in the fields of catalyst loading, drug sustained release, gas storage, and thermal insulation. The 21st century is the era of material science. With the rapid development of science and technology, traditional materials can no longer meet people's higher and higher requirements for material properties. Especially the physical and chemical properties of modern materials have attracted people's attention. This requires We can regulate the composition, structure, and morphology of materials at the molecular level, which provides a huge impetus for the basic research of new materials. When people synthesize inorganic...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01F7/54
Inventor 贾佩云孙元平
Owner NORTHEAST FORESTRY UNIVERSITY
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