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Method for producing flexible package lithium ion battery negative plates

A technology of lithium-ion batteries and manufacturing methods, which is applied in the field of manufacturing negative electrodes of flexible-packaged lithium-ion batteries, can solve the problems of large cycle expansion and short cycle life, and achieve the advantages of reducing cycle expansion, improving adhesive performance, and strong controllability Effect

Active Publication Date: 2013-05-08
DONGGUAN AMPEREX TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The purpose of the present invention is to provide a method for manufacturing a negative electrode sheet of a soft-packed lithium-ion battery in view of the deficiencies in the prior art, and the negative electrode sheet of a soft-packed lithium-ion battery produced by this method has the characteristics of high adhesion and high environmental friendliness , so that the cycle life of the soft-packaged lithium-ion battery comprising the negative electrode sheet made by the method is significantly improved, and the rebound after the battery cycle and the rebound of the pole piece are also greatly reduced, so as to overcome the cycle life of the soft-packaged lithium-ion battery in the prior art Short and big loop swell deficiencies

Method used

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  • Method for producing flexible package lithium ion battery negative plates
  • Method for producing flexible package lithium ion battery negative plates
  • Method for producing flexible package lithium ion battery negative plates

Examples

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Embodiment 1

[0026] Embodiment 1, a method for manufacturing a negative electrode sheet of a flexible package lithium ion battery provided in this embodiment, the negative electrode sheet includes a negative electrode current collector and a negative electrode diaphragm coated on the surface of the negative electrode current collector, the method includes the following steps:

[0027] Step 1: Add artificial graphite, polyvinylidene fluoride binder (final melting temperature of 170°C) and conductive carbon to the solvent N-methylpyrrolidone in a mass ratio of 96:2:2, and mix well to obtain negative electrode slurry , and then coating the negative electrode slurry on the negative electrode current collector, forming a negative electrode membrane on the negative electrode current collector after drying, and obtaining a negative electrode sheet to be baked after cold pressing.

[0028] Step 2, place the negative electrode sheet to be baked in a vacuum oven for baking, the temperature in the vac...

Embodiment 2

[0030] Embodiment 2, a method for manufacturing a flexible lithium-ion battery negative electrode sheet provided in this embodiment, the negative electrode sheet includes a negative electrode current collector and a negative electrode diaphragm coated on the surface of the negative electrode current collector, the method includes the following steps:

[0031] Step 1: Add natural graphite, polyvinylidene fluoride binder (final melting temperature of 155°C) and superconducting carbon into the solvent N-methylpyrrolidone in a mass ratio of 94:3:3, and mix well to obtain the negative electrode slurry Then, the negative electrode slurry is coated on the negative electrode collector, and after drying, the negative electrode membrane is formed on the negative electrode collector, and the negative electrode sheet to be baked is obtained after cold pressing.

[0032] Step 2, place the negative electrode sheet to be baked in a vacuum oven, the temperature in the vacuum oven is 160°C, the...

Embodiment 3

[0034] Embodiment 3, a method for manufacturing a flexible lithium-ion battery negative electrode sheet provided in this embodiment, the negative electrode sheet includes a negative electrode current collector and a negative electrode diaphragm coated on the surface of the negative electrode current collector, the method includes the following steps:

[0035]Step 1: Add mesophase carbon microspheres, polyvinylidene fluoride adhesive (final melting temperature: 180°C) and acetylene black light in a mass ratio of 90:5:5 to the solvent N-methylpyrrolidone, and mix well to obtain Negative electrode slurry, and then coating the negative electrode slurry on the negative electrode collector, forming a negative electrode membrane on the negative electrode collector after drying, and obtaining the negative electrode sheet to be baked after cold pressing.

[0036] Step 2, put the negative electrode sheet to be baked in a vacuum oven, the temperature in the vacuum oven is 200°C, the bakin...

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Abstract

The invention belongs to the technical field of lithium ion batteries, and in particular relates to a method for producing flexible package lithium ion battery negative plates, wherein the method comprises the steps that: adding a carbon material, a polyvinylidene fluoride adhesive agent and a conductive agent into the solvent, mixing uniformly, and coating cathode slurry on the negative current collector so as to form anode diaphragms; placing the negative plates to be baked in a vacuum oven to bake, wherein the temperature of the oven is higher than the final melting temperature of polyvinylidene fluoride, so as to melt polyvinylidene fluoride adhesive agent completely into liquid; and cooling the negative plates to be cooled so as to complete the production of the negative plates. Compared with the prior art, the method causes crystle transformation of polyvinylidene fluoride, so that a monoclinal TGTG' molecular chain configuration is transferred into an orthogonal TTTT molecular chain configuration with high remanent polarization and higher bonding strength; and the bonding performance is improved, and thus enhancing the cycle performance of batteries, reducing the cyclic swelling of batteries, and improving the rate capability of batteries simultaneously.

Description

technical field [0001] The invention belongs to the technical field of lithium-ion batteries, and in particular relates to a method for manufacturing a negative electrode sheet of a soft-packed lithium-ion battery. Background technique [0002] Lithium-ion battery is an electrochemical energy storage device, which is mainly composed of several parts such as positive electrode, negative electrode, separator and electrolyte. insert) material. [0003] At present, flexible packaging lithium-ion batteries have become the first choice for consumer electronics products. However, during the use of such batteries by consumers, the problem of sharp decrease in battery power and gradual increase in battery thickness (that is, large cycle expansion) often occurs. If these problems are not solved, the service life of electronic products will be reduced, and consumers will need to replace batteries frequently, resulting in a decrease in consumer satisfaction, thereby affecting consumer ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/62H01M4/1393
CPCY02E60/122Y02E60/10
Inventor 孙峰刘东任汪颖汪新王娜崔航刘现军
Owner DONGGUAN AMPEREX TECH
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