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Activated high-modulus low-shrinkage polyester industrial yarn and preparation method of same

A polyester industrial yarn, low shrinkage technology, applied in the direction of single-component polyester rayon filament, complete equipment for producing rayon, chemical post-processing of synthetic polymer rayon filament, etc. Achieve the effect of small dimensional stability index, uniform activator content and good abrasion resistance

Inactive Publication Date: 2013-03-27
ZHEJIANG HAILIDE NEW MATERIAL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the mainstream dipping equipment in developed countries such as Europe and the United States mainly adopts one-bath dipping equipment, and ordinary high-modulus low-polyester industrial yarn cannot be processed on one-bath dipping equipment.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] A kind of product specification is the prescription of the activated type high-modulus low-shrinkage polyester industrial yarn of 1330dtex / 360f, in parts by weight as follows:

[0023] 100 parts of Hailide HLD301 high-viscosity PET with an intrinsic viscosity of 1.05,

[0024] Sanyo 911 spinning oil 0.4 parts,

[0025] Sima TC12 activator 0.5 parts;

[0026] After testing, the breaking strength is 7.12CN / dtex, the breaking elongation is 13.2%, the intermediate elongation (4.0CN / dtex) is 5.4%, and the dry heat shrinkage (take the tow with a length of 1m and hang it on a 0.05CN / dtex For heavy objects, put them in an oven at 177°C for 10 minutes and then take them out to measure the length, and calculate the shortening ratio) to be 2.8%.

Embodiment 2

[0028] Another kind of product specification is the formula of activated type high-modulus low-shrinkage polyester industrial yarn of 1670dtex / 480f, in parts by weight as follows:

[0029] 100 parts of Hailide HLD301 high-viscosity PET with an intrinsic viscosity of 1.10,

[0030] Sanyo 911 spinning oil 0.6 parts,

[0031] Sima TC12 activator 0.3 part;

[0032] After testing, the breaking strength is 7.2CN / dtex, the breaking elongation is 14.2%, the intermediate elongation (4.0CN / dtex) is 5.6%, and the dry heat shrinkage (take the tow with a length of 1m and hang it on a 0.05CN / dtex For heavy objects, put them in an oven at 177°C for 10 minutes, then take them out to measure the length, and calculate the shortening ratio) to be 3.0%.

Embodiment 3

[0034] Another kind of product specification is the prescription of the activated type high-modulus low-shrinkage polyester industrial yarn of 1110dtex / 335f, by weight as follows:

[0035] 100 parts of Hailide HLD301 high-viscosity PET with an intrinsic viscosity of 1.10,

[0036] Sanyo 911 spinning oil 0.2 parts,

[0037] Sima TC12 activator 0.4 part;

[0038] After testing, the breaking strength is 7.05CN / dtex, the breaking elongation is 12.5%, the intermediate elongation (4.0CN / dtex) is 5.8%, and the dry heat shrinkage (take the tow with a length of 1m and hang it on a 0.05CN / dtex For heavy objects, put them in an oven at 177°C for 10 minutes, then take them out to measure the length, and calculate the shortening ratio) to be 3.0%.

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Abstract

The invention relates to an activated high-modulus low-shrinkage polyester industrial yarn and a preparation method of the same. The activated high-modulus low-shrinkage polyester industrial yarn is formed in a way that high-adhesion PET (polyester) slices are taken as raw materials and then are subjected to melt spinning, a proper amount of spinning oil is added, the drawing formation is carried out, a proper quantity of activators are added and then the winding is carried out. A formula contains the following components by weight parts: 100 parts of Halead (HLD) 301 high-adhesion PET, 0.2-0.6 part of Sanyo 911 spinning oil and 0.2-0.5 part of a Syma TC12 activator. The preparation method comprises the steps of: solid-phase polymerizing, melting, metering, cooling forming, oiling, drawing, activator feeding and winding. According to the yarn, the product breaking strength is over 7.0CN / dtex, the yarn has the advantages of good abrasion resistance, small index of dimensional stability, uniform content of the activator, and the like, and can be applied to the field of tyre cord fabrics, and the manufacturing cost of post processing is saved remarkably.

Description

technical field [0001] The invention belongs to the technical field of polymer fiber production, and in particular relates to an activated high-modulus low-shrinkage polyester industrial yarn and a preparation method thereof. Background technique [0002] In recent years, with the continuous advancement of technology, high-modulus low-shrinkage polyester industrial yarns have continued to expand in the fields of tire cord fabrics, rubber skeleton materials, etc., and the market demand for high-modulus low-shrinkage polyester industrial yarns is increasing. The high-modulus low-shrinkage polyester industrial filaments currently on the market can only be post-processed on the dipping equipment of the two-bath method because they have not been pre-activated. At present, the mainstream dipping equipment in developed countries such as Europe and the United States mainly adopts one-bath dipping equipment, and ordinary high-modulus low-polyester industrial yarn cannot be processed ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F6/62D01F11/08C08G63/183C08G63/80D06M15/55D01D13/00
Inventor 葛骏敏马鹏程
Owner ZHEJIANG HAILIDE NEW MATERIAL
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