Computer to conventional plate (CTcP) photosensitive resist, preparation method of the CTcP photosensitive resist and CTcP prepared from the CTcP photosensitive resist
A technology of photosensitive adhesive and polyepoxy acrylate, which is applied in photomechanical equipment, photoengraving process of pattern surface, and photosensitive materials for optical mechanical equipment, etc. Insufficient capacity, insufficient UV light source power, etc., to improve the printing endurance and alkali resistance.
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Embodiment 1
[0025] Add 113 grams (0.913 M) and 550 ml of dioxane (CH 2 ) 4 o 2及 The polyepoxy acrylate resin and m-cresol aldehyde resin that the mixed solution of ethylene glycol ether dissolves, wherein said polyepoxy acrylate resin accounts for polyepoxy acrylate resin and 15% of m-cresol aldehyde resin gross weight, in another Add 138 grams (0.514M) 2-diazo-1-naphthoquinone-5-sulfonyl chloride in a 1000ml flask, use 550ml (CH 2 ) 4 o 2 Dissolve, add 11 grams of activated carbon. Stir for 10 minutes, filter, pour the filtrate into the above-mentioned three-neck flask, stir and mix in a water bath, heat to 30°C, and start to add 10% NaHCO dropwise. 3 Solution, the reaction temperature is controlled by the rate of addition, and the reaction temperature is kept below 40°C for about 2 hours. After cooling, gradually pour it into 5 liters of cold water ≤ 20°C for water analysis. Filter, and dissolve the filter cake in acetone, adding the amount of acetone until the precipitate is com...
Embodiment 2
[0027] Add 113 grams (0.913 M) and 550 ml of dioxane (CH 2 ) 4 o 2及 Polyepoxy acrylate resin and m-cresol aldehyde resin dissolved in the mixed solution of ethylene glycol ether, wherein said polyepoxy acrylate resin accounts for 18% of polyepoxy acrylate resin and m-cresol aldehyde resin gross weight, in another Add 138 grams (0.514M) 2-diazo-1-naphthoquinone-5-sulfonyl chloride in a 1000ml flask, use 550ml (CH 2 ) 4 o 2 Dissolve, add 11 grams of activated carbon. Stir for 10 minutes, filter, pour the filtrate into the above-mentioned three-necked flask, stir and mix in a water bath, heat to 32°C, and start to add 10% NaHCO dropwise 3 Solution, the reaction temperature is controlled by the rate of addition, and the reaction temperature is kept below 40°C for about 2 hours. After cooling, gradually pour it into 5 liters of cold water ≤ 20°C for water analysis. Filter, and dissolve the filter cake in acetone, adding the amount of acetone until the precipitate is complete...
Embodiment 3
[0029] Add 113 grams (0.913 M) and 550 ml of dioxane (CH 2 ) 4 o 2及 Polyepoxy acrylate resin and m-cresol aldehyde resin dissolved in the mixed solution of ethylene glycol ether, wherein said polyepoxy acrylate resin accounts for 20% of polyepoxy acrylate resin and m-cresol aldehyde resin gross weight, in another Add 138 grams (0.514M) 2-diazo-1-naphthoquinone-5-sulfonyl chloride in a 1000ml flask, use 550ml (CH 2 ) 4 o 2 Dissolve, add 11 grams of activated carbon. Stir for 10 minutes, filter, pour the filtrate into the above-mentioned three-necked flask, stir and mix in a water bath, heat to 32°C, and start to add 10% NaHCO dropwise 3 Solution, the reaction temperature is controlled by the rate of addition, and the reaction temperature is kept below 40°C for about 2 hours. After cooling, gradually pour it into 5 liters of cold water ≤ 20°C for water analysis. Filter, and dissolve the filter cake in acetone, adding the amount of acetone until the precipitate is complete...
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