Dihydroporphin (III) chelates having plant growth regulating activity and use thereof as plant growth regulator
A plant growth regulator, plant growth regulation technology, applied in plant growth regulators, plant growth regulators, applications, etc., can solve the problem of easy decomposition and failure of products, poor solubility (almost insoluble in water, increasing the technical difficulty of heme And other issues
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Embodiment 1
[0062]Example 1: Preparation of pyropheophorbide-a iron chloride (compound I-1), using 2.0 grams of pyropheophorbide-a and 7.4 grams of iron hydrochloride as raw materials, according to the literature (Journal of Chromatography A, 721 (1996) 350-354; Chinese Pharmaceutical Journal, 2002, 37 (1) 64-65) method to obtain 1.27 grams of compound I-1, purity 98.0% (HPLC), Fe%: 9.13% ( Theoretical value: 8.95%), decomposed by heating at 188-201°C, UV: λ max 402nm (ε4.5×10 4 );MS m / z:588([M-CI] + ); IR(CsI)cm -1 :373 (Fe-Cl).
Embodiment 2
[0063] Example 2: Basically the same as Example 1, but using 0.2 gram of pyropheophorbide-a methyl ester as raw material (while adjusting the ratio of other raw materials), 0.10 gram of compound I-2 was obtained, with a purity of 96.0% (HPLC) , decomposed by heating at 191-203°C, UV: λ max 403nm (ε4.5×10 4 );MS m / z:602([M-CI] + ); IR(CsI)cm -1 :372 (Fe-Cl).
Embodiment 3
[0064] Example 3: Basically the same as Example 1, but using 0.2 gram of pyropheophorbide-a ethyl ester as raw material (while adjusting the ratio of other raw materials), 0.08 gram of compound I-3 was obtained, with a purity of 96.0% (HPLC) , decomposed by heating at 198-209°C, UV: λ max 403nm (ε4.4×10 4 );MS m / z:616([M-CI] + ); IR(CsI)cm -1 :373 (Fe-Cl).
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