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Fluorescent material with purple luminescence property and preparation method thereof

A technology of fluorescent materials and luminescent properties, applied in the field of fluorescent materials, can solve the problems of few patents and achieve the effect of good violet light emission properties

Inactive Publication Date: 2013-11-13
NINGBO UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

At present, there are few related patents in China

Method used

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  • Fluorescent material with purple luminescence property and preparation method thereof
  • Fluorescent material with purple luminescence property and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] Zn(OAC) 2 2H 2 O (0.10mmol, 22.2mg), quinolinecarboxylic acid (0.10mmol, 25.0mg), 1,10-phenanthroline (0.10mmol, 20.0mg) were mixed in 10ml H 2 O, after stirring for 10-30 minutes, put the mixture into a 25ml stainless steel autoclave lined with a polytetrafluoroethylene inner tube, react at 80 degrees Celsius for 2 days, then lower the temperature in the oven to room temperature, and open the reaction Kettle, washed with distilled water and air-dried to obtain colorless blocky crystals.

Embodiment 2

[0018] Zn(OAC) 2 2H 2 O (0.20mmol, 44.4mg), quinolinecarboxylic acid (0.10mmol, 25.0mg), 1,10-phenanthroline (0.05mmol, 10.0mg) were mixed in 10ml H 2 O, after stirring for 10-30 minutes, put the mixture into a 25ml stainless steel high-pressure reactor lined with a polytetrafluoroethylene inner tube, react at 120 degrees Celsius for 3 days, then lower the temperature in the oven to room temperature, and open the reaction Kettle, washed with distilled water and air-dried to obtain colorless blocky crystals.

Embodiment 3

[0020] Zn(OAC) 2 2H 2 O (0.40mmol, 88.8mg), quinolinecarboxylic acid (0.10mmol, 25.0mg), 1,10-phenanthroline (0.20mmol, 40.0mg) were mixed in 10ml H 2 O, after stirring for 10-30 minutes, put the mixture into a 25ml stainless steel autoclave lined with a polytetrafluoroethylene inner tube, react at 160 degrees Celsius for 4 days, then lower the temperature in the oven to room temperature, and open the reaction Kettle, washed with distilled water and air-dried to obtain colorless blocky crystals.

[0021] Rinse the colorless massive crystals obtained in the above examples with distilled water, and air-dry them naturally; after determination, the crystals are zinc quinoline carboxylic acid compounds, and their molecular formula is C 88 h 64 N 8 o 12 Zn 2 , the crystal system is monoclinic, the space group is P21 / c, and the unit cell parameters α=90°, γ=90°, β=97.5650°, the zinc ion is a modified octahedral coordination mode, two nitrogen coordination atoms come from o-ph...

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Abstract

The invention discloses a fluorescent material with a purple luminescence property and a preparation method thereof. The fluorescent material is characterized in that the fluorescent material is a zinc ethylcarbonate crystal prepared by carrying out a chemical reaction on phenanthroline and quinolinecarboxylic acid having a carboxylic group as well as zinc ions having optical activities, wherein the molecular formula of the zinc ethylcarbonate crystal is C88H64N8O12Zn2, the crystal system of the crystal is monoclinic, the space group of the crystal is P21c, and the cell parameters of the crystal are as follows: alpha is equal to 90 degrees, gamma is equal to 90 degrees, and beta is equal to 97.5650 degrees; and the zinc ion is in a deformed octahedral coordination mode, two nitrogen coordination atoms are derived from phenanthroline, three oxygen coordination atoms are derived from quinoline carboxylic acid, and an oxygen coordination atom is derived from water. The fluorescent material has the advantages of correct space structure and molecular formula, and contains Zn (II) ions with rich optical activities and carboxylic acid with strong coordination capability, thereby being beneficial to electron transition and energy transfer. Thus, the fluorescent material has a good purple luminescence property.

Description

technical field [0001] The invention relates to a fluorescent material, in particular to a fluorescent material with purple luminous performance and a preparation method thereof. Background technique [0002] Fluorescent materials have excellent properties of absorbing ultraviolet rays and emitting visible light, so fluorescent materials have been widely used in various aspects of life. Agricultural light conversion films can be made by adding fluorescent materials to the film, and fluorescent decorative materials can produce novel and peculiar visual effects, so they have been widely used in daily life. Organic fluorescent materials have a wide range of applications in medicine, and can be used to make medical fluorescent probes, so that the site of disease can be easily detected by intracellular imaging. Ultraviolet fluorescent ink can be made by mixing purple fluorescent materials with certain specific chemical components. This ink has outstanding uses in anti-counterfei...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K11/06C07F3/06
Inventor 李星刘志鹏邴月査美琴
Owner NINGBO UNIV
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