Adhesive binder, adhesive composition including the same, optical member, and a method for preparing adhesive binder layer
A binder and composition technology, applied in the direction of adhesives, polarizers, adhesive types, etc., can solve problems such as long curing time
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preparation example 1
[0091] Preparation Example 1: Preparation of Adhesive A
[0092] 60 g of ethyl acetate was put into a 1-liter four-necked flask, and then 84 g of butyl acrylate, 10 g of benzyl methacrylate, and 4 g of 4-hydroxybutyl acrylate were added thereto. After heating to 70°C, 0.08 g of initiator (Vazo-52, DuPont) and 20 g of ethyl acetate were added. The mixture was kept for 3 hours. To this mixture was added 320 g of ethyl acetate. After cooling to 40° C., 2 g of 2-isocyanoethyl methacrylate and 0.01 g of DBTDL were added as catalysts. The resulting mixture was reacted for 12 hours. Nitrogen was fed to the flask at a rate of 10 cc / min throughout the reaction. The polymerized product was found to have a viscosity of 4000 to 10000 cps at 25°C and a solids content of 20%.
preparation example 2
[0093] Preparation Example 2: Preparation of Adhesive B
[0094] The procedure of Preparation Example 1 was repeated except that butyl acrylate, benzyl methacrylate, 4-hydroxybutyl acrylate, and 2-isocyanoethyl methacrylate were used in amounts of 81 g, 15 g, 3 g, and 1 g, respectively.
preparation example 3
[0095] Preparation Example 3: Preparation of Adhesive C
[0096] The procedure of Preparation 1 was repeated except that butyl acrylate, benzyl methacrylate, and 4-hydroxybutyl acrylate were used in amounts of 86 g, 10 g, and 4 g, respectively, instead of 2-isocyanoethyl methacrylate .
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