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Heavy metal composite passivating agent used for paddy soil and preparation method thereof

A technology of heavy metals and passivating agents, applied in the restoration of polluted soil, chemical instruments and methods, soil conditioning materials, etc., can solve the problems of weak effect, reduce cadmium absorption, etc., to increase species, increase pH value, in situ Passivation effect of soil heavy metals

Active Publication Date: 2011-09-07
INST OF SUBTROPICAL AGRI CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The research results of Chen et al. (2000) showed that the addition of manganese oxide can reduce the content of cadmium extracted from EDTA, HAc and Hal in the soil, and reduce the absorption of cadmium in the aboveground parts of crops; the addition of iron oxide can also reduce the content of cadmium extracted from HAc, It also has a greater inhibitory effect on the absorption of cadmium in the aboveground parts of crops, but its effect is weaker than that of manganese oxide

Method used

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  • Heavy metal composite passivating agent used for paddy soil and preparation method thereof
  • Heavy metal composite passivating agent used for paddy soil and preparation method thereof
  • Heavy metal composite passivating agent used for paddy soil and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] A heavy metal compound passivator for paddy field soil, it is made of the mass fraction of following three kinds of raw materials:

[0039] Raw material mass fraction%

[0040] Sepiolite mineral powder 83.0

[0041] Iron manganese oxide 12.0

[0042] Quicklime 5.0.

[0043] A preparation method for a heavy metal compound passivator for paddy field soil, the steps are:

[0044] A. Select sepiolite raw ore, pass through 100 mesh, or 110 mesh, or 120 mesh, or 130 mesh, or 140 mesh sieve through ball milling, and set aside. Described sepiolite raw ore, its sepiolite content reaches 80-95%, the content (in terms of Cd, Pb) of heavy metal cadmium and lead≤5mg / kg, moisture content (in terms of H 2 O meter) ≤ 1.5%.

[0045] B. Select clean red mud and ferromanganese ore raw ore, mix evenly according to the ratio of 69% of clean red mud: 31% of ferromanganese ore raw ore, and ball mill through 100 mesh, or 110 mesh, or 120 mesh, or 130 mesh, 140 mesh Mesh sieve, spare. Th...

Embodiment 2- example 16

[0049] A heavy metal compound passivator for paddy field soil, which is made from the mass fraction of the following raw materials:

[0050]

[0051] Its preparation steps are identical with embodiment 1.

[0052] The finished product, which reduces the activity of soil heavy metals, sepiolite, iron manganese oxide (Fe 2 o 3 +MnO 2 ) and calcium oxide (CaO) and other active ingredients (in the form of sepiolite + Fe 2 o 3 +MnO 2 +CaO sum) as shown in the table below:

[0053]

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

minimum value

70.5

71.2

71.8

72.5

73.1

73.8

74.4

75.1

76.4

77.0

77.7

78.3

79.2

79.9

80.5

maximum value

85.4

86.1

86.7

87.3

87.9

88.5

89.2

89.8

91.0

91.6

92.3

92.9

93.7

94.3

95.0

[0054] The finished product c...

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Abstract

The invention discloses a heavy metal composite passivating agent used for paddy soil and a preparation method thereof. The heavy metal composite passivating agent is prepared from three raw materials, namely meerschaum mineral powder, iron and manganese oxides and quicklime, in proportion by the following steps of: A, preparing the meerschaum mineral powder; B preparing the iron and manganese oxides; and C, uniformly mixing the raw materials prepared in the steps A and B with the quicklime to obtain the composite passivating agent. The heavy metal composite passivating agent has a reasonable formula, the method is easy and simple to operate; and the heavy metal composite passivating agent can reduce 70.5 to 95.0 percent of the content of the effective components of meerschaum with heavy metal activity, the iron and manganese oxides (Fe2O3+MnO2), calcium oxide (CaO) and the like in the soil, and also has multiple functions of passivating soil heavy metals, restoring acidified soil and the like, can reduce the contents of active cadmium and lead in the soil of a polluted paddy field by 39.7 to 53.8 percent and 49.9 to 59.1 percent respectively, lower the contents of the cadmium and the lead in agriculture products by 35.1 to 46.9 percent and 35.3 to 53.1 percent respectively, and simultaneously improve the pH value of the soil by 0.22 and 0.43. The heavy metal composite passivating agent is mainly used for paddy production of extensive heavy metal pollution zones, and can also be used for the productions of corns, vegetables and the like planted in paddy fields.

Description

technical field [0001] The invention belongs to the technical field of agricultural environment conservation and restoration, and more specifically relates to a heavy metal composite passivator for paddy field soil, and also relates to a preparation method for a heavy metal composite passivator for paddy field soil. Rice production in vast heavy metal polluted areas can also be used in the production of rice fields, corn, vegetables, etc. Background technique [0002] With the continuous advancement of industrialization and urbanization, the problem of heavy metal pollution in my country's soil has been paid more and more attention by people. According to relevant reports, in the early 1980s, the area of ​​cultivated land polluted by heavy metals such as cadmium, lead, mercury, arsenic, chromium, and nickel in my country was only 2.67 million hm 2 , increased to 6.67 million hm in 1988 2 , had exceeded 10 million hm by the end of the last century 2 , has exceeded 20 milli...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K17/06B09C1/08
Inventor 黄道友朱奇宏刘守龙罗尊长孙楠饶中秀朱昌宇雷敏曹晓玲周斌
Owner INST OF SUBTROPICAL AGRI CHINESE ACAD OF SCI
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