Low-temperature cofired PTC (Positive Temperature Coefficient) ceramic material component
A ceramic material, low temperature co-firing technology, applied in the field of new PTC ceramic material composition, can solve the problem of PbO-BN glass phase reducing the sintering temperature of PTC ceramic material, etc., and achieve the effect of a wide range of applications
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Embodiment 1
[0013] A low-temperature co-fired PTC ceramic material composition is composed of a ceramic phase and a glass phase. The ceramic phase is a common PTC ceramic material, and the glass phase is a PbO-BN series material. The molar ratio of PbO-BN material is 1.5. Now the weight percentage of PbO and BN is: PbO: BN=93: 7 (wt %)
[0014] PTC ceramic materials need to be synthesized in advance, and the synthesis process is as follows:
[0015] BaCO 3 、TiO 2 , Y 2 o 3 , SrCO 3 , CaCO 3 , SiO 2 and Mn(NO 3 ) 2 , according to the chemical equation (1) of the following common PTC ceramic materials:
[0016] Ba 0.85 Ca 0.15 Ti 1.01 o 3 +0.25mol% Y 2 o 3 +2.4mol% SiO 2 +0.08mol%Mn(NO 3 ) 2 (1)
[0017] Mixing ingredients-ball milling-drying-pre-calcination synthesis, the temperature of pre-calcination synthesis is preferably 1100°C to 1200°C.
[0018] PbO-BN materials need to be mixed in advance, and the mixing process is as follows:
[0019] The molar ratio of ...
Embodiment 2
[0027] A low-temperature co-fired PTC ceramic material composition is composed of a ceramic phase and a glass phase. The ceramic phase is common PTC ceramic material, and the glass phase is PbO-BN material. The molar ratio of PbO-BN material is 2. Now the weight percentage of PbO and BN is: PbO: BN=95: 5 (wt %)
[0028] PTC ceramic materials need to be synthesized in advance, and the synthesis process is as follows:
[0029] BaCO 3 、TiO 2 , Y 2 o 3 , SrCO 3 , CaCO 3 , SiO 2 and Mn(NO 3 ) 2 , according to the chemical equation (1) of the following common PTC ceramic materials:
[0030] Ba 0.85 Ca 0.15 Ti 1.01 o 3 +0.25mol% Y 2 o 3 +2.4mol% SiO 2 +0.08mol%Mn(NO 3 ) 2 (1)
[0031] Mixing ingredients-ball milling-drying-pre-calcination synthesis, the temperature of pre-calcination synthesis is preferably 1100°C to 1200°C.
[0032] PbO-BN materials need to be mixed in advance, and the mixing process is as follows:
[0033] The molar ratio of PbO and BN is...
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