Preparation method of cyclohexanone from oxidation of cyclohexanol
A technology of cyclohexanol and cyclohexanone, which is applied in the fields of oxidative preparation of carbonyl compounds, chemical instruments and methods, organic chemistry, etc., can solve problems such as unseen research reports, and achieve increased reaction rate, reduced energy consumption, and protected catalysts Effect
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Embodiment 1
[0033] This example illustrates the reaction process and results using HTS as a catalyst.
[0034] Cyclohexanol, hydrogen peroxide, methyl alcohol and catalyst HTS are 1: 2 according to the mol ratio of cyclohexanol and hydrogen peroxide, the mass ratio of methyl alcohol and catalyst HTS is 20, and the mass ratio of cyclohexane and catalyst is 50: 1. React at a temperature of 30°C and a pressure of 1.5 MPa.
[0035] The results of the reaction for 2 hours were as follows: the conversion rate of cyclohexanol was 36%; the selectivity of cyclohexanone was 93%.
[0036]The results of the reaction for 15 hours were as follows: the conversion rate of cyclohexanol was 35%; the selectivity of cyclohexanone was 91%.
Embodiment 2
[0038] This example illustrates the reaction process and results using TS-1 as a catalyst.
[0039] With cyclohexanol, hydrogen peroxide, methyl alcohol and catalyst TS-1 according to the mol ratio of cyclohexanol and hydrogen peroxide as 1: 2, the mass ratio of solvent methanol and catalyst TS-1 is 20, the ratio of cyclohexanol and catalyst The mass ratio is 10:1, and the reaction is carried out at a temperature of 30° C. and a pressure of 1.5 MPa.
[0040] The results of the reaction for 2 hours were as follows: the conversion rate of cyclohexanol was 23%; the selectivity of cyclohexanone was 89%.
[0041] The results of the reaction for 15 hours were as follows: the conversion rate of cyclohexanol was 15%; the selectivity of cyclohexanone was 85%.
Embodiment 3
[0043] This example illustrates the reaction process and results using TS-1 as a catalyst.
[0044] Cyclohexanol, hydrogen peroxide, acetone and TS-1 are 1: 6 according to the mol ratio of cyclohexanol and hydrogen peroxide, the mass ratio of acetone and catalyst is 200, and the mass ratio of cyclohexanol and catalyst is 80: 1. React at a temperature of 60°C and a pressure of 1.0 MPa.
[0045] The results of the reaction for 2 hours were as follows: the conversion rate of cyclohexanol was 34%; the selectivity of cyclohexanone was 88%.
[0046] The results of the reaction for 15 hours were as follows: the conversion rate of cyclohexanol was 32%; the selectivity of cyclohexanone was 86%.
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