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Quick foaming agent

A foaming agent and fast technology, applied in non-explosive/non-thermal agent components, offensive equipment, explosives, etc., can solve the problems of affecting the blasting performance of emulsion explosives, affecting the service life of machinery and equipment, and difficult to control foaming time. The effect of less corrosiveness, long natural storage period and low cost of machinery and equipment

Inactive Publication Date: 2011-05-25
SHAANXI HUAQIN NEW ENERGY TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The commonly used chemical foaming agent is NaN0 3 , has the characteristics of low cost and automatic operation. If the foaming conditions are properly controlled, better blasting performance can be obtained. However, factors such as foaming temperature and foaming time are not easy to control, resulting in unsatisfactory foaming effect and affecting emulsification. Explosives and blasting performance mainly have the following deficiencies:
[0005] (3) There are two types of general foaming accelerators, one is acidic substances, such as nitric acid, hydrochloric acid, phosphoric acid, stearic acid, etc., and the other is salt substances such as: benzene nitrate, thiourea, sulfur Ammonium cyanate, etc., generally speaking, inorganic acid has a strong promoting effect, strong acid foams quickly, but is highly corrosive, and at the same time affects the service life of machinery and equipment
The effect of organic acid is small, but the foaming is slow

Method used

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  • Quick foaming agent

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] 1) Take 1.5g of thiourea, 25g of sodium nitrite, 4g of potassium nitrite, and 69.5g of water to make a 100g stabilizer; take 8g of ammonium nitrate, 2.5g of nitric acid, 2g of glacial acetic acid, sulfur 0.3 g of sodium cyanate, 0.6 g of phosphoric acid, 1.5 g of diammonium hydrogen phosphate, 0.8 g of citric acid, 2 g of urea, and 82.3 g of water are mixed to form a 100 g accelerator;

[0021] 2) When the emulsion explosive is 1000g, take 4g of the above-mentioned stabilizer and 5.2g of the above-mentioned accelerator and mix them to obtain the foaming agent of the present invention.

Embodiment 2

[0023] 1) Take 0.5g of thiourea, 20g of sodium nitrite, 3g of potassium nitrite, and 76.5g of water to make a 100g stabilizer; take 7g of ammonium nitrate, 2g of nitric acid, 1g of glacial acetic acid, and thiocyanate 0.2 g of sodium phosphate, 0.5 g of phosphoric acid, 1 g of diammonium hydrogen phosphate, 0.5 g of citric acid, 1 g of urea, and 86.8 g of water are mixed to form a 100 g accelerator;

[0024] 2) When the emulsion explosive is 1000g, take 3g of the above-mentioned stabilizer and 3.6g of the above-mentioned accelerator and mix them to obtain the foaming agent of the present invention.

Embodiment 3

[0026] 1) Take 1.5g of thiourea, 30g of sodium nitrite, 5g of potassium nitrite, and 63.5g of water to make a 100g stabilizer; take 11g of ammonium nitrate, 3g of nitric acid, 3g of glacial acetic acid, and thiocyanate Sodium acid is 0.5g, phosphoric acid is 0.7g, diammonium hydrogen phosphate is 2g, citric acid is 1.2g, urea is 3g, water is 75.6g and is mixed into 100g accelerator;

[0027] 2) When the emulsion explosive is 1000g, take 5g of the above-mentioned stabilizer and 7.5g of the above-mentioned accelerator and mix them to obtain the foaming agent of the present invention.

[0028] Quality index of blowing agent (see Table 1):

[0029] Table 1:

[0030]

[0031] Adopt the emulsion explosive inspection effect of the blowing agent of embodiment 1 (see table 2)

[0032] Table 2

[0033]

[0034] Effect evaluation experiment and results of the present invention: available from Table 2, the foaming time is short, without aftereffect, easy to control the density,...

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Abstract

The invention relates to a quick foaming agent for foaming emulsion explosives, which consists of a stabilizing agent and an accelerating agent. The addition amount of the stabilizing agent is 0.3 to 0.5 percent of an emulsion explosive; the addition amount of the accelerating agent is 1.2 to 1.5 times weight of the stabilizing agent of the emulsion explosive; the stabilizing agent consists of the following components in percentage by weight: 0.5 to 1.5 percent of sulfourea, 20 to 30 percent of sodium nitrite, 3 to 5 percent of potassium nitrite, and 63.5 to 76.5 percent of water; and the accelerating agent consists of the following components in percentage by weight: 7 to 11 percent of ammonium nitrate, 2 to 3 percent of hydrogen nitrate, 1 to 3 percent of glacial acetic acid, 0.2 to 0.5 percent of sodium thiocyanate, 0.5 to 0.7 percent of phosphoric acid, 1 to 2 percent of diammonium hydrogen phosphate, 0.5 to 1.2 percent of citric acid, 1 to 3 percent of urea and 75.6 to 86.8 percent of water. The quick foaming agent has the characteristics of high foaming speed, low corrosion, small aftereffect and the like; meanwhile, the ratio of foam materials can be adjusted according to the formula and process conditions of the emulsion explosive and performance requirement, and the continuous production of emulsion explosive packages is realized.

Description

technical field [0001] The invention relates to a special sensitizer for emulsified explosives, in particular to a rapid foaming agent for emulsified explosives. Background technique [0002] The function of the foaming agent is to form tiny bubbles in the emulsion explosive colloid, use the tiny bubbles to generate hot spots, and increase the density of the explosive. The commonly used chemical blowing agent is NaN0 3 , has the characteristics of low cost and automatic operation. If the foaming conditions are properly controlled, better blasting performance can be obtained. However, factors such as foaming temperature and foaming time are not easy to control, resulting in unsatisfactory foaming effect and affecting emulsification. Explosives and blasting performance mainly have the following deficiencies: [0003] (1) Na 2 N0 3 After adding such as colloid, the foaming speed is slow, and it needs to be kept warm for a period of time to achieve the required and sensitize...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C06B23/00
Inventor 马永宁
Owner SHAANXI HUAQIN NEW ENERGY TECH CO LTD
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