Method for adjusting Schottky contact barrier height of metal and N-type germanium
A Schottky contact and barrier height technology, applied in semiconductor devices and other directions to achieve low-cost effects
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Embodiment 1
[0019] Example 1: figure 1 A schematic flow chart of the preparation of metal / TaN / n-Ge contacts in the present invention is given, wherein: 1 is a germanium substrate; 2 is SiO 2 layer; 3 is a photoresist; 4 is a TaN layer; 5 is a metal layer; 6 is a metal Al layer. Firstly, clean the n-Ge(100) substrate with a resistivity of 0.043Ωcm: first use acetone and ethanol for 10 minutes to remove organic pollutants, repeat this process twice, and clean with cold deionized water; After the N-type substrate was soaked in HCl (36%): H 2 O=1(ml): 4(ml) solution for about 30s, remove oxides and metal impurities, and then wash with cold deionized water, this process needs to be repeated 5 times; then soak the n-Ge soaked in hydrochloric acid solution in HF:H 2 O=1(ml): 50(ml) solution for about 15s, then soak in deionized water for 15s to remove oxides, repeat this process 3 times; finally blow dry with nitrogen (see figure 1 (a)).
[0020] Put the cleaned N-type germanium substrate i...
Embodiment 2
[0022] Embodiment 2: similar to Embodiment 1, the difference is that the metal Ni deposited on the TaN layer is 400 nm, and the deposited TaN thicknesses are 0, 2, 4, 6, 8, 10, 15, and 25 nm, respectively. Finally, a Ni / TaN / n-Ge contact is prepared, and the TaN thickness adjusts the Ni / n-Ge Schottky barrier height, see figure 2 .
Embodiment 3
[0023] Example 3: Similar to Example 2, the difference is that 400 nm of metal Fe is deposited on the TaN layer. Fe / TaN / n-Ge contacts are finally prepared, and the thickness of TaN adjusts the height of the Fe / n-Ge Schottky barrier see figure 2 .
[0024] The present invention firstly cleans the N-type germanium (n-Ge) sheet, and then adopts traditional photolithography and corrosion processes to obtain the window where the metal contacts with the N-type germanium; then, deposits a layer of TaN and One layer of metal; standard photolithographic lift-off process; metal / TaN / n-Ge contacts obtained. During the manufacturing process, the purpose of adjusting the height of the metal / TaN / n-Ge Schottky contact barrier is realized by changing the thickness of TaN.
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