Highly flame-resistant external wall heat preservation material and process for producing same
A technology for external wall insulation and production technology, applied in insulation, building components, etc., can solve problems such as potential safety hazards, and achieve the effects of low smoke density, low free acid, and low smoke density
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[0041] 1. Preparation of modified low-hydroxyl phenolic resin:
[0042] The resole phenolic resin was synthesized under the conditions of alkalinity and methanol as a polymerization inhibitor, and the molar ratio of phenol to formaldehyde was 1:1.6-2.5. Based on the mass of phenol, polyvinyl alcohol accounts for 5-15% of phenol, polyurethane prepolymer containing NCO groups accounts for 1-50% of phenol, active rubber powder accounts for 2-20% of phenol, coupling agent The 10-20mm chopped glass fiber after treatment accounts for 2-10% of phenol.
[0043] Production process of modified low hydroxyl phenolic resin:
[0044] 1. Add acid (such as oxalic acid) to adjust the pH value to 3 to 4 when phenol and all polyvinyl alcohol are mixed evenly, and the reaction temperature is between 80 and 92 degrees, and the reaction is 50 minutes to 65 minutes (preferably 1 hour) after passing water to cool to 40~55 degree (preferably 50 degree).
[0045] 2. After adding all the polyurethan...
Embodiment 1
[0054] Mix phenol and polyvinyl alcohol accounting for 6% by mass of phenol evenly, adjust the pH value to 4 conditions, the reaction temperature is at 85 degrees, and cool to 50 degrees by passing water after reacting for 1 hour, add phenol mass parts (hereinafter the same ) 10% polyurethane prepolymer and then heated up to 80°C, reacted for 1 hour and cooled to 50°C with water. Add sodium hydroxide aqueous solution to adjust the pH value to 9, add all the formaldehyde under the condition, raise the temperature to 88 degrees, react for 3 to 4 hours (preferably 3.5 hours), and stop heating. Add active rubber powder accounting for 2% by mass of phenol, add treated chopped glass fibers accounting for 3% by mass of phenol, add acid to neutralize the pH value to about 7, and then vacuum dehydrate to adjust the viscosity to 25 degrees. 5500mPas, obtain the modified low hydroxyl phenolic resin.
[0055] High flame-retardant exterior wall insulation material (board), based on modifi...
Embodiment 2
[0059] When mixing phenol and 6% polyvinyl alcohol evenly, adjust the pH value to 4. The reaction temperature is 85 degrees. After reacting for 1 hour, pass water and cool to 50 degrees. After the reaction, the temperature was raised to 84 degrees, and after 1 hour of reaction, the water was cooled to 50 degrees. Add sodium hydroxide aqueous solution to adjust the pH value to 9, add all the formaldehyde under the condition, raise the temperature to 89 degrees, react for 3.5 hours, and stop heating. Add active rubber powder accounting for 2% by mass of phenol, add treated chopped glass fibers accounting for 3% by mass of phenol, add acid to neutralize the pH value to about 7, and then vacuum dehydrate to adjust the viscosity to 25 degrees. 5500mPas. A modified low-hydroxyl phenolic resin is obtained.
[0060] Based on modified low-hydroxyl phenolic resin, 100 parts modified water repellent 2 parts, emulsifier "AK8804" 2 parts, emulsifier "Tween 80" 2 parts, foaming agent "HFC...
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