Method of preparing environment friendly incrassation type nano-composite tanning agent for leather
A compound tanning agent and nano-technology, which is applied in the field of preparation of environmentally friendly thickened nano-composite tanning agents for leather, can solve problems such as low-end products are difficult to survive, and achieve the effect of improving leather profits, increasing profits, and high absorption rate
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Embodiment 1
[0014] Embodiment 1: 1) preparation of triethanolamine modified maleic anhydride
[0015] Mix 14.9g of triethanolamine and 14.4g of acrylic acid and heat up to 50°C, then add 0.15g of catalyst p-toluenesulfonic acid, heat up to 90°C, and then add triethanolamine to maleic anhydride in a molar ratio of 1:2 Maleic anhydride was incubated for 2 hours, the modified product was cooled to 50°C, and deionized water was added to adjust the solid content to 50% to obtain triethanolamine-modified maleic anhydride;
[0016] 2) Preparation of methacrylic acid-modified maleic anhydride / montmorillonite nanocomposite tanning agent
[0017] Disperse sodium montmorillonite (Na-MMT) in 100mL deionized water to make a solution with a mass concentration of 10%, stir at a constant temperature of 30°C for 60min, let it stand overnight, and add Na-MMT at 50°C the next day Potassium persulfate of quality such as montmorillonite (Na-MMT), fully stirred, ultrasonic treatment, and dried to obtain a com...
Embodiment 2
[0020] Embodiment 2: 1) preparation of triethanolamine modified maleic anhydride
[0021] Mix 14.9g of triethanolamine and 14.4g of acrylic acid and heat up to 50°C, then add 0.25g of catalyst p-toluenesulfonic acid, heat up to 90°C, and then add triethanolamine to maleic anhydride in a molar ratio of 1:3 Maleic anhydride was incubated for 2.5 hours, the modified product was cooled to 50°C, and deionized water was added to adjust the solid content to 50% to obtain triethanolamine-modified maleic anhydride;
[0022] 2) Preparation of methacrylic acid-modified maleic anhydride / montmorillonite nanocomposite tanning agent
[0023] Disperse sodium montmorillonite (Na-MMT) in 100mL deionized water to make a solution with a mass concentration of 10%, stir at a constant temperature of 30°C for 60min, let it stand overnight, and add Na-MMT at 50°C the next day Potassium persulfate of quality such as montmorillonite (Na-MMT), fully stirred, ultrasonic treatment, and dried to obtain a c...
Embodiment 3
[0026] Embodiment 3: 1) preparation of triethanolamine modified maleic anhydride
[0027] Mix 14.9g of triethanolamine and 14.4g of acrylic acid and heat up to 50°C, then add 0.20g of catalyst p-toluenesulfonic acid, heat up to 90°C, and then add triethanolamine to maleic anhydride in a molar ratio of 1:1 Maleic anhydride was incubated and reacted for 3 hours, the modified product was cooled to 50°C, and deionized water was added to adjust the solid content to 50% to obtain triethanolamine-modified maleic anhydride;
[0028] 2) Preparation of methacrylic acid-modified maleic anhydride / montmorillonite nanocomposite tanning agent
[0029] Disperse sodium montmorillonite (Na-MMT) in 100mL deionized water to make a solution with a mass concentration of 10%, stir at a constant temperature of 30°C for 60min, let it stand overnight, and add Na-MMT at 50°C the next day Potassium persulfate of quality such as montmorillonite (Na-MMT), fully stirred, ultrasonic treatment, and dried to ...
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