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Azo dye composition and application thereof

A technology of azo dyes and compositions, applied in the field of textile printing and dyeing, can solve the problems of poor compatibility, severe dye decomposition, intolerance to alkaline baths and high pH dyeing baths, etc.

Active Publication Date: 2010-06-09
浙江昱泰染化科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0010] In summary, although some commercially available disperse dyes can be dyed under weakly alkaline conditions, they are not resistant to alkaline baths with high concentrations of alkaline agents and high pH dyeing baths, and the compatibility between single dyes is poor, so they cannot better meet the requirements of the previous requirements. To deal with the needs of scouring and one-bath one-step dyeing, and some alkali-resistant disperse dyes hardly color the dyed fabrics during dyeing, and the dyes decompose seriously during the dyeing process
In the prior art, the research on alkaline dyeing is basically limited to the auxiliary agent and the dyestuff as the auxiliary, which fails to solve the problem of polyester fiber dyeing process fundamentally.

Method used

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  • Azo dye composition and application thereof
  • Azo dye composition and application thereof
  • Azo dye composition and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0071] With 51 kilograms of formula (a-1), 49 kg of azo dyes shown in formula (a-9), 125 kg of sodium lignosulfonate, after adding water and beating and mixing, grinding and dispersing with a grinder, spray drying, to obtain finished product. The dye is suitable for polyester fibers and their blended fabrics under alkaline conditions for pretreatment and dyeing combined with one-bath one-step dyeing, and can provide the fabric with orange hue with excellent fastness properties.

[0072]

[0073]

Embodiment 2~14

[0075] According to the data shown in Table 1, after mixing azo dyes, 125 kg of auxiliary agents, adding water and beating, grinding and dispersing with a grinder, and spray drying to obtain a finished product.

[0076] Table 1 (weight in kilograms)

[0077]

[0078]

Embodiment 15

[0080] 50 kilograms of the azo dye compositions prepared in Example 1, 10 kilograms in Example 7 and 40 kilograms in Example 9 were mixed to obtain a finished product. The dye is suitable for polyester fibers and their blended fabrics under alkaline conditions for pretreatment and dyeing combined with one-bath and one-step dyeing. The dyeing speed is fast and uniform, and it can provide black fabrics with excellent fastness properties.

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Abstract

The invention relates to an azo dye compound and the application thereof. The compound is the combination of at least two dyes with A in the general formula (I) selected from any structure of (a), (b)or (c); any combination with A to be at least one from (a), at least one from (b) or at least one from (c); or the combination of at least one dye shown by the general formula (1) and at least one general disperse dye, or / and a dye as shown by the formula (2). Each substituent is shown as the claim of right. The compound can dye polyester and blended fabric thereof under the condition of strong alkalinity with pH more than or equal to 11 and less than or equal to 14; the alkalinity condition can effectively remove slurry and oil on the fabric, and overcomes the defect that decomposition products can be separated out in an acid bath, and cause dyeing defect. The cloth and the fabric adopting the azo dye compound are neat and have excellent styles. In addition, the polyester fiber and the blended fabric thereof can be pretreated with alkalinity and be dyed in a bath and at one step, thus improving the efficiency, and reducing the manufacturing cost and the waste water from dyeing.

Description

technical field [0001] The invention belongs to the technical field of textile printing and dyeing, and relates to an azo dye composition and an environment-friendly, energy-saving and high-efficiency dyeing method applied to polyester fibers. Background technique [0002] The contamination of various oils in the spinning process of polyester and other chemical fiber fabrics is a problem that must be solved in the pre-dyeing process. At present, the removal of oil agents basically adopts alkaline conditions. However, such process conditions cause unnecessary trouble to the dyeing process. As we all know, conventional disperse dyes must be dyed under acidic conditions. After alkaline degreasing, they must be drained and washed, and then added to cloth and acetic acid to adjust the pH value for dyeing. How to shorten the dyeing process and achieve one-bath degreasing dyeing is a difficult problem in polyester dyeing. In the past ten years, the problems of energy shortage an...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09B67/36D06P1/02D06P3/52D06P3/24D06P3/82
Inventor 陈旭王喆荆丽丽
Owner 浙江昱泰染化科技有限公司
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