Sun blocking stack
A layered structure and base layer technology, applied in thin material handling, transportation and packaging, etc., can solve problems such as difficult neutralization and color tone
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Embodiment 1
[0084] A 2 m x 1 m x 6 mm thick sheet of ordinary transparent soda-lime float glass was loaded in a magnetron type cathode sputtering apparatus operated under reduced pressure (approximately 0.3 Pa) by means of a magnetic field. On the glass sheet is deposited a multi-layer anti-sunlight laminated structure comprising in order:
[0085] a) A first dielectric coating consisting of two oxide layers deposited from zinc-tin alloy cathodes of different compositions in a reactive atmosphere formed by a mixture of argon and oxygen. A first zinc-tin mixed oxide having a thickness of approximately 30 nanometers was formed from a cathode of a zinc-tin alloy having 52 wt% zinc and 48 wt% tin to form zinc stannate Zn 2 SnO 4 spinel structure. A second zinc-tin mixed oxide ZnSnO with a thickness of about 10 nanometers x Deposited from a zinc-tin alloy target with 90% by weight zinc and 10% by weight tin.
[0086] b) a first infrared reflective functional layer consisting of approximate...
Embodiment 2
[0119] Example 2 was carried out in the same manner as Example 1 but with a different stack structure. In this example, the following sequence is used:
[0120] a) A first dielectric coating consisting of two oxide layers deposited from zinc-tin alloy cathodes of different compositions in a reactive atmosphere formed by a mixture of argon and oxygen. A first zinc-tin mixed oxide with a thickness of approximately 24 nanometers was formed from a cathode of a zinc-tin alloy having 52 wt% zinc and 48 wt% tin to form zinc stannate Zn 2 SnO 4 spinel structure. A second zinc-tin mixed oxide ZnSnO with a thickness of about 8 nanometers x Deposited from a zinc-tin alloy target with 90% by weight zinc and 10% by weight tin.
[0121] b) a first infrared reflective functional layer consisting of about 9 nanometers of silver from an almost pure silver target in a neutral argon atmosphere,
[0122] c) A first sacrificial metal layer consisting of a layer of Ti deposited from titanium p...
Embodiment 3 to 15
[0152] Unless otherwise specified, the following Examples 3 to 15 were carried out in a similar manner to the above Example 1 but with different structures. The corresponding stack structures are given in Table 1 below, and the abbreviations used are explained below:
[0153] • D1 = first dielectric coating, consisting of two or three oxide or nitride or optionally oxynitride layers. The nitride layer is deposited from a metal target in a reactive mixture of nitrogen and argon. This applies to the other dielectrics of the stack (if this is the case). The Si used in these examples 3 N 4 Layers can be slightly oxidized in the form of SiOxNy. It should be noted that Si 3 N 4 and ZnO layers can be doped with aluminum in a known manner.
[0154] • D2 = intermediate dielectric coating, if present in an embodiment, consisting of an oxide or nitride or optionally oxynitride layer like D1.
[0155] • D3 = outer dielectric coating, consisting of one or two oxide or nitride or opti...
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